• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.24-25
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• 2017

Gamma-C₂S (γ-C₂S) is a substance that is difficult to react with water under normal temperature but can absorb a large amount of CO₂ in the air. The addition of γ-C₂S to cementitious materials through the curing of CO₂ can improve the pore structure and improve the durability of the material. In this study, three kind of Ca-bearing materials : CaO, Ca(OH)₂, CaCO₃, were calcined 2.5h at 1450℃ to synthesize γ-C₂S after mixing with SiO₂ respectively. Among them, Ca(OH)₂ mixed with SiO₂ after calcining shows highest content. Synthesized γ-C₂S was added to the cement mortar, after water curing for 1 month, accelerated carbonation test was experimented. After 28d accelerated carbonation test, pore structure will be detectived by MIP. Based on the MIP result, following the calculation method of Fractal theory, the pore structure will be quantitative described.

• Journal of the Korea Institute of Building Construction
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• v.15 no.3
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• pp.281-289
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• 2015

Carbonation of concrete causes reduction of pH and subsequently causes steel corrosion for reinforced concrete structure. However, for plain concrete structure or PC product, it can lead to a decrease in porosity, high density, improvement of concrete, shrinkage-compensation. Recently, based on this theory, research of $CO_2$ curing effect has been performed, but it was mainly focused on its effects on compressive strength using only ordinary portland cement. Researches on $CO_2$ curing effect for concrete containing $CO_2$ reactive materials such as ${\gamma}-C_2S$, MgO haven't been investigated. Therefore, this study has performed experiments under water-binder ratio 40%, and the replacement ratios of ${\gamma}-C_2S$ and MgO were 90%. Micro-chemical analysis, measurement of compressive strength according to admixtures and $CO_2$ curing were investigated. Results from this study revealed that higher strength was measured in case of $CO_2$ curing compared with none $CO_2$ curing for plain specimen indicating difference between 1.08 and 1.26 times, in case of ${\gamma}-C_2S$ 90, MgO 90 specimen, incorporating high volume replaced as much as 90%, it was proven that when applying $CO_2$ curing, higher strength which has difference between 14.56 and 45.7 times, and between 6.5 and 10.37 times was measured for each specimen compared to none $CO_2$ curing. Through micro-chemical analysis, massive amount of $CaCO_3$, $MgCO_3$ and decrease of porosity were appeared.

• Journal of the Korean Ceramic Society
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• v.53 no.2
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• pp.194-199
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• 2016

Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.

• Journal of Radiation Protection and Research
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• v.26 no.3
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• pp.287-290
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• 2001

The 9.17MeV gamma-rays from the $^{13}C(p,\;{\gamma})^{14}N,\;^{14}N({\gamma},\;{\gamma})^{14}N$ reactions were measured. The incident 9.17MeV gamma-ray was produced from the $^{13}C(p,\;{\gamma})^{14}N$ reaction at Ep=1.75MeV resonance. The 1.75MeV proton beam was accelerated using the 3MV SNU-AMS Tandetron and 1.7MV KIGAM Tandem accelerators. The enriched 13C target was $121{\mu}g/cm^2$ self-supporting foil, and we used liquid nitrogen as a resonant absorption target. We used a HP-Ge detector with 30% efficiency and less 2keV energy resolution. We developed new method to detect the scattered 9.17MeV gamma-ray from the nitrogen target by using the energy difference between the Doppler shifted gamma-ray from the $^{13}C(p,\;{\gamma})^{14}N$ reaction and the resonant absorbed and rescattered gamma-ray from the $^{14}N({\gamma},\;{\gamma})^{14}N$ reaction.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.118-119
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• 2016

γ-C₂S is known as a kind of substance that it does not react with water at room temperature. However it could react with the CO₂ producing CaCO₃ and silica gel as the carbonation products. Thus γ-C₂S can be used as a mineral addition to improve the compressive strength and durability of concrete. On the other hand, the manufacture of γ-C₂S can give an effective utilization of industrial by-product with low energy consumption and low CO₂ emission. This paper aims to summarize the development situation on this field.

