• Title/Summary/Keyword: Functional filler

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Effects of Sintering Additives on the Thermal and Mechanical Properties of AlN by Pressureless Sintering (상압소결 질화알루미늄의 소결 첨가제 변화에 따른 열적 및 기계적 특성)

  • Hwang, Jin Uk;Mun, So Youn;Nam, Sang Yong;Dow, Hwan Soo
    • Journal of Powder Materials
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    • v.26 no.5
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    • pp.395-404
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    • 2019
  • Aluminum nitride (AlN) has excellent electrical insulation property, high thermal conductivity, and a low thermal expansion coefficient; therefore, it is widely used as a heat sink, heat-conductive filler, and heat dissipation substrate. However, it is well known that the AlN-based materials have disadvantages such as low sinterability and poor mechanical properties. In this study, the effects of addition of various amounts (1-6 wt.%) of sintering additives $Y_2O_3$ and $Sm_2O_3$ on the thermal and mechanical properties of AlN samples pressureless sintered at $1850^{\circ}C$ in an $N_2$ atmosphere for a holding time of 2 h are examined. All AlN samples exhibit relative densities of more than 97%. It showed that the higher thermal conductivity as the $Y_2O_3$ content increased than the $Sm_2O_3$ additive, whereas all AlN samples exhibited higher mechanical properties as $Sm_2O_3$ content increased. The formation of secondary phases by reaction of $Y_2O_3$, $Sm_2O_3$ with oxygen from AlN lattice influenced the thermal and mechanical properties of AlN samples due to the reaction of the oxygen contents in AlN lattice.

Modern Paper Quality Control

  • Olavi Komppa
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.06a
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    • pp.16-23
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    • 2000
  • The increasing functional needs of top-quality printing papers and packaging paperboards, and especially the rapid developments in electronic printing processes and various computer printers during past few years, set new targets and requirements for modern paper quality. Most of these paper grades of today have relatively high filler content, are moderately or heavily calendered , and have many coating layers for the best appearance and performance. In practice, this means that many of the traditional quality assurance methods, mostly designed to measure papers made of pure. native pulp only, can not reliably (or at all) be used to analyze or rank the quality of modern papers. Hence, introduction of new measurement techniques is necessary to assure and further develop the paper quality today and in the future. Paper formation , i.e. small scale (millimeter scale) variation of basis weight, is the most important quality parameter of paper-making due to its influence on practically all the other quality properties of paper. The ideal paper would be completely uniform so that the basis weight of each small point (area) measured would be the same. In practice, of course, this is not possible because there always exists relatively large local variations in paper. However, these small scale basis weight variations are the major reason for many other quality problems, including calender blacking uneven coating result, uneven printing result, etc. The traditionally used visual inspection or optical measurement of the paper does not give us a reliable understanding of the material variations in the paper because in modern paper making process the optical behavior of paper is strongly affected by using e.g. fillers, dye or coating colors. Futhermore, the opacity (optical density) of the paper is changed at different process stages like wet pressing and calendering. The greatest advantage of using beta transmission method to measure paper formation is that it can be very reliably calibrated to measure true basis weight variation of all kinds of paper and board, independently on sample basis weight or paper grade. This gives us the possibility to measure, compare and judge papers made of different raw materials, different color, or even to measure heavily calendered, coated or printed papers. Scientific research of paper physics has shown that the orientation of the top layer (paper surface) fibers of the sheet paly the key role in paper curling and cockling , causing the typical practical problems (paper jam) with modern fax and copy machines, electronic printing , etc. On the other hand, the fiber orientation at the surface and middle layer of the sheet controls the bending stiffness of paperboard . Therefore, a reliable measurement of paper surface fiber orientation gives us a magnificent tool to investigate and predict paper curling and coclking tendency, and provides the necessary information to finetune, the manufacturing process for optimum quality. many papers, especially heavily calendered and coated grades, do resist liquid and gas penetration very much, bing beyond the measurement range of the traditional instruments or resulting invonveniently long measuring time per sample . The increased surface hardness and use of filler minerals and mechanical pulp make a reliable, nonleaking sample contact to the measurement head a challenge of its own. Paper surface coating causes, as expected, a layer which has completely different permeability characteristics compared to the other layer of the sheet. The latest developments in sensor technologies have made it possible to reliably measure gas flow in well controlled conditions, allowing us to investigate the gas penetration of open structures, such as cigarette paper, tissue or sack paper, and in the low permeability range analyze even fully greaseproof papers, silicon papers, heavily coated papers and boards or even detect defects in barrier coatings ! Even nitrogen or helium may be used as the gas, giving us completely new possibilities to rank the products or to find correlation to critical process or converting parameters. All the modern paper machines include many on-line measuring instruments which are used to give the necessary information for automatic process control systems. hence, the reliability of this information obtained from different sensors is vital for good optimizing and process stability. If any of these on-line sensors do not operate perfectly ass planned (having even small measurement error or malfunction ), the process control will set the machine to operate away from the optimum , resulting loss of profit or eventual problems in quality or runnability. To assure optimum operation of the paper machines, a novel quality assurance policy for the on-line measurements has been developed, including control procedures utilizing traceable, accredited standards for the best reliability and performance.

