• 한국지열·수열에너지학회논문집
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• 제13권2호
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• pp.9-15
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• 2017

When applying geothermal systems in cities such as seoul where high density development prevails, the selection of geothermal system capable of obtaining a large capacity in the limited grounds is necessary. In this study, an easy-to-use design tool is developed in the form of spreadsheet by applying the calculation theory of existing closed-loop vertical ground heat exchanger that can be used in the early design stage of the open-loop ground heat exchanger. By only using the maximum cooling and heating load, it is possible to calculate optimal design open-loop ground heat exchanger. Further research is needed, we are plan to improve the program considering the heat loss of groundwater flowing in the inner casing, G-Function for Open-Loop, and verification by applying actual projects.

• 유기물자원화
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• 제24권2호
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• pp.31-39
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• 2016

저수조는 유입/유출량의 시간적인 편차 때문에 필요하다. 저수조 용량 산정하기 위해서 공급(예, 강수) 누적 량과 요구(예, 관수) 누적 량의 차이를 사용한다. (-)와 (+)영역의 상관없이 누적 량 차의 절댓값 최대치가 되었을 때 용량의 산정이 이루어진다. 본 논문에서는, 온실 시설물의 강수와 관수를 이용하여 비선형적인 공급이나 요구량에서도 이를 적용하여 용량을 산정하였고, 비선형적인 변화가 커졌을 시에도 적용 할 수 있음을 증명하였다. 그리고 모니터링에 대한 시간 간격이 작아짐에 따라서, 저수조 용량이 증가되며, 강수량의 경우에는 약 10일을 변곡점으로 증가폭이 감소됨을 보인다.

• Transactions on Electrical and Electronic Materials
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• 제4권3호
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• pp.19-24
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• 2003

The experimental and simulation study of insulator failure by cement growth on suspended insulators (16,500kgf) for transmission line was discussed. To get more practical and analytic calculation results, the advanced program was used. This analysis tool was possible to calculate stress behaviors with mechanical loading when cement displacement happened. From simulation results, the. cement displacement changed with linear according to temperature. The shear stress was about $7 kgf/mm^2$ at $0.07\%$ displacement provided from $200^{\circ}C$, then it could be seen that the cement would be fractured even if $0.07\%$ displacement acted, because the cement had about $7-9 kgf/mm^2$ flexure strength. The curve patterns of shear stress with the increase of mechanical loading were changed at $0.02\%$ as a turning point, when the cement displacement was over $0.02\%$ the shear stresses decreased reversely with the increase of mechanical loading. From analysis on porcelain body it was known that there were enough margin to protect the fracture of porcelain body before the cement

• 한국안전학회지
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• 제21권6호
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• pp.38-45
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• 2006

Polymeric floorings mainly consisted of PVC are easily decomposed by many kinds of hot environmental factors, then generate hazardous asphyxiate gases and/or toxic gases etc. Therefore the mechanism of decomposition and quantitative toxic indices of products are very important for preventing safety and health disasters, especially in case of confined area. So we have investigated decomposition kinetics, numbers of process involved, toxicity indices of product and so on, using DSC, TGA, FT-IR and Pyrolyzer-GC/MS. The thermal decomposition process of polymeric floorings can be mainly divided by dehydrochlorinated reaction and polyene decomposition step, and activation energies of those are approximately $53.93{\sim}62.42kcal/mol$. Especially lethal concentration($LC_{50}$), fractional effective dose (FED) are calculated by measuring the amount of decomposition product. The values on $LC_{50}$ of sample G are ranged $2,003{\sim}2,019(mg/m^{3})$ in case of sample K and H are $1,877,\;1,998(g/m^{3})$ respectively. Even if the results are estimated by calculation method without animal test and/or clinical demonstration, these values could be very useful data for occupational health, hygiene and safety control.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3247-3251
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• 2010

Molecular structures of the various conformers for the four stereoisomers of tetra-t-butyl-tetra-O-methylsulfinylcalix[4]arene (1) were optimized using DFT BLYP and mPW1PW91/6-31G(d,p) (hybrid HF-DF) calculation methods. We have analyzed the total electronic and Gibbs free energies and normal vibrational frequencies of 16 different structures from four major conformations (cone (CONE), partial cone (PC), 1,2-alternate (1,2-A), 1,3-alternate (1,3-A)) of the four stereoisomers [1(rccc), 1(rcct), 1(rctt), 1(rtct)]. The mPW1PW91/6-31G(d,p) calculations suggested that the $1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, and $1(rtct)_{1,3-A}$ were the most stable conformations of the respective stereoisomers. These outcomes are in accordance with the experimental structures obtained from X-ray crystallography. The electrostatic repulsion between the sulfinyl and methoxy groups is a primary factor for the relative stabilities of the four different conformations. The IR spectra of the most stable conformers [$1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, $1(rtct)_{1,3-A}$] of each stereoisomer were compared to each other.

• 한국기후변화학회지
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• 제7권1호
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• pp.19-29
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• 2016

In this study, the emission intensity calculation method of GHGs was developed by considering the characteristics of the models and time series. The telematics device was installed on the car (OBD-II) to collect information on the operation conditions from each sample vehicle of public authorities. Based on emission intensity of GHGs, it presented a methodology of quantitative comparison of GHGs emission by vehicles. Collected driving information of vehicle was used for operating characteristics analysis of the target vehicle, and it was confirmed different operating characteristics through comparison of the results and previous study. GHGs emission intensity were analyzed considering characteristics of vehicle type by passenger car, van, cargo, and considering characteristics of the time series by summer, winter, and intermediate. From the analysis result, it was calculated GHGs emission intensity based on mileage ($g\;CO_2\;eq./km$) and operating time ($g\;CO_2\;eq./sec$).

