• Environmental and Resource Economics Review
• /
• v.20 no.2
• /
• pp.309-333
• /
• 2011

Korea is one of the countries that propel new renewable energy industrialization actively in the context of change in this industrial structure. The previous government declared this kind of industrialization as a national goal in 2004 and the current government also supports this strategy. However, it is necessary to check whether this strategy is proper and effective. The reason is because solar, wind and fuel cells that have attracted public attention as the new growth engines cannot replace main industries yet. This paper tries to analyze the economic effects of new renewable energy industrialization by dividing them into production effect and job creation effect. The result of this analysis shows that solar energy is not effective at all, while wind energy is very effective in both production and job creation. In conclusion, this paper suggests that the government has to propel new renewable energy industrialization after consideration of these kinds of economic effects.

• Polymer(Korea)
• /
• v.35 no.1
• /
• pp.35-39
• /
• 2011

In this work, mesoporous carbons (CMK-3) were prepared by a conventional templating method using mesoporous silica (SBA-15) for using catalyst supports in polymer electrolyte membrane fuel cells (PEMFCs). The CMK-3 were chemically activated to obtain high surface area and small pore diameter with different potassium hydroxide (KOH) amounts, i.e., 0, 1, 3, and 4 g as an activating agent. And then Pt-Ru was deposited onto activated CMK-3 (K-CMK-3) by a chemical reduction method. The characteristics of Pt-Ru catalysts deposited onto K-CMK-3 were determined by surface area and pore size analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and inductive coupled plasma-mass spectrometry (ICP-MS). The electrochemical properties of Pt-Ru/K-CMK-3 catalysts were also analyzed by cyclic voltammetry (CV). From the results, the K3g-CMK-3 carbon supports activated with 3 g KOH showed the highest specific surface areas. In addition, the K3g-CMK-3 led to uniform dispersion of Pt-Ru onto K-CMK-3, resulted in the enhancement of elelctro-catalystic activity of Pt-Ru catalysts.

• Korean Chemical Engineering Research
• /
• v.49 no.6
• /
• pp.715-719
• /
• 2011

The $La_{0.7}Sr_{0.3}Cr_{1-x}Ni_{x}O_{3}$(LSCN-x) perovskites were prepared by citric acid and EDTA using a sol-gel method. The LSCN-x was characterized by BET, XRD, SEM, $H_2$-TPR, EA and TEM. The catalytic performance of LSCN-x catalysts in steam reforming of propane in the temperature range 600~$800^{\circ}C$ was investigated. Propane conversion and hydrogen yield increased with an increase in the amount of added Ni up to x=0.5 in the B-site, denoted as LSCN-0.5, under S/C=1 and S/C=1.7 reaction conditions. The LSCN-0.5 catalyst exhibited the best performance under Ni-substitution of which propane conversion and hydrogen yield was 100%, 95.9% at $800^{\circ}C$ in the S/C=1.7 condition, respectively. The morphology of carbon deposited on the catalysts after reaction exhibited filamentous carbon and amount of carbon deposited on the catalysts after reaction increased with an increase in the amount of added Ni.

• Korean Chemical Engineering Research
• /
• v.57 no.6
• /
• pp.768-773
• /
• 2019

The Fenton reaction, which evaluates the electrochemical durability of polymer membranes of polymer electrolyte fuel cells (PEMFC), and the degradation of polymer membranes by OCV holding method are compared. The Fenton reaction is a method that can evaluate the chemical durability of the polymer membrane at outside the cell in a shorter time than the OCV Holding method. The Fenton reaction was carried out at 30% hydrogen peroxide, 10 ppm iron, and $80^{\circ}C$ for 24 hours. OCV Holding was driven at $90^{\circ}C$, 30% relative humidity and OCV for 168 hours. The Fenton reaction caused a lot of degradation inside the polymer membrane. On the other hand, in OCV Holding, the membrane thickness was thinned by the entire surface and internal degradation. The fluorine emission rate was more than 10 times higher than that of OCV Holding due to the Fenton reaction. The hydrogen permeation rate increased about 30% at 24 hours of Fenton reaction. At OCV Holding, hydrogen permeability decreased after 24 hours and then increased. As a whole, there was a difference in a membranes deteriorated by Fenton reaction and OCV Holding.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.29 no.5
• /
• pp.187-191
• /
• 2019

Perovskite-type oxides have consistently attracted considerable attention for their applications in high-temperature electrochemical devices, such as electrolytes and electrodes of solid oxide fuel cells, oxygen permeating membranes and sensors etc. Among them, the electrical conductivity of 10 % Sr and 10 % Mg doped $LaAlO_3$ (LSAM9191) was measured using impedance spectroscopy and 4-probe d.c. method. Below $550^{\circ}C$, the grain boundary resistance mostly determined the overall conductivity; however, it nearly disappeared above $800^{\circ}C$. Using the defect model and curve fitting, the ionic and electronic conductivity contributions were also separated. In the temperature region where the sample resistance is mostly determined by the grain volume property, LSAM9191 was an oxygen ion conductor at low $Po_2$ and a mixed conductor at high $Po_2$. With increasing temperature, the ionic conduction region only slightly increased. Thus, LSAM9191 is a promising material as an oxygen ion conductor at high temperature and in low $Po_2$.

