한국구조물진단유지관리공학회 논문집 (Journal of the Korea institute for structural maintenance and inspection)

  • 제22권3호
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  • Pages.90-96
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  • 2018
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  • 2234-6937(pISSN)
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  • 2287-6979(eISSN)
한국구조물진단유지관리공학회 (Korea Institute for Structural Maintenance Inspection)
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스테인리스 스틸 슬래그 AOD 혼입 시멘트 페이스트의 탄산화 양생에 의한 공극특성

Pore Characteristics of Stainless Steel Slag AOD Blended Cement Pastes by Carbonation Curing

  • 황철성 (가천대학교 토목환경공학과) ;
  • 박경태 (가천대학교 토목환경공학과) ;
  • 최영철 (가천대학교 토목환경공학과)
  • 투고 : 2018.03.09
  • 심사 : 2018.04.26
  • 발행 : 2018.05.01
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초록

본 연구에서는 탄소 포집 물질인 ${\gamma}-C_2S$를 함유하고 있는 Stainless Steel Slag AOD를 포함한 시멘트 페이스트의 역학적 및 미세구조 변화를 연구하였다. ${\gamma}-C_2S$는 비수경성이며 그러므로 물과 반응하지 않는다. 그러나 ${\gamma}-C_2S$는 물에 의한 탄산화 양생조건에서 반응성을 가지고 있다. 그 반응은 페이스트 안의 공극을 치밀하게 형성하기 때문에 STS-A를 사용한 시멘트 페이스트의 공극구조는 탄산화 ($CO_2$ 농도는 약 5%)후에 수은압입시험에 의해 측정될 수 있다. 또한 Fractal 특성은 시멘트 페이스트의 미세구조변화는 탄산화 영향에 대하여 연구하였다. 그 결과로부터 STS-A를 포함하는 탄산화 시멘트 페이스트는 강도가 증가하였고 공극구조는 더 치밀해졌다.

In this study, the mechanical and micro-structural change of cement pastes incorporating Stainless-Steel Slag Argon Oxygen Decarburization Slag (STS-A) containing ${\gamma}-C_2S$ as a carbon capture materials were investigated with carbonation curing condition. ${\gamma}-C_2S$ is non-hydraulic, therefore does not react with water. But ${\gamma}-C_2S$ has a reactivity under carbonation curing condition with water. The reaction products fill up the pore in pastes. The microstructure of STS-A blended cement pastes could be densified by this reaction. The pore structure of cement pastes incorporating STS-A was measured using mercury intrusion porosimetry (MIP) after carbonation curing ($CO_2$ concentration is about 5%). Also the fractal characteristics were investigated for the effect of carbonation curing on the micro-structural change of paste specimens. From the results, the compressive strength of carbonated specimens incorporating STS-A increased and pore-structure of carbonated paste is more complicated.

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