• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.348-356
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• 2021

The lignocellulose-based dried watermelon rind (WR) was modified with sulfuric acid, namely SWR for enhancement of methylene blue (MB) adsorption from the aqueous solution. According to FT-IR analysis, after the modification of WR with sulfuric acid, the functional groups of R-SO₃H, COOH and -OH groups was formated or enhanced on the surface of the WR. Moreover, the point of zero charge (pHpzc) was changed from 6.3 to 4.1 after modification, which widened the range for adsorbing of cationic dye MB. The adsorption process of MB onto the SWR was suitable for pseudo-2nd-order and Langmuir model and the maximum adsorption capacity of Langmuir was found to be 334.45 mg/g at pH 7. In adition, the adsorption process occurs through the electrostatic interaction, hydrogen bridge formation, electron donor-acceptor relationship, and 𝜋-𝜋 electron dispersing force between functional groups on the carbon surface with MB molecules. Depending on functional groups available on the SWR surface, the MB adsorption mechanism can occur in combination with various interactions.

• Environmental Engineering Research
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• v.19 no.3
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• pp.247-253
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• 2014

The aim of this study was to characterize quintinite in fluoride removal from aqueous solutions, using batch experiments. Experimental results showed that the maximum adsorption capacity of fluoride to quintinite was 7.71 mg/g. The adsorption of fluoride to quintinite was not changed at pH 5-9, but decreased considerably in highly acidic (pH < 3) and alkaline (pH > 11) solution conditions. Kinetic model analysis showed that among the three models (pseudo-first-order, pseudo-second-order, and Elovich), the pseudo-second-order model was the most suitable for describing the kinetic data. From the nonlinear regression analysis, the pseudo-second-order parameter values were determined to be $q_e=0.18mg/g$ and $k_2=28.80g/mg/hr$. Equilibrium isotherm model analysis demonstrated that among the three models (Langmuir, Freundlich, and Redlich-Peterson), both the Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. The model analysis superimposed the Redlich-Peterson model fit on the Freundlich fit. The Freundlich model parameter values were determined from the nonlinear regression to be $K_F=0.20L/g$ and 1/n=0.51. This study demonstrated that quintinite could be used as an adsorbent for the removal of fluoride from aqueous solutions.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1998.04a
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• pp.465-472
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• 1998

In this study, analytic solution and finite element formulation for the free vibration analysis of thin-walled circular arch, based on linearized virtual work and Vlasov's assumption, including restrained warping effect and second order terms of finite semitangential rotations, is presented. The total potential energy is derived by applying the Hellinger-Reissner principle. In this formulation, all displacement parameters of deformation are defined at the centroid axis. For the finite element formulation, the two node cubic Hermitian polynomials are utilized as shape functions. In special case, potential energy functional of thin-walled curved beam with monosymmetric cross section is derived. From this methodology, analytic solution for the free vibration of monosymmetric circular arch with simply supported is derived. In order to illustrate the accuracy of this study, various parameter studies for free vibration of circular arches are presented and compared with numerical solution analyzed by the FEM using straight beam element.

• Corrosion Science and Technology
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• v.23 no.1
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• pp.20-32
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• 2024

Metal corrosion in acidic environments is a major issue in various industrial applications. This study evaluates the 4-piperonylideneaminoantipyrine (PPDAA) corrosion inhibition efficiency for mild steel in a hydrochloric acid (HCl) solution. The weight loss method was used to determine the corrosion inhibition efficiency at different concentrations and immersion time periods. Results revealed that the highest inhibition efficiency (94.3%) was achieved at 5 mM concentration after 5 hours of immersion time. To inspect the surface morphology of the inhibitor film on the mild steel surface, scanning electron microscopy (SEM) was used before and after immersion in 1.0 M HCl. Density functional theory (DFT) calculations were performed to investigate the molecular structure and electronic properties of the inhibitor molecule to understand the corrosion inhibition mechanism. Theoretical results showed that the inhibitor molecule can adsorb onto the mild steel surface through its nitrogen and oxygen atoms, forming a protective layer that prevents HCl corrosive attack. These findings highlight the potential of PPDAA as an effective corrosion inhibitor for mild steel in HCl solution. Moreover, combining experimental and theoretical approaches provides insights into the mechanism of corrosion inhibition, which is essential for developing effective strategies to prevent metal corrosion in acidic environments.

• 제어로봇시스템학회:학술대회논문집
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• 1994.10a
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• pp.289-292
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• 1994

In this paper, the equations of motion are constructed systematically for multibody systems containing closed kinematic loops. For the displacement analysis of the closed loops, we introduce a new mixed coordinates by adding to the reference coordinates, relative coordinates corresponding to the degrees of freedom of the system. The mixed coordinates makes easy derive the explicit closed form solution. The explicit functional relationship expressed in closed form is of great advantages in system dimension reduction and no need of an iterative scheme for the displacement analysis. This forms of equation are built up in the general purpose computer program for the kinematic and dynamic analysis of multiboty systems.

