• Title/Summary/Keyword: Formation free energy

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Ultra-shallow Junction with Elevated SiCe Source/ Drain fabricated by Laser Induced Atomic Layer Doping (레이저 유도 원자층 도핑(Ll-ALD)법으로 성장시킨 SiGe 소스/드레인 얕은 접합 형성)

  • 장원수;정은식;배지철;이용재
    • Proceedings of the IEEK Conference
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    • 2002.06b
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    • pp.29-32
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    • 2002
  • This paper describes a novel structure of NMOSFET with elevated SiGe source/drain region and ultra-shallow source/drain extension(SDE)region. A new ultra-shallow junction formation technology. Which is based on damage-free process for rcplacing of low energy ion implantation, is realized using ultra-high vacuum chemical vapor deposition(UHVCVD) and excimer laser annealing(ELA).

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Natural gas hydrates in the eastern deep-water Ulleung Basin (동부 심해 울릉분지의 천연가스 하이드레이트)

  • Ryu, Byong-Jae;Kim, Ji-Hoon;Chung, Bu-Heung;Lee, Young-Joo
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.610-612
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    • 2008
  • Piston cores retrieved from the eastern part of the deep-water Ulleung Basin were analyzed to access the potential of hydrocarbon gas generation and natural gas hydrate (NGH) formation. Seismic data acquired in the study area were also analyzed to determine the presence of hydrocarbon gas and/or NGH, and to map their distribution. Core analyses revealed high total organic carbon (TOC) contents which favor hydrocarbon generation. The cores recovered from the southern study area showed the sufficient residual hydrocarbon gas concentrations for the formation of significant NGH. These cores also showed the cracks developed parallel to the bedding that suggest significant gas content in situ. A number of seismic blanking zones were observed on seismic data. They are identified as vertical to sub-vertical chimneys caused by the upward migration of pore fluid or gas, and containing of free gas and/or NGH. Often, they are associated with velocity pull-up structures that are interpreted to be the result of high-velocity NGH. The seismic data also showed several bottom-simulating reflectors (BSRs) that are associated with overlying NGH and underlying free gas. The distribution of blanking zones and BSRs would be impacted by the lateral differences of upward methane fluxes.

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Evaluation of the applicability of a buoyancy-modified turbulence model for free surface flow analysis based on the VOF method (VOF 기반 자유수면 흐름 해석을 위한 부력 수정 난류 모형의 적용성 평가)

  • Lee, Du Hana
    • Journal of Korea Water Resources Association
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    • v.57 no.8
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    • pp.493-507
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    • 2024
  • RANS-based CFD analysis is widely applied in various engineering fields, including practical hydraulic engineering, due to its high computational efficiency. However, problems of non-physical behavior in the analysis of two phase flow, such as free surfaces, have long been raised. The two-equation turbulence models used in general RANS-based analysis were developed for single phase flow and simulate unrealistically high turbulence energy at the interface where there are abrupt changes in fluid density. To solve this issue, one of the methods recently developed is the buoyancy-modified turbulence model, which has been partially validated in coastal engineering, but has not been applied to open channel flows. In this study, the applicability of the buoyancy-modified turbulence model is evaluated using the VOF method in the open-source program OpenFoam. The results of the uniform flow showed that both the buoyancy-modified k-𝜖 model and the buoyancy-modified k-ω SST model effectively simulated the reduction of turbulence energy near the free surface. Specifically, the buoyancy-modified k-ω SST model accurately simulated the vertical velocity distribution. Additionally, the model is applied to dam-break flows to examine cases with significant surface variation and cavity formation. The simulation results show that the buoyancy-modified turbulence models produce varying results depending on the VOF method and shows non-physical behavior different from experimental results. While the buoyancy-modified turbulence model is applicable in cases with stable surface shapes, it still has limitations in general application when there are rapid changes in the free surface. It is concluded that appropriate adjustments to the turbulence model are necessary for flows with rapid surface changes or cavity formation.

Observation of carbon sedimentation effect and soot concentration in diesel engine after intake valve modification

  • Mahmud, Md. Iqbal;Cho, Haeng Muk
    • Journal of Energy Engineering
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    • v.21 no.4
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    • pp.378-384
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    • 2012
  • Higher compression ratio is required in diesel engine to ignite the fuel that leads to better efficiency. For complete combustion inside the cylinder it is important to ensure the clean air flow with free of debris and as cool as possible. In this manner, modification of intake valve arrangements is taken in to consideration importantly. In this paper, the intake valve arrangements are modified with newly designed valve mixer. It causes swirl flow of air through the intake port that mixing with the fuel followed by complete combustion. The use of valve mixer reduces the carbon sediment formation on valve fillet and its face area as the carbon particles gradually take place on it after certain running period. It therefore, helps to increase the valve lifetime. And at the same time it reduces the exhaust elements i.e. soot from the automobiles to a significant level.

Magneto-optical Measurements of Semiconductor Quantum Structures in Pulsed-magnetic Fields

  • Kim, Yongmin
    • Applied Science and Convergence Technology
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    • v.23 no.1
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    • pp.1-13
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    • 2014
  • Semiconductor quantum structures are often characterized by their energy gaps which are modified by the quantum size effect. Energy levels in semiconductors can be realized by optical transitions within confined structures. Photoluminescence spectroscopy in magnetic fields at low temperatures has proved to be a powerful technique for investigating the electronic states of quantum semiconductor heterostructures and offers a complimentary tool to electrical transport studies. In this review, we examine comprehensive investigations of magneto-excitonic and Landau transitions in a large variety of undoped and doped quantum-well structures. Strong magnetic fields change the diamagnetic energy shift of free excitons from quadratic to linear in B in undoped single quantum well samples. Two-dimensional electron gas induced by modulation doping shows pronounce quantum oscillations in integer quantum Hall regime and discontinuous transition at ${\nu}=1$. Such discontinuous transition can be explained as the formation of spin waves or Skyrmions.

