• Title/Summary/Keyword: Forming Agent

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Improved Mesoporous Structure of High Surface Area Carbon Nanofiber for Electrical Double-Layer Capacitors

  • Lee, Young-Geun.;An, Geon-Hyoung;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.27 no.4
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    • pp.192-198
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    • 2017
  • Carbon nanofiber (CNF) is used as an electrode material for electrical double layer capacitors (EDLCs), and is being consistently researched to improve its electrochemical performance. However, CNF still faces important challenges due to the low mesopore volume, leading to a poor high-rate performance. In the present study, we prepared the unique architecture of the activated mesoporous CNF with a high specific surface area and high mesopore volume, which were successfully synthesized using PMMA as a pore-forming agent and the KOH activation. The activated mesoporous CNF was found to exhibit the high specific surface area of $703m^2g^{-1}$, total pore volume of $0.51cm^3g^{-1}$, average pore diameter of 2.9 nm, and high mesopore volume of 35.2 %. The activated mesoporous CNF also indicated the high specific capacitance of $143F\;g^{-1}$, high-rate performance, high energy density of $17.9-13.0W\;h\;kg^{-1}$, and excellent cycling stability. Therefore, this unique architecture with a high specific surface area and high mesopore volume provides profitable synergistic effects in terms of the increased electrical double-layer area and favorable ion diffusion at a high current density. Consequently, the activated mesoporous CNF is a promising candidate as an electrode material for high-performance EDLCs.

Formation of Coating Film on Rice Surface during Cooking and Artificial Coating Method with Glutinous Rice Powder (밥짓기 과정중 피막(皮膜) 형성(形成) 형상(現象)과 찹쌀분(粉) 첨가(添加)에 의한 피막층(皮膜層)의 보강(補强))

  • Lee, Seung-Ju;Chun, Jae-Kun
    • Applied Biological Chemistry
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    • v.29 no.3
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    • pp.241-247
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    • 1986
  • The relationship between rice and the fluid during cooking was investigated to examine the factors affecting the quality of cooked rice and a new rice cooking method was proposed to improve the unpalatability of aged Milyang 23-long grain rice variety. The changes of heights of rice-bed and the fluid during cooking were measured with a laboratory cooking apparatus made of flat bottomed graduated glass cylinder. Around the boiling, a sudden disappearance of the fluid was observed and then thin film was formed on the rice grains. This film coating was fortified by the addition of 1-2%(w/w) of glutinous rice powder as a film forming agent. The artificial coating on the cooked rice of low quality remarkably improved the gloss, moisture content and shape and the extent of leaching of rice solid into the fluid was reduced with the treatment.

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Polyclonal Antibody against Paenibacillus larvae and its Application (Paenibacillus larvae에 대한 다클론 항체 및 그 응용)

  • 백경찬;양옥순;정규회;윤병수
    • Korean journal of applied entomology
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    • v.41 no.1
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    • pp.49-53
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    • 2002
  • Paenibacillus larvae is a gram-positive, spore-forming bacterium that is etiological agent for american foulbrood disease (AFB), which is the most severe disease in honey bee. To detect P. larvae from infected honeybee-comb or larvae, polyclonal antibody against whole bacterium was produced from guineapig and its specificity was evaluated. After optimization of ELISA-based detection system using these antibodies, a number of different P. larvae strains were analysed. Polyclonal antibody against P. larvae ATCC 25747 showed high affinity to most strains of P. larvae including P. larvae. strain ATCC 9545 (type strain), ATCC 25747 and other korean strain, SJl5 but exhibited no cross-reaction with other bacterial species. Additionally, this type of ELISA system was used for the detection of AFB in field-application The results have shown that this antibody could be useful for the rapid identification and monitoring of P. larvae in honeybee-comb.

Anti-Corrosion Characteristics of Steel Structures with Polyaniline Anti-Corrosive Coatings (강 구조물에 대한 폴리아닐린 함유도료의 방청특성)

  • Song, Min-Kyung;Kong, Seung-Dae;Oh, Eun-Ha;Yoon, Hun-Cheol;Kim, Yoon-Shin;Im, Ho-Sub
    • Journal of Environmental Health Sciences
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    • v.36 no.3
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    • pp.236-246
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    • 2010
  • In preparative anti-corrosive coating experiments, polyaniline was obtained by reacting an oxidizing agent with the monomer aniline. Further, the primer coating was prepared using a variety of widely-used materials such as urethane resin. For the top coating, epoxy resin and acrylic urethane resin were used. Characteristics of the coatings were assessed according to KS and ASTM specifications, and the structure of the polyaniline was characterized using FT-IR and TGA. For analysis of anti-corrosive properties in salt-spray experiments, measurements of the oxidation state of iron and surface atomic analysis were conducted using XPS and SEM-EDX. Unlike general anti-corrosive coatings which exhibit anti-corrosive effects only as a primer coating, the anti-corrosive coatings using polyaniline as the anti-corrosive pigment showed a marked synergistic effect with the top coatings. In other words, the top coatings not only produce a fine view effect, but also increase, through interaction with the primer coatings, the resistance to diffusion of corrosive factors from the external environment. It was also found that, unlike the heavy metal oxide-forming layer of the passive barrier alone, the polyaniline anti-corrosive pigment oxidized iron at the interface with the iron substrate to form a passive barrier in the oxidic layer, and itself formed a potential barrier layer with anti-corrosive factors from the external environment. Although the passive layer was damaged, the damaged area did not become completely oxidized iron; on the contrary, it showed a tendency to reduction. This can be interpreted such that a passive layer is formed again on the damaged area, and that at the same time there is a tendency to self-healing.

