• Title/Summary/Keyword: Formaldehyde adsorption

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The Effects of Humidity Control Capability and Removal Toxic Gases of Activated Carbon to the Display Environment of Cultural Properties (문화재 전시 공간에 대한 활성탄의 습도 제어 및 유해가스 제거 효과 연구)

  • Kang, Sae Rom;Choi, Yu Ri;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.30 no.2
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    • pp.235-241
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    • 2014
  • In this study, we are trying to verify humidity control capability of the exhibition environment of cultural property by measuring adsorption and desorption performance, the control ability of harmful substances by the adsorption experiments of harmful gases. In the experiment of adsorption and desorption performance, in the low humidity area, Artsorb desorbed overwhelmingly more than activated carbon whereas activated carbon absorbed more. Adsorption speed was faster slightly in Artsorb absorption speed was similar in both. In the middle humidity area, absorption by artsorb was slightly more and desorption was similar in both so characteristic of Artsorb didn't appear. Also, Adsorption speed was faster in activated carbon but in the process of desorption, the speed of Artsorb was faster. In adsorption experiment of harmful substances, the concentration in the environment with activated carbon was lower than one with Artsorb, but the difference appeared small. And as a result of observation of the difference in concentration due to adsorption of harmful gas by the change in the metal specimen, the most change was shown in lead specimen and the color difference between the lead specimens of the activated carbon and Artsorb appeared greatly.

A Study on the Characteristics of a Pt/TiO2 Catalyst Prepared by Liquid-Phase Ruduction for Formaldehyde Oxidation at Room Temperature (액상환원 기반 Pt/TiO2 촉매 제조를 이용한 포름알데히드 상온 산화 반응 특성 연구)

  • Jae Heon Kim;Younghee Jang;Geo Jong Kim;Sung Chul Kim;Sung Su Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.612-618
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    • 2023
  • Modern society spends more than 80% of its daily life indoors, emphasizing the need for attention to indoor air pollution due to the improvement in living standards. In this study, the performance and reaction characteristics of the Pt/TiO2 catalysts prepared by liquid-phase reduction for the removal of formaldehyde (HCHO), one of the indoor air pollutants, at room temperature without the need for additional light or heat were investigated. As a result, it showed that catalysts prepared by the same method showed approximately 40~80% various activities depending on the type of TiO2. XRD, BET, and XPS analyses were performed to investigate the particle size, crystal structure, specific surface area, and O/Ti molar ratio of the support material, and it revealed that the correlation between the properties and performance was insignificant. To explore the oxidation reaction pathway of formaldehyde (HCHO), in situ DRIFT analysis using carbon monoxide and H2-TPR was perfomed. The results revealed that the performance was demonstrated by the oxidation state of the active metal and the adsorption-desorption characteristics of the adsorbate species.

Micro Porous Clay Mineral Absorption / Desorption Moisture-Proof Performance of The Atmospheric Humidity and Decomposing The Polyamide Adsorption Performance Characterization of Formaldehyde (미세 다공질 광물과 아미드계 분해제의 적용을 통한 건축자재의 습도 조절과 폼알데히드 분해 성능 특성 평가)

  • Lee, Che Cheol;Kim, Yun Hwan;Yun, Seng Hee
    • KIEAE Journal
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    • v.14 no.3
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    • pp.105-109
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    • 2014
  • The recent rising living standards, environment-friendly, well-being and health aspects of life in the basic gratification, as well as the desire for a pleasant environment emotionally environmentally friendly way of external space or industrial interest in the indoor environment, the manifestation. In particular, the biggest problem of the indoor environment has been emerged as a Sick House Syndrome indoor space that is provided to the building materials, and the impact on the domestic and the indoor environment, and clean the house in a health standards are specified as laws. The performance rating and the various materials to create environmentally-friendly standards for building materials. The more detail, Porous clay material, toxic substances released by applying the high humidity and the water itself, and to absorb the moisture, if the emissions, without a separate device, to maintain a comfortable indoor environment and at the same time, one of the causes of Sick House Syndrome breaking down harmful substances to absorb a comfortable indoor environment to maintain an environmentally-friendly building interior material studies. It is aimed at the development to multi-functional high performance eco-friendly construction materials, rather than through one feature performance, identify key features for national and international eco-friendly building materials can exert Water Vapour Adsorption raw, decomposed materials for the application and selection.