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.3
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• pp.90-96
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• 2018

In this study, the mechanical and micro-structural change of cement pastes incorporating Stainless-Steel Slag Argon Oxygen Decarburization Slag (STS-A) containing ${\gamma}-C_2S$ as a carbon capture materials were investigated with carbonation curing condition. ${\gamma}-C_2S$ is non-hydraulic, therefore does not react with water. But ${\gamma}-C_2S$ has a reactivity under carbonation curing condition with water. The reaction products fill up the pore in pastes. The microstructure of STS-A blended cement pastes could be densified by this reaction. The pore structure of cement pastes incorporating STS-A was measured using mercury intrusion porosimetry (MIP) after carbonation curing ($CO_2$ concentration is about 5%). Also the fractal characteristics were investigated for the effect of carbonation curing on the micro-structural change of paste specimens. From the results, the compressive strength of carbonated specimens incorporating STS-A increased and pore-structure of carbonated paste is more complicated.

• Journal of the Korean Mathematical Society
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• v.49 no.4
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• pp.733-743
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• 2012

For the "Hopf bundle" $S^1{\rightarrow}S^{2n,1}{\rightarrow}\mathbb{C}H^n$, horizontal lifts of simple closed curves are studied. Let ${\gamma}$ be a piecewise smooth, simple closed curve on a complete totally geodesic surface $S$ in the base space. Then the holonomy displacement along ${\gamma}$ is given by $$V({\gamma})=e^{{\lambda}A({\gamma})i}$$ where $A({\gamma})$ is the area of the region on the surface $S$ surrounded by ${\gamma}$; ${\lambda}=1/2$ or 0 depending on whether $S$ is a complex submanifold or not. We also carry out a similar investigation for the complex Heisenberg group $\mathbb{R}{\rightarrow}\mathcal{H}^{2n+1}{\rightarrow}\mathbb{C}^n$.

• Honam Mathematical Journal
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• v.40 no.4
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• pp.809-816
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• 2018

The aim of this research paper is to evaluate fifty double integrals invoving generalized hypergeometric function (25 each) in the form of $${{\int}^1_0}{{\int}^1_0}\;x^{{\gamma}-1}y^{{\gamma}+c-1}(1-x)^{c-1}(1-y)^{c+{\ell}}(1-xy)^{{\delta}-2c-{\ell}-1}{\times}_3F_2\[{^{a,\;b,\;2c+{\ell}+1}_{\frac{1}{2}(a+b+i+1),\;2c+j}}\;;{\frac{(1-x)y}{1-xy}}\]dxdy$$ and $${{\int}^1_0}{{\int}^1_0}\;x^{{\gamma}-1}y^{{\gamma}+c+{\ell}}(1-x)^{c+{\ell}}(1-y)^{c-1}(1-xy)^{{\delta}-2c-{\ell}-1}{\times}_3F_2\[{^{a,\;b,\;2c+{\ell}+1}_{\frac{1}{2}(a+b+i+1),\;2c+j}}\;;{\frac{1-y}{1-xy}}\]dxdy$$ in the most general form for any ${\ell}{\in}{\mathbb{Z}}$ and i, j = 0, ${\pm}1$, ${\pm}2$. The results are derived with the help of generalization of Edwards's well known double integral due to Kim, et al. and generalized classical Watson's summation theorem obtained earlier by Lavoie, et al. More than one hundred ineteresting special cases have also been obtained.

• Journal of the Chungcheong Mathematical Society
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• v.13 no.1
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• pp.139-144
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• 2000