Fusarium graminearum의 ZEB2 동형단백질에 의한 지랄레논 생합성 자가조절

  • Park, Ae Ran;Lee, Yin-Won
    • 한국균학회소식:학술대회논문집
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    • 2016.05a
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    • pp.27-27
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    • 2016
  • The ascomycete fungus Fusarium graminearum is the most common pathogen of Fusarium head blight (FHB), a devastating disease for major cereal crops worldwide. FHB causes significant crop losses by reducing grain yield and quality as well as contaminating cereals with trichothecenes and zearalenone (ZEA) that pose a serious threat to animal health and food safety. ZEA is a causative agent of hyperestrogenic syndrome in mammals and can result in reproductive disorders in farm animals. In F. graminearum, the ZEA biosynthetic cluster is composed of four genes, PKS4, PKS13, ZEB1, and ZEB2, which encode a reducing polyketide synthase, a nonreducing polyketide synthase, an isoamyl alcohol oxidase, and a transcription factor, respectively. Although it is known that ZEB2 primarily acts as a regulator of ZEA biosynthetic cluster genes, the mechanism underlying this regulation remains undetermined. In this study, two isoforms (ZEB2L and ZEB2S) from the ZEB2 gene in F. graminearum were characterized. It was revealed that ZEB2L contains a basic leucine zipper (bZIP) DNA-binding domain at the N-terminus, whereas ZEB2S is an N-terminally truncated form of ZEB2L that lacks the bZIP domain. Interestingly, ZEA triggered the induction of both ZEB2L and ZEB2S transcription. In ZEA producing condition, the expression of ZEB2S transcripts via alternative promoter usage was directly or indirectly initiated by ZEA. Physical interaction between ZEB2L and ZEB2L as well as between ZEB2L and ZEB2S was observed in the nucleus. The ZEB2S-ZEB2S interaction was detected in both the cytosol and the nucleus. ZEB2L-ZEB2L oligomers activated ZEA biosynthetic cluster genes, including ZEB2L. ZEB2S inhibited ZEB2L transcription by forming ZEB2L-ZEB2S heterodimers, which reduced the DNA-binding activity of ZEB2L. This study provides insight into the autoregulation of ZEB2 expression by alternative promoter usage and a feedback loop during ZEA production.

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Multilevel Precision-Based Rational Design of Chemical Inhibitors Targeting the Hydrophobic Cleft of Toxoplasma gondii Apical Membrane Antigen 1 (AMA1)

  • Vetrivel, Umashankar;Muralikumar, Shalini;Mahalakshmi, B;K, Lily Therese;HN, Madhavan;Alameen, Mohamed;Thirumudi, Indhuja
    • Genomics & Informatics
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    • v.14 no.2
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    • pp.53-61
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    • 2016
  • Toxoplasma gondii is an intracellular Apicomplexan parasite and a causative agent of toxoplasmosis in human. It causes encephalitis, uveitis, chorioretinitis, and congenital infection. T. gondii invades the host cell by forming a moving junction (MJ) complex. This complex formation is initiated by intermolecular interactions between the two secretory parasitic proteins-namely, apical membrane antigen 1 (AMA1) and rhoptry neck protein 2 (RON2) and is critically essential for the host invasion process. By this study, we propose two potential leads, NSC95522 and NSC179676 that can efficiently target the AMA1 hydrophobic cleft, which is a hotspot for targeting MJ complex formation. The proposed leads are the result of an exhaustive conformational search-based virtual screen with multilevel precision scoring of the docking affinities. These two compounds surpassed all the precision levels of docking and also the stringent post docking and cumulative molecular dynamics evaluations. Moreover, the backbone flexibility of hotspot residues in the hydrophobic cleft, which has been previously reported to be essential for accommodative binding of RON2 to AMA1, was also highly perturbed by these compounds. Furthermore, binding free energy calculations of these two compounds also revealed a significant affinity to AMA1. Machine learning approaches also predicted these two compounds to possess more relevant activities. Hence, these two leads, NSC95522 and NSC179676, may prove to be potential inhibitors targeting AMA1-RON2 complex formation towards combating toxoplasmosis.