Synthesis of 8-HQR and 8-HQRS Chelate Resins and It's Ion Exchange Properties (8-HQR 및 8-HQRS 킬레이트 수지의 합성과 그의 이온교환 성질)

  • Dong Won Kim;Kong Soo Kim;Hong Soo Kim
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.69-75
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    • 1986
  • 8-Hydroxyquinoline-resorcinol(8-HQR) and 8-hydroxyquinoline-resorcinol-salicylic acid (8-HQRS) chelate resins were prepared by the condensation reaction of 8-hydroxyquinoline, or 8-hydroxyquinoline-salicylic acid, in the presence of resorcinol with formaldehyde. The ion exchange capacities of 8-HQR and 8-HQRS resins were 4.1 meq/g and 5.4 meq/g, respectively. The adsorption and distribution coefficient of metal ions, such as Fe(III), Cu(II), Pb(II), Co(II) and Ni(II) on these resins were discussed. The adsorption of metal ions on these chelate resins showed that the maximum adsorption condition is pH 7. And the distribution coefficient of metal ions on these resins was increased with decreasing of hydrochloric acid concentration.

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Synthesis of CHBM-DVB Ion Exchanger and It's Ion Exchange Behavior (CHBM-DVB 이온교환체의 합성과 그의 이온교환작용)

  • Dong Won Kim;Kong Soo Kim;Nam Kee Lee
    • Journal of the Korean Chemical Society
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    • v.29 no.2
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    • pp.164-171
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    • 1985
  • The salicylic acid-formaldehyde condensed copolymer (SAF) and the 3-carboxy-4-hydroxy benzyl methacrylate divinylbenzene copolymer (CHBM-DVB) were synthesized. The capacities of SAF and CHBM-DVB ion exchangers were 4.6meq/g and 3.9 meq/g, respectively. The adsorption of several heavy metal ions on these weakly acidic ion exchangers and the property of ion exchanger were discussed. The distribution coefficients in hydrochloric acid solution and the elution behavior of several heavy metal ions were also discussed.

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Development of SPR Gas Sensor for Small Molecules Using Molecularly Imprinted Polymer Thin Films

  • Jang, Seong-U;Jin, Seong-Il;Park, Chan-Ryang
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.242.2-242.2
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    • 2011
  • Molecularly imprinted polymer thin films were applied to develop a gas sensor based on the surface plasmon resonance phenomenon for small gaseous molecules such as toluene and xylene. The imprinted polymer films were synthesized via photo-polymerization method using various combination of templates, functional monomers and cross-linkers. The temperature of pre-polymerization solutions and the power of UV light were controlled for optimized performance of gas sensing. The morphology and porosity of the polymer films were controlled by varying the mixing ratios of the pre-polymerization solutions and confirmed by atomic force microscopy. By fitting the adsorption/desorption sensorgrams to conventional kinetic models, the effects of different templates and cross-linkers were interpreted in term of the structural differences of the polymer networks formed on the gold film. The sensitivity and selectivity of sensors were estimated for toluene and xylene, and also for humidity and other gaseous molecules such as formaldehyde and ammonia.

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Development of Susceptible Functional Fibers Using Microencapsulation of Susceptible Materials(III) ―Fragrant Functional Fibers― (감성물질의 마이크로캡슐화에 의한 감성기능 섬유의 개발(III) -방향 기능 섬유-)

  • Kim, Moon Sik;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.8 no.4
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    • pp.11-18
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    • 1996
  • Natural functional compound in the textile finishing for health and amenity using fragrant material have been applied by microencapsulation method. The microcapsules containing fragrant materials as functional compound were produced by in situ polymerization using urea-formaldehyde prepolymer. The average diameter of microcapsules is 2.75$\mu$ and particle size ranges over 0.5~10$\mu$. Fragment material is extracted approximatly proportioned from microcapsule at room temperature. The adsorption of microcapsule was improved by pretreatment of cationic agent. Fragrant materials in microcapsule was revealed to have long release time.

