Browse > Article
http://dx.doi.org/10.9713/kcer.2011.49.6.715

Study of Catalytic Performance of $La_{0.7}Sr_{0.3}Cr_{1-x}Ni_{x}O_{3}$ Perovskite for Steam Reforming of Propane  

Kim, Jae-Ro (Department of Hydrogen & Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
Kim, Nak-Hyeon (Department of Mineral & Resources Engineering, Chonbuk National University)
Sohn, Jung-Min (Department of Mineral & Resources Engineering, Chonbuk National University)
Publication Information
Korean Chemical Engineering Research / v.49, no.6, 2011 , pp. 715-719 More about this Journal
Abstract
The $La_{0.7}Sr_{0.3}Cr_{1-x}Ni_{x}O_{3}$(LSCN-x) perovskites were prepared by citric acid and EDTA using a sol-gel method. The LSCN-x was characterized by BET, XRD, SEM, $H_2$-TPR, EA and TEM. The catalytic performance of LSCN-x catalysts in steam reforming of propane in the temperature range 600~$800^{\circ}C$ was investigated. Propane conversion and hydrogen yield increased with an increase in the amount of added Ni up to x=0.5 in the B-site, denoted as LSCN-0.5, under S/C=1 and S/C=1.7 reaction conditions. The LSCN-0.5 catalyst exhibited the best performance under Ni-substitution of which propane conversion and hydrogen yield was 100%, 95.9% at $800^{\circ}C$ in the S/C=1.7 condition, respectively. The morphology of carbon deposited on the catalysts after reaction exhibited filamentous carbon and amount of carbon deposited on the catalysts after reaction increased with an increase in the amount of added Ni.
Keywords
Steam Reforming of Propane; Perovskite; Ni-Substitution; Carbon Deposition;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Ming, Q., Healey, T., Allen, L. and Irving, P., "Steam Reforming of Hydrocarbon fuels," Catal. Today, 77, 51(2002).   DOI   ScienceOn
2 Kikuchi, R., Iwasa, Y., Takeguchi, T. and Eguchi, K., "Partial Oxidation of $CH_{4}$ and $C_{3}H_{8}$ over Hexaaluminate-type Oxides," Appl. Catal. A: General, 281, 61(2005).   DOI   ScienceOn
3 Avci, A. K., Trimm, D. L. and Onsan, Z. I., "Quantitative Investigation of Catalytic Natural Gas Conversion for Hydrogen Fuel Cell Applications," Chem. Eng. J., 90(1-2), 77(2002).   DOI   ScienceOn
4 Kolios, G., Frauhammer, J. and Eigenberger, G., "Autothermal Fixed-bed Reactor Concepts", Chem. Eng. Sci., 55(24), 5945(2000).   DOI   ScienceOn
5 Takenaka, S., Orita, Y., Umebayashi, H., Matsune, H and Kishida, M., "High Resistance to Carbon Deposition of Silica-coated Ni Catalysts in Propane Stream Reforming," Appl. Catal. A:General, 351(2), 189(2008).   DOI   ScienceOn
6 Shiraga, M., Li, D., Atake, I., Shishido, T., Oumi, Y., Sano, T. and Takehira, K., "Partial Oxidation of Propane to Synthesis Gas over Noble Metals-promoted Ni/Mg(Al)O Catalysts-High Activity of Ru-Ni/Mg(Al)O Catalyst", Appl. Catal. A:General, 318, 143(2007).   DOI   ScienceOn
7 Urasaki, K., Tokunaga, K., Sekine, Y., Matsukata, M. and Kikuchi, E., "Production of Hydrogen by Steam Reforming of Ethanol over Cobalt and Nickel Catalysts Supported on Perovskitetype Oxides," Catal. Commun., 9(5), 600(2008).   DOI   ScienceOn
8 Urasaki, K., Sekine, Y., Kawabe, S., Kikuchi, E. and Matsukata, M., "Catalytic Activities and Coking Resistance of Ni/perovskites in Steam Reforming of Methane, " Appl. Catal. A., 286(1), 23(2005).   DOI   ScienceOn
9 Gallego, G. S., Mondragon, F., Barrault, J., Tatibouet, J. M. and Dupeyrat, C. B., "$CO_{2}$ Reforming of $CH_{4}$ over La-Ni Based Perovskite Precursors," Appl. Catal. A., 311, 164(2006).   DOI   ScienceOn