The generalized noncommutative torus $T_{\rho}^d$ of rank m was defined in [2]. Assume that for the completely irrational noncommutative subtorus $A_{\rho}$ of rank m of $T_{\rho}^d$ there is no integer q > 1 such that $tr(K_0(A_{\rho}))=\frac{1}{q}{\cdot}tr(K_0(A_{\rho^{\prime}}))$ for $A_{\rho^{\prime}}$ a completely irrational noncommutative torus of rank m. All $C^*$-algebras ${\Gamma}({\eta})$ of sections of locally trivial $C^*$-algebra bundles ${\eta}$ over $M=\prod_{i=1}^{e}S^{2k_i}{\times}\prod_{i=1}^{s}S^{2n_i+1}$, $\prod_{i=1}^{s}\mathbb{PR}_{2n_i}$, or $\prod_{i=1}^{s}L_{k_i}(n_i)$ with fibres $T_{\rho}^d{\otimes}M_c(\mathbb{C})$ were constructed in [6, 7, 8]. We prove that ${\Gamma}({\eta}){\otimes}M_{p^{\infty}}$ is isomorphic to $C(M){\otimes}A_{\rho}{\otimes}M_{cd}(\mathbb{C}){\otimes}M_{p^{\infty}}$ if and only if the set of prime factors of cd is a subset of the set of prime factors of p, that $\mathcal{O}_{2u}{\otimes}{\Gamma}({\eta})$ is isomorphic to $\mathcal{O}_{2u}{\otimes}C(M){\otimes}A_{\rho}{\otimes}M_{cd}(\mathbb{C})$ if and only if cd and 2u - 1 are relatively prime, and that $\mathcal{O}_{\infty}{\otimes}{\Gamma}({\eta})$ is not isomorphic to $\mathcal{O}_{\infty}{\otimes}C(M){\otimes}A_{\rho}{\otimes}M_{cd}(\mathbb{C})$ if cd > 1 when no non-trivial matrix algebra can be ${\Gamma}({\eta})$.

• 대한생식의학회:학술대회논문집
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• 2001.03a
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• pp.195-205
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• 2001