• Korean Chemical Engineering Research
• /
• v.57 no.3
• /
• pp.344-350
• /
• 2019

Durability is very important for the commercialization of membranes and electrode assemblies (MEA) developed for proton exchange membrane fuel cells (PEMFC). Durability evaluation of stationary PEMFC MEA has a problem that the voltage change rate should be measured for a long time over 1000 hours under constant current conditions. In this study, the electrochemical durability evaluation protocol of membranes (OCV holding method) using to vehicle MEAs was applied to the stationary MEA for the purpose of shortening the durability evaluation time. After operation of the stationary and automobile MEA for 168 hours under conditions of OCV, cathode oxygen, $90^{\circ}C$ and relative humidity of 30%, I-V, LSV, CV, impedance and FER were measured and compared. When the hydrogen permeability, OCV change, ionic conductivity, and fluorine flow rate, which represent the durability of the membrane after degradation, were all examined, it was shown that durability of stationary MEA membrane was better than that of vehicles MEA membrane. In addition, the electrode degradation of stationary MEA was smaller than that of vehicles MEA after degradation operation. It was possible to evaluate in a short time using automotive protocol that the durability of stationary MEA was superior that of vehicle MEA in terms of membrane and the electrode.

• Applied Chemistry for Engineering
• /
• v.22 no.3
• /
• pp.312-318
• /
• 2011

We have investigated the kinetics and catalytic activity of $CO_2$-lignite gasification with various metal precursors as catalysts. $K_2CO_3$, $Mn(NO_3)_2$, and $Ce(NO_3)_3$ were used and impregnated on a coal using an evaporator. The gasification experiments were carried out with the low rank coal loaded with 5 wt% catalyst at the temperature range from $700{\sim}900^{\circ}C$ and atmospheric pressure with the $N_2-CO_2$ reactant gas mixture. The catalytic effect on the gasification rate of the low rank coal with $CO_2$ was determined by the thermogravimetric analyzer. It was observed that the low rank coal reached the complete carbon conversion regardless of the kinds of catalysts at $900^{\circ}C$ from the results of TGA. The catalytic activity was ranked as 5 wt% $K_2CO_3$ > 5 wt% $Mn(NO_3)_2$ > 5 wt% $Ce(NO_3)_3$ > Non-catalyst at $900^{\circ}C$. The gasification rate increased with increasing the temperature. The activation energy of the catalytic gasification with 5 wt% $K_2CO_3$ was 119.0 kJ/mol, which was the lowest among all catalysts.

• Applied Chemistry for Engineering
• /
• v.22 no.3
• /
• pp.255-260
• /
• 2011

$NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina which is expected to an inorganic solid electrolyte of high temperature polymer electrolyte membrane fuel cells (PEMFC) was prepared by ion-exchange reaction of $K^{+}-{\beta}^{{\prime}{\prime}}$-alumina pellet with $NH_4NO_3$ aqueous solution and molten $NH_4NO_3$ salts as an ion-exchange medium in the autoclave and the heating mentle reaction. In the autoclave reaction, the concentrations of $NH_4NO_3$ solution was chosen at 5 and 10 M. Each ion-exchange reaction was carried out at 130, 150, 170, and $200^{\circ}C$ for 2, 4, 6 and 8 h. In the heating mentle reaction, ion-exchange was performed at $200^{\circ}C$ for 2, 4, 6 and 8 h with molten $NH_4NO_3$ salts. In order to determine the effect of reaction times, each ion-exchange reaction was repeated 3 times. The phase stability and the ion-exchange rate of $NH_4{^+}-{\beta}^{{\prime}{\prime}}$-alumina were analyzed by XRD and ICP.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
• /
• v.13 no.6
• /
• pp.556-561
• /
• 2020

The aging and declining agricultural population in the modern society requires improvement of the agricultural environment and is one of the representative problems. And since most of the work systems always require a transport work, the ratio of labor consumed in the transport work is very high. Accordingly, many types of transport vehicles are being developed and sold, and in the early days, most of them are powered transport vehicles using fossil fuels. However, it is paying attention to next-generation eco-friendly energy such as hydrogen, fuel cells, solar power, and bio due to the strengthening of international environmental regulations such as global warming and the Convention on Climate Change and the depletion of fossil fuels. Therefore, in this study, the ultimate goal is to develop an eco-friendly, easy-to-operate, safe agricultural electric vehicle that replaces fossil fuels. It was designed with a focus on controlling a wide range of vehicle speeds and securing stability of electric agricultural vehicles. Considering the performance and design, it is composed of a frame, a driving part, a steering part, and a controller system, and we are going to review and manufacture each part. It is believed that the manufactured electric vehicle for agriculture can be easily and conveniently operated in an agricultural society where young manpower is scarce, and can be helpful to the agricultural society through high efficiency.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.27 no.7
• /
• pp.1124-1128
• /
• 2021

As regulations of emissions from ships become more stringent, electric propulsion systems have been increasingly used to solve this problem in vessels ranging from large merchant ships to small and medium-sized ships. Methods for improving the efficiency of the electric propulsion system include the improvement of power sources; the use of a system linked to environmentally friendly power sources, such as batteries, fuel cells, and solar power; and the development of hardware and control methodology for rectifiers, power conversion devices, and propulsion motors. The method using a phase-shifting transformer with diodes has been widely used for rectification. Power semiconductor devices with grid connection to an environmentally friendly power source using DC distribution, a variable speed power source, and the application of small and medium-sized electric propulsion systems have been developed. Accordingly, the demand for active front-end (AFE) rectifiers is increasing. In this study, a method using a neural network rather than a conventional proportional-integral controller was proposed to control the AFE rectifier. Tested controller data were used to design a neural network controller trained through MATLAB/Simulink. The neural network controller was applied to a rectification system designed using PSIM software. The results indicated the effectiveness of improving the waveform and power factor DC output stage according to the load variation. The proposed system can be applied as a rectification system for small and medium-sized environmentally friendly ships.