• Title/Summary/Keyword: Flux solution

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FLUX DECLINE DURING THE ULTRA-FILTRATION OF DILUTE SI COLLOIDAL SOLUTION WITH HOLLOW FIBER MEMBRANE

  • Park, Ho-Sang;Nam, Suk-Tae;Jeon, Jae-Hong;Lee, Seok-Ki
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.95-96
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    • 1999
  • The ultrafiltration behavior of dilute colloidal solution containing Si particles has been investigated. The experiments in cross flow mode have been performed at different operating condition by using the membrane with 20 kDa cut-off. The flux decline was due to the development of membrane fouling which was a dynamic process of two distinctive stages. For the high trans-membrane pressure, the pore blocking resistance was dominant at the initial period of filtraion and was followed by the cake resistance. And for the low cross flow velocity, the membrane fouling was governed by the cake filtration model at the initial stage of filtration process. Flux jump was observed temporally during the membrane filtration of mixed feed solution.

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Effect of intermittent operation modes on performance of reverse osmosis (RO) membrane in desalination and water treatment

  • Yang, Heungsik;Choi, Jihyeok;Choi, Yongjun;Lee, Sangho
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.39-49
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    • 2022
  • Seawater desalination is doubtlessly a viable option to supply fresh drinking water. Nevertheless, RO (reverse osmosis) desalination plants in specific areas may be intermittently operated to match the imbalance between water demand and supply. Although a handful of works have been done on other membrane systems, few studies have attempted to mitigate fouling in intermittent RO systems. Accordingly, the objectives of this paper were to examine the effect of the intermittent operation on RO fouling; and to compare four intermittent operation modes including feed solution recirculation, membrane storage in the feed solution, deionized water (DI) recirculation, and membrane storage in DI water. Results showed that intermittent operation reduced RO fouling under several conditions. However, the extents of fouling mitigation were different depending on the feed conditions, foulant types, and membrane lay-up methods. When the feed solution was recirculated during the lay-up, the restoration of the flux was less significant than that by the feed solution feed-up. The use of deionized water during the lay-up was effective to restore flux, especially when the feed solution contains scale-forming salts (CaSO4) and/or colloidal silica.

Micellar Enhanced Ultrafiltration (MEUF) and Activated Carbon Fiber (ACF) Hybrid Processes for the Removal of Cadmium from an Aqueous Solution

  • Rafique, Rahman Faizur;Lee, Seunghwan
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.775-780
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    • 2014
  • Micellar enhanced ultrafiltration (MEUF) was used to remove cadmium from an aqueous solution using sodium dodecyl sulfate (SDS) as a surfactant. Operational parameters such as initial permeate flux, retentate pressure, initial cadmium concentration, pH solution, molecular weight cut-off (MWCO), and molar ratio of cadmium to SDS were investigated. Removal efficiency of cadmium from an aqueous solution increased with an increase of retentate pressure, pH solution and molar ratio of cadmium to SDS, and decreased with an increase of initial permeate flux. Higher removal efficiency of cadmium from the aqueous solution was achieved using lower MWCO (smaller membrane pore size). Under optimized experimental condition, cadmium removal efficiency reached 74.6 % within an hour. Using MEUF-ACF hybrid process the removal efficiency of both cadmium and SDS was found to be over 90%.

Thrust Characteristics Analysis considering the effect of the loops of flux in a LIM for Railway Transit (맴돌이 자속의 영향을 고려한 철도차량용 선형유도전동기의 추력 특성 연구)

  • Park, Chan-Bae;Lee, Hyung-Woo;Han, Kyung-Hee;Lee, Byung-Song;Kwon, Sam-Young;Park, Hyun-June
    • Proceedings of the KSR Conference
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    • 2007.11a
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    • pp.1605-1609
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    • 2007
  • In the case of Linear induction motor(LIM), numerical analysis method like Finite Element Method(FEM) has been mainly used to analyze the travelling magnetic field problem which includes the velocity-induced electromotive force. If the problem including the velocity-induced electromotive force is analyzed by FEM using Galerkin method, the solution can be oscillated according to Peclet Number, which is determined by conductivity, permeability, moving velocity and size of mesh. Consequently, the accuracy of the solution can be low and the Loops of flux can be occurred at the secondary back-iron. These loops of flux occurred at the secondary back-iron does not exist physically, but it can be occurred in the analysis. In this case, the loops of flux can be generally removed by using Up-Wind method which is impossible to apply a conventional S/W tool(Maxwell 2D). Therefore, in this paper, authors examined the Loops of flux occurred at the secondary back-iron of LIM according to variations of Peclet Number, and analyzed whether these loops of flux affect on the thrust force characteristics of LIM or not.

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Critical Flux with Respect to Aeration Rate for the Submerged Microfiltration Hollow Fiber Membrane in the Activated Sludge Solution (활성슬러지 수용액 내 침지식 정밀여과용 중공사막의 산기량에 따른 임계 투과유속)

  • Jeong, Doin;Chung, Kun Yong
    • Membrane Journal
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    • v.26 no.2
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    • pp.166-172
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    • 2016
  • In this study critical permeation flux was measured by the flux-step method with respect to aeration rate. The hollow fiber membrane module which has $85cm^2$ of effective area and $0.4{\mu}m$ nominal pore size was submerged in the activated sludge solution of MLSS 5,000 mg/L. The critical flux for without aeration was measured of $15.2L/m^2{\cdot}h$. However, the critical flux increased from 20.6 to $32.5L/m^2{\cdot}h$ as the aeration rate increased from 100 to 1,000 mL/min.