태반 영양배엽 (trophoblast)은 포유동물의 발생과정 중 가장 먼저 분화되는 세포로서, 자궁환경내에서 배아가 착상, 발생, 및 분화하기 위해서 반드시 필요한 태반을 형성하는 색심적인 세포이다. 영양배엽 세포의 분화과정중의 결함은 배아의 사산이나 임신질환 등의 치명적 결과를 초래한다. 하지만, 영양배엽 세포의 분화를 조절하는 분자생물학적인 메카니즘은 아직 규명되지 않고 있다. 영양배엽 세포의 분화를 조절하는 경로를 규경하기 위한 선결과제는 분화된 영양배엽 세포에서만 발현하는 많은 유전자들이 밝혀져야만 한다. 본 연구팀은 최근에 분화된 영양배엽 세포에서만 발현하는 두 종류의 새로운 유전자들을 찾았다. 한 종류는 homeobox를 보유하고 있는 조절 유전자 Psx이고, 다른 한 종류는 임신호르몬인 태반 프로락틴 라이크 단백질 유전자 PLP-C${\beta}$이다. 본 연구과제의 목표는 이들 유전자의 기능과 조절 메카니즘을 규명함으로써, 영양배엽 세포의 분화를 조절하는 조절경로를 밝히는 것이다. 이를 위하여 다음과 같은 일련의 연구를 수행할 것이다. 1) Psx 유전자가 분화된 영양배엽 세포에서만 발현케 하는 조절 메카니즘을 규명하기 위해 functional assays, in vitro footprinting, gel mobility shift assays, 생쥐형질전화, UV crosslinking, Southwestern blot 등의 방법을 통해 Psx 유전자의 cis-acting 요인과 trans-acting factor를 밝혀 분석한다. 2) 영양배엽 세포의 분화조절 경로를 규명하기 위해 random oligonuclotide library screening, DD-PCR, subtractive screening 등의 방법을 이용하여 Psx 유전자에 의해 조절되는 하부유전자를 밝힌다. 3) Psx 유전자를 knock-out시켜 영양배엽 세포가 발달 및 분화하는데 미치는 역할을 밝힌다. 4) Yeast two-hybrid screening방법을 이용하여 태반 프로락틴 유전자의 수용체를 찾아 이들의 신호전달 기전을 밝힌다. 제1차년 연구결과로서, mouse와 rat으로부터 각각 Psx 유전자의 genomic DNA를 클로닝하여, 유전자 구조를 비교한 결과, mouse Psx (mPsx2)는 4개의 exons으로 이루어져 있는 반면에, rat Psx (Psx3)는 3개의 exons으로 구성되어 있었다. 즉, rPsx3는 mPsx2의 exon1이 없었다. Notrhern blot과 in situ hybridization 분석에 의해 mouse와 rat에서 Psx 유전자가 다르게 발현 조절되는 현상을 밝혔다. 실제로 mPsx2와 rPsx3의 5'-flanking지역을 클로닝하여 염기서열 분석 결과 전혀 homology를 찾을 수 없었다. 또한, 이들 각각 promoter의 activity를 luciferase reporter를 이용하여 조사한 결과 Rcho-1 trophoblast cells에서 각기 다른 activity를 보여 주는 것을 발견하였다. Psx 유전자의 transcription start sites는 Primer extension에 의해 밝혔다. 또한 Psx2 유전자를 knock-out 시키기 위해 targeting vector를 Osdupde1에 제작하였다. 본 과제를 시작할 때 새로운 프로락틴 유전자 하나를 클로닝하여 이 유전자를 PLP-I라고 이름을 붙였다. 이 후 이 유전자 (PLP-I)는 PLP-C${\beta}$라고 이름을 붙이게 되었다. Mouse PLP-C${\beta}$ 유전자의 counterpart를 rat에서 찾아 염기서열을 비교한 결과 mouse와 rat에서 PLP-C${\beta}$유전자의 homology는 약 79% (amino acid level)였다. 본 연구과정을 통해 또 하나의 새로운 PLP-C subfamily member를 mouse로부터 클로닝 하였고, 이 유전자를 PLP-C${\gamma}$라 하였다. PLP-C${\beta}$와 PLP-C${\gamma}$의 발현 유형은 Northern blot과 in 냐셔 hybridization 분석에 의해 태반의 제한된 spongitrophoblast와 trophoblast giant cells에서만 발현하는 것을 밝혔다. 놀랍게도 이들 두 새로운 유전자는 alternative splicing에 의해 두 종류의 isoform이 있음을 밝혔다. PLP family member 유전자로서 splicing에 의한 isoforms을 보여 주는 유전자로는 PLP-C${\beta}$와 PLP-C${\gamma}$가 최초이다. 이들 isoform mRNAs의 발현 유형은 RT-PCR 방법을 이용하여 규명하였다. 또 하나의 새로운 발견은 PLP-C${\beta}$와 PLP-C${\gamma}$가 독특한 유전자 구조를 갖고 있었다. 즉, PLP-C${\beta}$는 exon3의 alternative splicing에 의해 5개 혹은 6개의 exons을 갖는 two isoforms이 생긴다. 반면에 PLP-C${\gamma}$는 exon2가 alternative splcing이 되면서 7개의 exons을 갖거나 6개의 exons을 갖는 isoforms을 만든다. 그리고, PLP-C${\gamma}$의 promoter activity를 trophoblast Rcho-l${\gamma}$ 세포주를 이용하여 PLP-C${\gamma}$ 의 1.5 kb 5'-flanking 지역이 trophoblast-specific promoter activity를 갖고 있음을 밝혔다. PLP-C${\gamma}$ 유전자의 transcription start site는 Primer extension에 의해 밝혔다. 제 1차 년도의 연구결과를 토대로, 2차년에서는 다음단계의 연구를 수행하고자 한다. 즉, 1) mPsx2와 rPsx3의 promoter를 비교분석 함으로서 mouse와 rat에서 Psx 유전자가 다르게 조절되는 메카니즘 규명, 2) Psx와 PLP-C 유전자의 promoter에 있는 cis-acting elements 탐색, 3) Psx2와 Psx3의 단백질을 이용하여 이들이 binding하는 target sequence 규명, 4) 제작한 Psx2 targeting vector를 이용하여 ES cells에서 Psx2 유전자 knock-out, 5) Psx 유전자를 과발현시키는 세포주를 만들고 Psx에 의해 조절되는 유전자 탐색, 6) 새로 밝히 PLP-C members 유전자들의 조절기전을 Rcho-1 세포주를 이용하여 여러 거지 성장인자와 다른 호르몬에 대한 반응을 탐색, 7) Psx와 PLP-C${\gamma}$ 유전자의 chromosomal mapping 등을 밝힐 것이다.