• Nuclear Engineering and Technology
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• 제54권1호
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• pp.30-35
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• 2022

In a nuclear reactor, gamma radiation is the dominant energy deposition in non-fuel regions. Heat is generated upon gamma deposition and consequently affects the mechanical and thermal structure of the material. Therefore, the safety of samples should be carefully considered so that their integrity and quality can be retained. To evaluate relevant parameters, an in-core gamma thermometer (GT) was used to measure gamma heating (GH) throughout the operation of the McMaster nuclear reactor (MNR) at four irradiation sites. Additionally, a Monte Carlo reactor physics code (Serpent-2) was utilized to model the MNR with the GT located in the same irradiation sites used in the measurement to verify its predictions against measured GH. This research aids in the development of modeling, calculation, and prediction of the GH utilizing Serpent-2 as well as implementing a new GH measurement at the MNR core. After all uncertainties were quantified for both approaches, comparable GH profiles were observed between the measurements and calculations. In addition, the GH values found in the four sites represent a strong level of radiation based on the distance of the sample from the core. In this study, the maximum and minimum GH values were found at 0.32 ± 0.05 W/g and 0.15 ± 0.02 W/g, respectively, corresponding to 320 Sv/s and 150 Sv/s. These values are crucial to be considered whenever sample is planned to be irradiated inside the MNR core.

• 대한기계학회논문집B
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• 제32권8호
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• pp.604-611
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• 2008

Detailed analysis of NO formation routes and its contributions with strain rate in hydrogen/air flames were numerically investigated. LiG detailed reaction mechanism has been used for calculation, which is compared with experimental data in literature. It shows good agreement with experiment for both temperature and NO mole fraction. Three routes have been found important for NO formation in hydrogen flames. These are the Thermal route, NNH route and $N_2O$ route. Strain rate were varied to discuss the $EI_{NO}$ reduction trend in hydrogen nonpremixed flames, which are analyzed by each NO formation routes. As a result, as the strain rate increase, $EI_{NO}$ decrease sharply until strain rate $100s^{-1}$ and decrease slowly until strain rate $310s^{-1}$ again, after that $EI_{NO}$ keeps nearly constant. It can be identified that $EI_{NO}$ trend with the strain rate is well explained by a combination of variation of production rate of above Thermal, NNH and $N_2O$ route. Also result of Thermal-Mech. that includes only thermal NO reaction is compared with those of Full-Mech. As a result, It can be identified that there was difference between the two results of calculation. It is attributed to result that Thermal-mech did not consider contributions of NNH and $N_2O$ route. From these result, we can conclude that NOx emission characteristics of hydrogen nonpremixed flames should consider contributions of above three routes simultaneously.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.2889-2894
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• 2013

A new complex [$Ni(phen)(C_9H_8Br_2NO_3)_2{\cdot}2CH_3OH{\cdot}2H_2O$] [phen: 1,10-phenanthroline $C_9H_8Br_2NO_3$: 3,5-dibromo-L-tyrosine] was synthesized and characterized by IR, elemental analysis and single crystal X-ray diffraction. X-ray crystallography shows that Ni(II) ion is six-coordinated. The Ni(II) ion coordinates with four nitrogen atoms and two oxygen atoms from three ligands, forming a mononuclear Ni(II) complex. The crystal crystallizes in the Orthorhombic system, space group $P2_12_12$ with a = 12.9546 ${\AA}$, b = 14.9822 ${\AA}$, c = 9.9705 ${\AA}$, V = 1935.2 ${\AA}$, Z = 1, F(000) = 1008, S = 0.969, ${\rho}_{calcd}=1.742g{\cdot}cm^{-3}$, ${\mu}=4.688mm^{-1}$, $R_1$ = 0.0529 and $wR_2$ = 0.0738 for 3424 observed reflections (I > $2{\sigma}(I)$). Theoretical study of the title complex was carried out by density functional theory (DFT) method and the B3LYP method employing the $6-3l+G^*$ basis set. The energy gap between HOMO and LUMO indicates that this complex is prone to interact with DNA. CCDC: 908041.

• 한국방재학회 논문집
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• 제2권2호
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• pp.95-104
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• 2002

이 논문은 콘크리트 콘 파괴에 의해 지배될 때의 인장력의 예측과 Headed bar의 인발 파괴 양상을 보여준다. 1개의 다른 플레이트 형상과 세가지의 서로 다른 용접 방법에 따라 시험이 이루어졌다. 시험의 변수는 Headed plate에 연결된 철근의 직경(16mm, 19mm, 22mm), 형상(원형, 직사각형, 정사각형)과 head plate의 차원(면적, 두께), 철근과 head plate와의 연결을 위한 용접 방법(일반용접, 마찰용접)이다. Headed bar는 ASTM 970-98에 기초한 모양과 두께를 가진 다른 단면적으로 제조되었으며 콘크리트의 부착 길이는 CSA 23.3-94에 의거하여 산정되었다. 정적 인장하중이 적용되었으며 시험 인발 성능은 ACI-349와 CCD 방법과 같은 현재의 설계방법에 의해 산출된 값과 비교하였다. 실험결과와 기존식을 비교하면 Headed bar가 앵커와 달리 넓은 플레이트 면적과 이형철근으로 인해 기준식에 비해 높은 강도와 큰 파괴 반경을 나타내었다.