Hepatoprotective Effect of Catechin Isolated from the Root of Rosa rugosa Thunb (해당화 뿌리에서 분리한 Catechin의 간보호효과)

  • Hur, Jong-Moon;Kim, In-Ho;Park, Jong-Cheol
    • Korean Journal of Medicinal Crop Science
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    • v.15 no.1
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    • pp.21-25
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    • 2007
  • The root of Rosa rugosa has been used in folkloric medicine as a treatment agent for diabetes. In the present study, we investigated whether (+)-catechin isolated from this plant can change the activities of hepatic drug metabolizing enzymes in rats treated with bromobenzene. Pretreatment with (+)-catechin gave no effects on the activities of aminopyrine N-demethylase and aniline hydroxylase, enzymes forming toxic bromobenzene epoxide intermediates and glutathione Stransferase, an enzyme removing toxic epoxides. However, the activity of epoxide hydrolase, an enzyme detoxifying the bromobenzene toxic intermediates was mildly recovered by (+)-catechin treatment.

Anodic Oxidation Behavior of AZ31 Magnesium Alloy in Aqueous Electrolyte Containing Various Na2CO3 Concentrations

  • Moon, Sungmo;Kim, Yeajin
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.331-338
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    • 2016
  • In this work, anodic oxidation behavior of AZ31 Mg alloy was studied as a function of $Na_2CO_3$ concentration in electrolyte by voltage-time curves and observation of surface appearances and morphologies after the anodic treatments, using optical microscopy and confocal scanning laser microscopy (CSLM). The voltage-time curves of AZ31 Mg alloy surface and surface appearances after the anodic treatments showed three different regions with $Na_2CO_3$ concentration : region I, below 0.2 M $Na_2CO_3$ where shiny surface with a number of small size pits; region II, between 0.4 M and 0.6 M $Na_2CO_3$ where dark surface with relatively low number of large size burned or dark spots; region III, more than 0.8 M $Na_2CO_3$ where bright surface with or without large size dark spots were obtained. The anodically treated AZ31 Mg alloy surface became significantly brightened with increasing $Na_2CO_3$ concentration from 0.5 M to 0.8 M which was attribute to the formation of denser and smoother surface films. Pits and porous protruding reaction products were found at relatively large size and small size spots, respectively, on the AZ31 Mg alloy surface in low concentration of $Na_2CO_3$ less than 0.2 M. The formation of pits is attributed to the result of repetition of the formation and detachment of porous anodic reaction products. Based on the experimental results obtained in this work, it is concluded that more uniform, denser and smoother surface of AZ31 Mg alloy could be obtained at more than 0.8 M $Na_2CO_3$ concentration if there is no other oxide forming agent.

Achieving and Reasoning about Common Beliefs based on Social Networking Services: on the Group Chatting Model of KakaoTalk (소셜 네트워크에서 공통믿음의 형성과 추론: 카카오톡 채팅방을 중심으로)

  • Kim, Koono
    • Journal of the Korean Institute of Intelligent Systems
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    • v.27 no.1
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    • pp.7-14
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    • 2017
  • Theoretically, it is known that common beliefs and/or common knowledge cannot be attained in asynchronously distributed multiagent environments, however, it show that some propositions with deadlines can be attained as common beliefs among a set of fully trusted agents even when they communicate to each other asynchronously. Generally, in the multiagent environment, the attainment of common beliefs is approached as a problem of communication, and for the common beliefs paradox that the common beliefs is not attained on a system without communication time restriction is applied to loose coarser granularity and it prove that forming common beliefs is possible by relaxing necessary requirements through the KakaoTalk chatting model. I also experimented with the reasoning function that confirms the common beliefs by inquiring about the common belief generated by implementing the inference function in each agent of the KakaoTalk chatting model. Through utilizing metalogic programming, a formalization of the presentation and reasoning of common beliefs has been achieved, and the group chatting model of KakaoTalk was adopted in experiments to show that common beliefs can be formed among distributed agents using asynchronous communication.

Effects of Porosity on Durability in a Porous Nozzle for Continuous Casting (연속주조용 Porous Nozzle의 기공율이 내구성에 미치는 영향)

  • Yoon, Sanghyeon;Cho, Mun-Kyu;Jeong, Doo Hoa;Lee, Heesoo
    • Korean Journal of Metals and Materials
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    • v.48 no.7
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    • pp.625-629
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    • 2010
  • This study investigates the effects of porosity on the thermal stability and the thermal shock resistance of a porous nozzle used for blowing an inert gas. The samples of $Al_2O_3-SiO_2-ZrO_2$ system, which had the apparent porosity of 16~30% and bulk density of $2.6{\sim}3.2g/cm^3$, were prepared by adding different graphite contents (5, 10, 20 wt%) as a pore-forming agent. The thermal shock test was conducted at ${\Delta}T=500$, 1000, and $1400^{\circ}C$ also and the thermal stability was also carried out at 1550, 1600, and $1650^{\circ}C$ for 5 hrs. The specimen contained 10 wt% graphite had uniform pore size distribution, whereas the specimen with 20 wt% graphite showed non-uniform pore size distribution. As a result of thermal shock test, the specimen containing 10 wt% graphite appears to have higher mechanical strength than the other specimens (5, 20 wt% graphite). Both the 5 wt% and 20 wt% graphite specimens developed a non-uniform pore size distribution and cracks that were generated by intensive thermal stress.