Surface Characterization of Zinc Selenide Thin Films Obtained by RF co-sputtering

  • Lee, Seokhee;Kang, Jisoo;Park, Juyun;Kang, Yong-Cheol
    • Journal of the Korean Chemical Society
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    • v.66 no.5
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    • pp.341-348
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    • 2022
  • In this work, radio frequency magnetron sputtering was used to deposit zinc selenide thin films on p-type silicon (100) wafers and glass substrates in a high vacuum chamber. Several surface characterization instruments were implemented to study the thin films. X-ray photoelectron spectroscopy results revealed that oxidized Zn bound to Se (Zn-Se) at 1022.7 ± 0.1 eV becomes the dominant oxidized species when Se concentration exceeds 70%. Scanning electron microscopy coupled with energy dispersive spectroscopy showed that incorporating Se in Zn thin films will lead to formation of ZnSe grains on the surface. Contact angle measurements indicated that ZnSe-60 exhibited the lowest total surface free energy value of 24.94 mN/m. Lastly, ultraviolet-visible spectrophotometry and ultraviolet photoelectron spectroscopy data evinced that the energy band gap gradually increases with increasing Se concentration with ZnSe-70 having the highest work function value of 4.91 eV.

Effect of Aflatoxin on the Growth of Bacillus megaterium (Aflatoxin이 Bacillus megaterium의 생육(生育)에 미치는 영향)

  • Choi, Eon-Ho;Lee, Kwan-Young;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.8 no.1
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    • pp.47-52
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    • 1976
  • Growth inhibition and morphological alteration of Bacillus megaterium NRRL B-1368 in aflatoxin-containing TGY liquid media and its growth restoration in normal media were investigated. Crude aflatoxins $(B_1\;22.7%,\;B_2\;1.6%,\;G_1\;3.6\;%\;and\;G_2\;0.2%)$ at concentrations of more than $20{\mu}g/ml$ inhibited the growth of the microorganism and prevented the formation of septum, resulting in abnormal elongation and disturbance of cell division. The aberrant cells, however, grew normally by septum formation and cell division upon returning to aflatoxin-free culture media. It was, therefore, assumed that aflatoxin affects the function of mesosome related to septum formation in bacteria.

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Degradation of Anthracene by a Pseudomonas strain, NGK1

  • Shinde Manohar;Kim, Chi-Kyung;Tim
    • Journal of Microbiology
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    • v.37 no.2
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    • pp.73-79
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    • 1999
  • Pseudomonas sp. NGK1, isolated by naphthalene enrichment culture technique, is capable of degrading anthracene as a sole source of carbon and energy. The organism degraded anthracene through the intermediate formation of 1,2-dihydroxyanthracene, 2-hydroxy-3-naphthoic acid, salicylate, and catechol. The intermediates were isolated and characterized by TLC, spectrophotometry, and HPLC analysis. The cell free extract of anthracene-grown cells showed activities of anthracene dioxygenase, 2-hydroxy-3-naphthylaldehyde dehydrogenae, 2-hydroxy-3-naphthoate hydroxylase, salicylate hydroxylase and catechol 2,3-dioxygenase. The formed catechol as a metabolite is degraded through meta-cleavage with the formation of ${\alpha}$-hydroxymuconic semi-aldehyde.

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Effects of Wicking on Solder Joint Profile in Gullwing Lead (워킹이 Gullwing 리드의 솔더 접합부 형상에 미치는 영향)

  • 최동필;유중돈;이태수;최상균
    • Journal of Welding and Joining
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    • v.16 no.4
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    • pp.117-124
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    • 1998
  • During the reflow process in SMT, the molten solder has been observed to move upward and solidify along the gullwing lead, which is called the wicking phenomenon. In this paper, possible causes of the wicking are investigated, and its effects on the solder joint profile are quantitatively estimated by introducing the wicking constant. The free energy reduction by intermetallic formation between the copper and tin seems to be the major source of wicking action. The joint profiles of the gullwing lead are calculated using the previous finite element formulation incorporated with the wicking constant. The calculated results show reasonably good agreements with the experimental data when the wicking effects are considered.

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Thermodynamics of Metal Chelate Formation of 8-Hydroxyquinoline-5-Sulfonic Acid (8-Hydroxyquinoline-5-Sulfonic Acid의 금속킬레이트 생성에 관한 열역학적 고찰)

  • Kun Moo LEE
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.5-8
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    • 1969
  • Acid dissociation constants and chelate stability constants of 8-hydroxyquinoline-5-sulfonic acid have been determined for divalent metal ions. Co (Ⅱ), Ni (Ⅱ) and Zn (Ⅱ) by means of the Calvin-Bjerrum technique at the various temperatures. The standard free energy changes for the reactions at $20^{\circ}$, $30^{\circ}$, $40^{\circ}$and $50^{\circ}C$ were calculated, and the corresponding values of ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ applying over this temperature range are reported. The results are interpreted on the basis of current theories of metal chelate formation in aqueous solution.

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