• Nonlinear Functional Analysis and Applications
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• v.28 no.3
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• pp.601-612
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• 2023

The existence of solution of the fractional order differential equations is very important mathematical field. Thus, in this work, we discuss, under some hypothesis, the existence of a positive solution for the nonlinear fourth order fractional boundary value problem which includes the p-Laplacian transform. The proposed method in the article is based on the fixed point theorem. More precisely, Krasnosilsky's theorem on a fixed point and some properties of the Green's function were used to study the existence of a solution for fourth order fractional boundary value problem. The main theoretical result of the paper is explained by example.

• Environmental Engineering Research
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• v.20 no.1
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• pp.73-78
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• 2015

The aim of this study was to examine the phosphate (P) removal by quintinite from aqueous solutions. Batch experiments were performed to examine the effects of reaction time, temperature, initial phosphate concentration, initial solution pH and stream water on the phosphate adsorption to quintinite. Kinetic, thermodynamic and equilibrium isotherm models were used to analyze the experimental data. Results showed that the maximum P adsorption capacity was 4.77 mgP/g under given conditions (initial P concentration = 2-20 mgP/L; adsorbent dose = 1.2 g/L; reaction time = 4 hr). Kinetic model analysis showed that the pseudo second-order model was the most suitable for describing the kinetic data. Thermodynamic analysis indicated that phosphate sorption to quintinite increased with increasing temperature from 15 to $45^{\circ}C$, indicating the spontaneous and endothermic nature of sorption process (${\Delta}H^0=487.08\;kJ/mol$; ${\Delta}S^0=1,696.12\;J/(K{\cdot}mol)$; ${\Delta}G^0=-1.67$ to -52.56 kJ/mol). Equilibrium isotherm analysis demonstrated that both Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. In the pH experiments, the phosphate adsorption to quintinite was not varied at pH 3.0-7.1 (1.50-1.55 mgP/g) but decreased considerably at a highly alkaline solution (0.70 mgP/g at pH 11.0). Results also indicated that under given conditions (initial P concentration=2 mgP/L; adsorbent dose=0.8 g/L; reaction time=4 hr), phosphate removal in the stream water (1.88 mgP/g) was lower than that in the synthetic solution (2.07 mgP/g), possibly due to the presence of anions such as (bi)carbonate and sulfate in the stream water.

• Steel and Composite Structures
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• v.49 no.6
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• pp.713-728
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• 2023

This paper aims to investigate the free vibration analysis of FG plates, taking into account the effects of even and uneven porosity. The study employs the Hellinger-Reisner functional and obtains the element's bending stress and membrane stress fields from the analytical solution of the governing equations of the thick plate and plane problem, respectively. The displacement field serves as the second independent field. While few articles on free vibration analysis of circular plates exist, this paper investigates the free vibration of both rectangular and circular plates. After validating the proposed element, the paper investigates the effects of porosity distributions on the natural frequency of the FG porous plate. The study calculates the natural frequency of thin and thick bending plates with different aspect ratios and support conditions for various porosity and volume fraction index values. The study uses three types of porosity distributions, X, V, and O, for the uneven porosity distribution case. For O and V porosity distribution modes, porosity has a minor effect on the natural frequency for both circular and rectangular plates. However, in the case of even porosity distribution or X porosity distribution, the effect of porosity on the natural frequency of circular and rectangular plates increases with an increase in the volume fraction index.

• Nonlinear Functional Analysis and Applications
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• v.26 no.5
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• pp.917-933
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• 2021

In this paper, we investigate the behavior and sensitivity analysis of a solution set for a parametric generalized multi-valued nonlinear quasi-variational inclusion problem in a real Hilbert space. For this study, we utilize the technique of resolvent operator and the property of a fixed-point set of a multi-valued contractive mapping. We also examine Lipschitz continuity of the solution set with respect to the parameter under some appropriate conditions.

• Korean Management Science Review
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• v.12 no.3
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• pp.135-161
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• 1995

This paper is concerned with a conceptual design of a knowledge-based modeler for network analysis. The "knowledge-based modeler" approach is suggested as a method for incorporating the user's qualitative knowledge and subjective decison in the course of the mathematical modeling and the subsequent solution procedure. The submodules of the proposed modeler such as database, model/algorithm base and functional knowledge bases are identified and the flows of information between the submodules are sequentially defined. A prototype system is implemented for experimental purpose by using the application software GURU.ware GURU.