Effect of Interfacial Bonding on Piezoresistivity in Carbon Nanotube and Reduced Graphene Oxide Polymer Nanocomposites (탄소나노튜브 및 환원된 산화그래핀과 고분자간 계면결합력이 나노복합재의 압전 거동에 미치는 영향)

  • Hwang, Sang-Ha;Kim, Hyeon-Ju;Sung, Dae-Han;Jung, Yeong-Tae;Kang, Ku-Hyek;Park, Young-Bin
    • Journal of Adhesion and Interface
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    • v.13 no.3
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    • pp.137-144
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    • 2012
  • Chemical functionalization of carbon nanomaterials (CNMs) is generally carried out for increasing interfacial adhesion between filler and polymer matrix for CNM-polymer nanocomposites. The chemically functionalized CNTs can produce strong interfacial bonds with many polymers, allowing CNT based nanocomposites to possess high mechanical and functional properties. Hence, increased surface adhesion can be measured indirectly by observing increased mechanical properties. However, there is a more direct way to observe interfacial bonds between polymer and CNM by measuring piezoresistivity behavior so that we can imagine the behavior of CNM particles in polymer matrix under deflection. Fuctionalization of MWCNT and rGO was carried out by oxidization reaction of MWCNT and rGO with $H_2SO_4/HNO_3$ solution. Electrical resistivities of MWCNT-PMMA and rGO-PMMA composites were decreased after functionalization because of the destructive fuctionalization process. Meanwhile, piezoresistivities of functionalized CNM-PMMA composites showed more sensitive behavior under the same deflection as compared to pristine CNM-PMMA composites. Therefore, mobility of CNM in polymer matrix was found to be improved with chemical functionalization.

An Experimental Study on the Mechanical and Durability Properties of Ductile Cement Panel Used Vacuum Extrusion Molding (진공압출성형 고인성 시멘트 패널의 역학 및 내구특성에 관한 실험적 연구)

  • Rho, Hyoung-Nam;Lee, Jong-Suk;Han, Byung-Chan;Kwon, Young-Jin;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.473-476
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    • 2008
  • Due to the pursuit of high function and international price increase in the field of construction, the application of the secondary product using cement is on the increase gradually in the construction industry in the pursuit of economic cost reduction by the shortening of the construction time like Expediting and the dry construction method at the same time. However, it is in very urgent situation of measures to improve the structural performance or durable performance because it is limited for use in terms of panel in interior exterior building or functional repair reinforce as yet. Accordingly, this study is to investigate applicability of permanent Formwork like mould with the structural performance or excellent durable performance in the field of construction, and to derive optimum mixture in the performance and quality of manufacture. As a result of analysis comparison with the dynamic and durable properties of vacuum extrusion molding high toughness cement panel according to the mixture of four conditions, this study has found that the test body of mixing ECC-DP3 using small filler and large granulated blast furnace slag and powder flame retardant had excellent relative hardness and bending stress strain. The durable performance has shown excellent tendency by the decrease of porosity and enhancement of water-tightness.