10 Mawdsley, J. R. and Krause, T. R., "Rare Earth-first-row Transition Metal Perovskites as Catalysts for the Autothermal Reforming of Hydrocarbon Fuels to Generate Hydrogen," Appl. Catal. A., 334, 311(2008).   DOI   ScienceOn
11 Mori, M., Hiei, Y. and Sammes, N. M., "Sintering Behavior of Ca- or Sr-doped $LaCrO_{3}$ Perovskites Including Second Phase of $AECrO_{4}$ (AE=Sr, Ca) in Air," Solid State Ionics, 135(1-4), 743 (2000).   DOI   ScienceOn
12 Mori, M., Hiei, Y. and Sammes, N. M., "Sintering Behavior and Mechanism of Sr-doped Lanthanum Chromites with A Site Excess Composition in Air," Solid State Ionics, 123(1-4), 103(1999).   DOI   ScienceOn
13 Barison, S., Battagliarin, M., Daolio, S., Fabrizio, M., Miorin, E., Antonucci, P. L., Candamano, S., Modafferi, V., Bauer, E. M., Bellitto, C. and Righini, G., "Novel $Au/La_{1-x}Sr_{x}MnO_{3}$ and $Au/La_{1-x}Sr_{x}CrO_{3}$ Composites: Catalytic Activity for Propane Partial Oxidation and Reforming," Solid State Ionics, 177(39-40), 3473 (2007).   DOI   ScienceOn
14 Pecchi, G., Reyes, P., Zamora, R., Cadus, L. E. and Fierro, J. L. G., "Effect of the Preparation Method on the Catalytic Activity of $La_{1-x}Ca_{x}FeO_{3}$ Perovskite-type Oxides," J. Solid State Chem., 181(4), 905(2008).   DOI   ScienceOn
15 Snoeck, J. W., Froment, G. F. and Fowles, M., "Filamentous Carbon Formation and Gasification: Thermodynamics, Driving Force, Nucleation, and Steady-state Growth", J. Catal., 169(1), 240(1997).   DOI   ScienceOn
16 Lima, S. M., Assaf, J. M., Pena, M. A. and Fierro, J. L. G., "Structural Features of $La_{1-x}Ce_{x}NiO_{3}$ Mixed Oxides and Performance for the Dry Reforming of Methane," Appl. Catal. A., 311, 94(2006).   DOI   ScienceOn
17 Valderrama, G., Goldwasser, M. R., de Navarro, C. U., Tatibouet, J. M., Barrault, J., Batiot-Dupeyrat, C. and Martinez, F., "Dry Reforming of Methane over Ni Perovskite Type Oxides," Catal. Today, 107-108, 785(2005).   DOI   ScienceOn
18 Sauvet, A. L. and Irvine, J. T. S., "Catalytic Activity for Steam Methane Reforming and Physical Characterisation of $La_{1-x}Sr_{x}Cr_{1-y}Ni_{y}O_{3-delta}$", Solid State Ionics, 167(1-2), 1(2004).   DOI   ScienceOn
19 Erri, P., Dinka, P. and Varma, A., "Novel Perovskite-based Catalysts for Autothermal JP-8 Fuel Reforming, " Chem. Eng. Sci., 61(16), 5328(2006).   DOI   ScienceOn
20 Guo, J., Lou, H., Zhu, Y. and Zheng, X., "La-based Perovskite Precursors Preparation and its Catalytic Activity for $CO_{2}$ Refonning of $CH_{4}$", Mater. Lett., 57(28), 4450(2003).   DOI   ScienceOn
21 Valderrama, G., Kiennemann, A. and Goldwasser, M. R., "Dry Reforming of $CH_{4}$ over Solid Solutions of $LaN_{1-x}Co_xO_{3}$", Catal. Today, 133, 142(2008).
22 Sfeir, J., Buffat, P. A., Mockli, P., Xanthopoulos, N., Vasquez, R., Mathieu, H. J., Van herle, J. and Thampi, K. R., "Lanthanum Chromite Based Catalysts for Oxidation of Methane Directly on SOFC Anodes", J. Catal., 202(2), 229(2001).   DOI   ScienceOn
23 Boukamp, B. A., "The Amazing Perovskite Anode," Nat. Mat., 2(5), 294(2003).   DOI   ScienceOn
24 Moon, J.-W., Lim, Y. H., Oh, Y.-K., Lee, M.-J., Choi, B.-H. and Hwang, H. J., "Polarization Resistance of $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ Air Electrode Synthesized by Glycine-Nitrate Process", J. Korean Ceram. Soc., 42(12), 800(2005).   DOI   ScienceOn
25 Yang, Y. J., Wen, T. L., Tu, H., Wang, D. Q. and Yang, J., "Characteristics of Lanthanum Strontium Chromite Prepared by Glycine Nitrate Process," Solid State Ionics, 135(1-4), 475(2000).   DOI   ScienceOn