• Carbon letters
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• v.28
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• pp.66-71
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• 2018

To improve the flame retardant performance of cellulose fibers, fluorine functional groups were introduced under various controlled fluorination conditions. The properties of the fluorinated cellulose fibers were analyzed by X-ray photoelectron spectroscopy and a thermogravimetric analysis. The fluorine functional group content in the fluorinated cellulose fibers increased with an increase in the fluorination temperature. However, the fluorination reaction increased the char yield and decreased the rate of degradation of the cellulose fibers by introducing donors, enabling the formation of a thick and compact char layer. Therefore, the flame retardant properties of cellulose fibers were improved following the fluorination treatment.

• Proceeding of EDISON Challenge
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• 2014.03a
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• pp.115-125
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• 2014

We investigate dissociation of diatomic molecules and anions using density functional theory (DFT) and density-corrected density functional theory (DC-DFT). We scan the potential energy curve of CH, NH and NO neutral molecule and its anion with both DFT and DC-DFT (in form of Hartree-Fock DFT, HF-DFT) using various functionals. Using CCSD(T) results as reference, we perform the error decomposition scheme recently proposed by Kim et al. The results show while most neutrals are $functio{\acute{n}}al$ error $domi{\bar{n}}ating$ normal calculations, $CH^-$ and $NO^-$ anions are density-driven error dominating abnormal calculations. In case of $NH^-$, traditional DFT goes to a wrong dissociation limit indicating abnormality, but both HF-DFT and CCSD(T) results need further investigation due to the kinks on the curve.

• Journal of Electrochemical Science and Technology
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• v.8 no.2
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• pp.162-168
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• 2017

$LiNi_xCo_yMn_zO_2$ cathode materials have been the focus of much attention because of their high specific capacity. However, because of the poor interfacial stability between cathodes and electrolytes, the cycling performance of these materials fades rapidly, especially at high temperatures. In the present paper, we propose the use of tris(trimethylsilyl) phosphate (TMSPO), which contains phosphate and silyl functional groups, as a functional additive in electrolytes. The addition of TMSPO resulted in the formation of cathode electrolyte interphase (CEI) layers on the surfaces of the cathodes and effectively suppressed electrolyte decomposition reactions, even at high temperatures. As a result, cells cycled with TMSPO exhibited remarkable capacity, which remained after 50 cycles (82.0%), compared to cells cycled without TMSPO (64.6%).

• Macromolecular Research
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• v.17 no.9
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• pp.697-702
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• 2009

Mesoporous ethanesilica thin film was prepared using PEO-PLGA-PEO triblock copolymers as structure-directing agents and (1,2-bis(triethoxysilyl) ethane BTESE; bridged organosilicates) as inorganic precursors via one-step sol-gel condensation of ethanesilica precursors. The mesostructure of ethanesilica films is critically dependent on the processing experimental parameters after the hydrolyzed silica sol mixture was spin-cast. This study examined the effects of the block copolymer template/organosilica precursor ratio in the casting solution and aging period before calcination of the mesostructure. It was further demonstrated that mesoscopic ordering of organosilicate thin films is induced by the rearrangement of block copolymer template/organosilica hybrid during thermal decomposition of the PEO-PLGA-PEO triblock copolymer. The mesoporous structure and morphology were characterized by SAXS, TEM and solid-state NMR measurement.

• Carbon letters
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• v.7 no.4
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• pp.277-281
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• 2006

In this study, in order to easily provide functional groups on the surface of carbon nanotubes, dual structural multiwalled carbon nanotubes which have crystalline graphite and turbostratic carbon wall were synthesized by modified vertical thermal decomposition method. Synthesized dual structural MWCNTs were characterized by FE-SEM, TGA, HR-TEM, Raman spectroscopy and BET specific surface area analyzer. The average innermost and outermost diameters of the synthesized nanotubes were around 45 and 75 nm, respectively. The large empty inner space and the presence of graphitic carbons on the surface may open potential applications for gas storage and collection of hazardous materials.