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Investigation of the Electromechanical Response of Smart Ultra-high Performance Fiber Reinforced Concretes Under Flexural (휨하중을 받는 스마트 초고강도 섬유보강 콘크리트의 전기역학적 거동 조사)

  • Kim, Tae-Uk;Kim, Min-Kyoung;Kim, Dong-Joo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.57-65
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    • 2022
  • This study investigated the electromechanical response of smart ultra-high performance fiber reinforced concretes (S-UHPFRCs) under flexural loading to evaluate the self-sensing capacity of S-UHPFRCs in both tension and compression region. The electrical resistivity of S-UHPFRCs under flexural continuously changed even after first cracking due to the deflection-hardening behavior of S-UHPFRCs with the appearance of multiple microcracks. As the equivalent bending stress increased, the electrical resistivity of S-UHPFRCs decreased from 976.57 to 514.05 kΩ(47.0%) as the equivalent bending stress increased in compression region, and that did from 979.61 to 682.28 kΩ(30.4%) in tension region. The stress sensitivity coefficient of S-UHPFRCs in compression and tension region was 1.709 and 1.098 %/MPa, respectively. And, the deflection sensitivity coefficient of S-UHPFRCs in compression region(30.06 %/mm) was higher than that in tension region(19.72 %/mm). The initial deflection sensing capacity of S-UHPFRCs was almost 50% of each deflection sensitivity coefficient, and it was confirmed that it has an excellent sensing capacity for the initial deflection. Although both stress- and deflection-sensing capacity of S-UHPFRCs under flexural were higher in compression region than in tension region, S-UHPFRCs are sufficient as a self-sensing material to be applied to the construction field.

Electromechanical Properties of Smart Repair Materials based on Rapid Setting Cement Including Fine Steel Slag Aggregates (제강 슬래그 잔골재가 혼입된 초속경 시멘트 기반 스마트 보수재료의 전기역학적 특성)

  • Tae-Uk Kim;Min-Kyoung Kim;Dong-Joo Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.4
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    • pp.62-69
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    • 2023
  • This study investigated the electromechanical properties of cement based smart repair materials (SRMs) according to the different amounts of fine steel slag aggregates (FSSAs). SRMs can self-diagnose the quality of repairing and self-sense the damage of repaired zone. The replacement ratios of FSSAs to sand for SRMs were 0% (FSSA00), 25% (FSSA25), and 50% (FSSA50) by sand weight. The electrical resistivity of SRMs generally decreased as the compressive stress of SRMs increased: the electrical resistivity of FSSA25 at the age of 7 hours decreased from 78.16 to 63.68 kΩ-cm as the compressive stress increased from 0 to 22.37 MPa. As the replacement ratio of FSSAs by weight of sand increased from 0% to 25%, the stress sensitivity coefficient (SSC) of SRM at the age of 7 h increased from 0.471 to 0.828 %/MPa owing to the increased number of partially conductive paths in the SRMs. However, as the replacement ratio of FSSAs further increased up to 50%, the SSC decreased from 0.828 to 0.649 %/MPa because some of the partially conductive paths changed to continued conductive ones. SRMs are expected to self-sense the quality and future damage of repaired zone only by measuring the electrical resistivity of the repaired zone in addition to fast recovery in the mechanical resistance of structures.

CO2 Separation Performance of PEBAX Mixed Matrix Membrane Using PEI-GO@ZIF-8 as Filler (충진물로 PEI-GO@ZIF-8를 사용한 PEBAX 혼합막의 CO2 분리 성능)

  • Eun Sun Yi;Se Ryeong Hong;Hyun Kyung Lee
    • Membrane Journal
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    • v.33 no.1
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    • pp.23-33
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    • 2023
  • In this study, a mixed matrix membrane was prepared by varying the contents of PEI-GO@ZIF-8 synthesized in PEBAX 2533, and the permeation characteristics of N2 and CO2 were studied. The N2 permeability of the PEBAX/PEIGO@ZIF-8 mixed matrix membrane decreased as the PEI-GO@ZIF-8 content increased, and the CO2 permeability showed different trends depending on the PEI-GO@ZIF-8 content. The CO2 permeability increased in pure PEBAX membrane up to PEBAX/PEI-GO@ZIF-8 0.1 wt%, but decreased at the subsequent content. The PEI-GO@ZIF-8 0.1 wt% mixed matrix membrane had a CO2 permeability of 221.9 Barrer and a CO2/N2 selectivity of 60.0, showing the highest permeation properties with improved CO2 permeability and CO2/N2 selectivity among the prepared mixed matrix membrane and we obtained a result that reached the Robeson upper-bound. This is due to the -COOH, -O-, and -OH functional groups of GO and the amine group bonded to PEI, which interact friendly with CO2, and the effect of ZIF-8, which causes gate-opening for CO2 while the fillers are evenly dispersed in PEBAX.