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A Study on Initial Control Performance of the Adsorption Protector for Construction Surface about Contaminant (흡착보양재 적용에 따른 실내 오염물질 초기제어 성능에 관한 연구)

  • Heo, Jung-Yong;Choi, Chang-Ho;Lee, Yun-Gyu
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.4
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    • pp.229-235
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    • 2009
  • In a domestic construction field, floor surface must be covered not to be scratched and polluted by protector until resident comes in. However this protector restricts the contaminant to leave from floor surface. So when the protector is removed, much contaminant is emitted from the floor surface to inside and makes a bad influence on the indoor air quality, In this research, it will be tested the reduction performance of contaminant between a normal protector and a contaminant absorption protector using charcoal powder.

Application of DBD Plasma Catalysis Hybrid Process to remove Organic Acids in Odors (악취물질인 유기산 제거를 위한 DBD 플라즈마 촉매 복합공정의 적용)

  • Hong, Eun-Gi;Suh, Jeong-Min;Choi, Kum-Chan
    • Journal of Environmental Science International
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    • v.23 no.9
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    • pp.1627-1634
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    • 2014
  • Odor control technology include absorption, adsorption, incineration and biological treatments. But, most of processes have some problems such as secondary organic acids discharge at the final odor treatment facility. In order to solve the problems for effective treatment of organic acids in odor, it is necessary to develop a new type advanced odor control technology. Some of the technology are plasma only process and plasma hybrid process as key process of the advanced technology. In this study, odor removal performance was compared DBD(Dielectric Barrier Discharge)plasma process with PCHP(plasma catalysis hybrid process) by gaseous ammonia, formaldehyde and acetic acid. Plasma only process by acetic acid obtained higher treatment efficiency above 90%, and PCHP reached its efficiency up to 96%. Acetic acid is relatively easy pollutant to control its concentration other than sulfur and nitrogen odor compounds, because it has tendency to react with water quickly. To test of the performance of DBD plasma process by applied voltage, the tests were conducted to find the dependence of experimental conditions of the applied voltage at 13 kV and 15 kV separately. With an applied voltage at 15 kV, the treatment efficiency was achieved to more higher than 13 kV from 83% to 99% on ammonia, formaldehyde and acetic acid. It seems to the odor treatment efficiency depends on the applied voltage, temperature, humidity and chemical bonding of odors.

Ion-exchange Separation and Spectrophotometric Determination of Trace Amount of Aluminium with Thorinin the Presence of Triton X-100 (Triton X-100 존재하에 Thorin에 의한 미량의 알루미늄 이온의 분광학적 정량 및 이온-교환 분리)

  • Park, Chan-Il;Cha, Ki-Won;Jung, Duck-Chae
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.515-520
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    • 1999
  • The spectrophotometric determination of Al(III) with thorin have been investigated. The optimum condition of pH, concentration of ligand and surfactant, and stability were evaluated. The thorin ligand offers selective separation of Al(III) from sample solution containing Fe(III), Ni(II), Cu(II), Pb(II) and Cu(II). Various surfactants were tested and Triton X-100 showed the best stability and the maximum absorbance in an aqueous solution of Al(III)-Thorin-Triton X-100 complex appears about 526 nm. The method was applied for the determination of Al(III) in mixed sample solution. Separation and preconcentration was performed with a short column filled with resorcinol-formaldehyde resin. Control of the pH during the column operation is essential because the adsorption capacities are very sensitive to change in pH. Their separation was carried out in 0.2 M acetic acid-sodium acetate buffer solution (pH 4.5) and 1.0 M $HNO_3$media.

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