• 전기의세계
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• v.31 no.3
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• pp.209-217
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• 1982

This paper considers a finite spectrum assignment Problem for a functional retarded linear differential system with delays in control only. In this problem, by generalizing from an abstract linear system characterized by Semigroups on a Hilbert space to a finite dimensional linear system, we unify the relationship between a control-delayed system and its non-delayed system, and then by using the spectrum of the generator-decomposition of Semigroup, we try to get a feedback law which yields a finite spectrum of the closed-loop system, located at an arbitrarily preassigned sets of n points in the complex plane. The comparative examinations between the standard spectrum assignment method and the method of spectral projection for the feedback law which consists of proportional and finite interval terms over present and past values of control variables are also considered. The analysis is carry down to the elementary spectral projection level because, in spite of all the research efforts, so far there has been no significant attempt to obtain the feedback implementation directly from the abstract representation forms in the case of multivariables.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2603-2606
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• 2010

Novel soluble triazoleimide oligomers terminated with arylacetylene terminated were synthesized by the Cu(I)-catalysed 1,3-dipolar cycloaddition polymerization of diazides and imide-containing dialkyne. Several molecular weight triazoleimide oligomers were prepared from diazide and dialkyne monomers with different stoichiometric combinations. The curing behaviors of the oligomers were tested by differential scanning calorimetry (DSC). The thermal properties of the cured products were evaluated by DSC and thermogravimetric analysis (TGA). These cured oligomers showed the glass transition temperature of about $225-235^{\circ}C$ and the decomposition temperature (at 5% weight loss) of about $385-393^{\circ}C$ in nitrogen.

• Journal of the Korean Society of Tobacco Science
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• v.27 no.1 s.53
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• pp.59-67
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• 2005

Activated carbon fiber (ACF) was surface modified by nitric acid to improve the adsorption efficiency of the propylamine. The adsorption amount of propylamine of the modified ACF increased $17\%$ more than that of as-received ACF. Desorption of propylamine from the propylamine saturated ACF was occurred in two steps, the first step started arround $50^{\circ}C$ showing the desorption of physically adsorbed propylamine and the second step started at $200^{\circ}C$ showing the decomposition of chemically adsorbed propylamine. Total desorption amount of propylamine from the modified ACF was larger than that of the as-received ACF because of increased functional groups. The oxygen and nitrogen contents on the modified ACF increased by 1.5 and 3 times compared with the as-received ACF. A part of propylamine adsorbed on ACF formed pyridine-like or pyrrolic structures with 2 carbons exposed on the surface of the ACF. It was found that propylamine reacted with strong or weak acidic functional groups such as -COOH or -OH existed on ACF surface.

• Proceedings of the CALSEC Conference
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• 1997.11a
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• pp.263-268
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• 1997

Functional Modeling methodology, IDEF0 is widely used for modeling, analysis and description of enterprise system. The limitation of modeling components restricts applicability and give rise to confusion about model. In this paper, we propose new method to extend IDEF0. The first is adding modeling components which are semantic representations. In addition to ICOMs, we add the time and cost component which is required to execute the function. The second is tracing mechanism. When we need some information, we drive the functions related with the information by reverse tracing of the function which produces the information as a output and input. Through the tracing, we find out the bottleneck process or high cost process. Finally, we suggest the final decomposition level. We call the final decomposed function into unit function which has only one output data. We can combine and reconstruct some of functions because an unit function is similar to ‘lego block’. To reach the integrated system, the main problem to be solved is the integration of information produced by different functional subsystem. This can be resolved when the creation of data must be dependent on only one function. Through view integration of function output, we can guarantee the integrity of data.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.2 no.1
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• pp.13-17
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• 2001

The configuration design of kinematic mechanisms of industrial sewing machine has been studied using a functional approach. The configuration design methodology has been applied to shorten the development cycle time of mechanisms and to manage design data efficiently Expert system has been used to embody the decomposition of functional requirements. It has been interfaced with a CAD system through the API program to show the assembly and parts of the mechanism. Constraints also can be handled by the expert system through the rule induction and the case based reasoning process. The configuration design system includes the kinematical analysis and optimization of the mechanisms of an industrial sewing machine by the interface between the expert system and an analysis program by means of API Program supplied by expert system. The conceptual design of sewing machine mechanism can be Performed rapidly and efficiently.