Characteristics of the Sinusoidal Flux Continuous Operation Mode for the Submerged Flat-sheet Membrane Module in Cutting Oil Solution (절삭유 수용액내 침지식 평막 모듈에 대한 사인파형 투과유속 연속운전 방식의 특성)

  • Won, In Hye;Chung, Kun Yong
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.646-652
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    • 2015
  • In this study transmembrane pressure (TMP) was measured with respect to permeate flux through the submerged flat sheet membrane for the emulsion and semi-synthetic cutting oil solutions. The effective area and nominal pore size of the used microfiltration membrane were $0.02m^2$ and $0.15{\mu}m$, respectively. The experiments were carried out simultaneously for run/stop (R/S) and sinusoidal flux continuous operation (SFCO) modes using two submerged membrane module in the reservoir. TMP for the case of SFCO was maintained under 60% of R/S, and the effect on TMP drop decreased as the permeate flux increased for emulsion cutting oil solution. Membrane fouling for the semisynthetic solution showing low turbidity was induced lower comparing to the emulsion solution. Also, the effect on TMP drop for SFCO decreased during long-term operation.

Effects of Surface Water Chemistry and Physicochemical Characteristics of Humic Acid on Fouling of Membrane (원수의 수질화학과 HA의 물리화학적 특성이 막 오염에 미치는 영향)

  • Bae, Jin-Youl;Han, Ihnsup;Park, Sung-Ho;Shin, Jee-Won
    • Journal of Korean Society on Water Environment
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    • v.21 no.3
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    • pp.242-247
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    • 2005
  • In this study, we investigated the removal efficiencies of pollutants and permeate fluxes depending on chemistry of feed water, various molecular weight cut-offs (MWCOs) and materials of membrane, operating pressure. We used seven MWCO membranes of YC0.5, YM1, YM3, YM10, YM30, YM100 and PM30, humic acid solution and surface water as feed water, and examined variation in permeate flux. Results of TOC removal experiment demonstrate that MWCO lower 1,000daltons could remove humic acid effectively. As increasing solution pH and decreasing divalent cations ($Ca^{2+}$) concentration, TOC removal increased. But $UV_{254}$ removal efficiency increased with higher divalent cation concentration and solution pH. Membrane fouling increased with increasing electrolyte (NaCl), divalent cation concentration and decreasing solution pH. In spite of initial permeate flux of the hydrophobic membrane (PM30) was higher than that of the hydrophilic membrane (YM30), flux decline of PM30 was significant during operation. At higher operating pressure, compactness of the cake layer on the membrane surface increased, resulting in gradual increase in hydraulic resistance.

Choline chloride-Glycerol (1:2 mol) as draw solution in forward osmosis for dewatering purpose

  • Dutta, Supritam;Dave, Pragnesh;Nath, Kaushik
    • Membrane and Water Treatment
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    • v.13 no.2
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    • pp.63-72
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    • 2022
  • Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m-2h-1) with relatively low reverse solute flux (0.125 g m-2h-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m-2h-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

Fine Size YAG:Tb Phosphor Particles Prepared by Spray Pyrolysis (분무 열분해 공정에 의해 합성된 미세 YAG:Tb 형광체)

  • Lee, Hyo Jin;Hong, Seung Kwon;Jung, Dae Soo;Kang, Yun Chan;Jung, Kyeong Youl
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.407-411
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    • 2005
  • YAG:Tb($Y_3Al_5O_{12}:Tb$) phosphor particles were prepared by spray pyrolysis from spray solution containing various types of flux materials. The effects of type of flux, organic material and post-treatment temperature on the characteristics of morphology, crystallinity and photoluminescence of YAG:Tb phosphor particles were investigated. Citric acid and ethylene glycol used as organic additive improved the photoluminescence intensity of the YAG:Tb phosphor particles without destruction of the morphology after post-treatment at high temperature. However, the spherical shape of the precursor particles obtained by spray pyrolysis from spray solution containing high amount of flux material disappeared after post-treatment at $1300^{\circ}C$. YAG:Tb phosphor particles prepared from spray solution containing lithium carbonate flux had fine size and regular morphology after post-treatment. Lithium carbonate used as flux material was also efficient in improvement of the photoluminescence intensity of the YAG:Tb phosphor particles. The optimum photoluminescence intensity of the YAG:Tb phosphor particles prepared from spray solution containing lithium carbonate flux was 189% of that of the phosphor particles prepared from spray solution without flux material.

Phytochemical-based Tannic Acid Derivatives as Draw Solutes for Forward Osmosis Process (정삼투 공정의 유도용질로서의 식물 화학물질 기반의 탄닌산 유도체)

  • Kim, Taehyung;Ju, Changha;Kang, Hyo
    • Membrane Journal
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    • v.28 no.3
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    • pp.157-168
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    • 2018
  • Potassium tannate (TA-K), which is prepared by base treatment of the bio-renewable tannic acid (TA), was evaluated for its potential application as a draw solute for water purification by forward osmosis. The forward osmosis and recovery properties of TA-K were systematically investigated. In the application of forward osmosis through the active layer facing feed solution (AL-FS) method, the water flux of TA-K draw solution was significantly higher than that of the TA draw solution, while that of the latter was not identified. At a low concentration of 100 mM, the osmotic pressure (1,135 mOsmol/kg) of the TA-K draw solution was approximately 6.5 times that (173 mOsmol/kg) of the NaCl draw solution. Furthermore, the water flux and specific salt flux (6.14 LMH, 1.26 g/L) of the TA-K draw solution at 100 mM were approximately 2.5 and 0.5 times those of the NaCl draw solution (2.46 LMH, 2.63 g/L) at the same concentration, respectively. For reuse, TA-K was precipitated by using a metal ion and recovered through membrane filtration. This study demonstrates the applicability of a phytochemical material as a draw solute for forward osmosis.