• 제목/요약/키워드: Fluidized-bed reactor

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Effects of Operating Variables on CO Conversion of WGS Catalyst in a Fluidized Bed Reactor Equipped with Bed Insert (내부 삽입물을 적용한 유동층 반응기에서 WGS 촉매의 CO 전화율에 미치는 조업변수들의 영향)

  • Park, Jihye;Lee, Dongho;Park, Youngeheol;Moon, Jongho;Rhee, Youngwoo;Ryu, Hojung
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.2
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    • pp.209-217
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    • 2014
  • To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor, a spring type bed insert was developed. In this study, effects of operating variables such as steam/CO ratio, gas velocity, syngas concentration on CO conversion were investigated in a fluidized bed reactor using the spring type bed insert to hold the WGS catalyst as tablet shape. CO conversion increased initially as the steam/CO ratio increased. But further increment of the steam/CO ratio caused decreasing of CO conversion because of increment of gas velocity and decrement of syngas concentration. Moreover, CO conversion decreased as the gas velocity increased and the syngas concentration decreased at the same steam/CO ratio. Continuous operation up to 48 hours (2 days) was carried out to check reactivity decay of WGS catalyst supported by spring type bed insert. The average CO conversion was 99.04% and we could conclude that the WGS reactivity at those conditions was maintained up to 48 hours.

The Dynamic Characteristics of a Two Phase Fluidized Beds (이상 유동층 반응기의 동특성에 관하여)

  • Suh, Myung-Gyo;Suh, Jung-Ho;Kang, Jun-Soo
    • Korean Journal of Food Science and Technology
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    • v.25 no.3
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    • pp.210-213
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    • 1993
  • The purpose of this research was to investigate fluidization characteristics of three solid particles, correlations between voidage and superficial velocity. The inside diameter of a column did not affect the fraction void-superficial velocity relationship for fluidization systems which was obtained as follows: $\frac{u}{u_t}={\varepsilon}^{3.703}----Sea\;Sand$ $\frac{u}{u_t}={\varepsilon}^{3.5665}----long\;Exchange$ $\frac{u}{u_t}={\varepsilon}^{4.066}----GAC$ And the sphericial type media is good for fluidized systems as it maintains low voidage. Actually, if biofilm attached to media (bioparticle), the density became lower in fluidized bed biofilm reactor. Therefore, as the density of media become higher, it is easy to maintain fluidized beds.

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Mathematical Model for a Three-Phase Fluidized Bed Biofilm Reactor in Wastewater Treatment

  • Choi, Jeong-Woo;Min, Ju-Hong;Lee, Won-Hong;Lee, Sang-Back
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.4 no.1
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    • pp.51-58
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    • 1999
  • A mathematical model for a three phase fluidized bed bioreactor (TFBBR) was proposed to describe oxygen utilization rate, biomass concentration and the removal efficiency of Chemical Oxygen Demand (COD) in wastewater treatment. The model consisted of the biofilm model to describe the oxygen uptake rate and the hydraulic model to describe flow characteristics to cause the oxygen distribution in the reactor. The biofilm model represented the oxygen uptake rate by individual bioparticle and the hydrodynamics of fluids presented an axial dispersion flow with back mixing in the liquid phase and a plug flow in the gas phase. The difference of setting velocity along the column height due to the distributions of size and number of bioparticle was considered. The proposed model was able to predict the biomass concentration and the dissolved oxygen concentration along the column height. The removal efficiency of COD was calculated based on the oxygen consumption amounts that were obtained from the dissolved oxygen concentration. The predicted oxygen concentration by the proposed model agreed reasonably well with experimental measurement in a TFBBR. The effects of various operating parameters on the oxygen concentration were simulated based on the proposed model. The media size and media density affected the performance of a TFBBR. The dissolved oxygen concentration was significantly affected by the superficial liquid velocity but the removal efficiency of COD was significantly affected by the superficial gas velocity.

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Development of Innovation DME Process from Natural Gas and Biomass in KOREA (천연가스와 바이오매스로부터 개선된 DME 공정의 개발)

  • Cho, Wonjun;Song, Taekyong;Baek, Youngsoon;Kim, Seung-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.107-107
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    • 2010
  • Hydrogen is an alternative fuel for the future energy which can reduce pollutants and greenhouse gases. Synthesis gas have played an important role of synthesizing the valuable chemical compound, for example methanol, DME and GTL chemicals. Renewable biomass feedstocks can be potentially used for fuels and chemical production. Current thermal processing techniques such as fast pyrolysis, slow pyrolysis, and gasification tend to generate products with a large slate of compounds. Lignocellulose feedstocks such as forest residues are promising for the production of bio-oil and synthesis gas. Pyrolysis and gasification was investigated using thermogravimetric analyzer (TGA) and bubbling fluidized bed gasification reactor to utilize forest woody biomass. Most of the materials decomposed between $320^{\circ}C$ and $380^{\circ}C$ at heating rates of $5{\sim}20^{\circ}C/min$ in thermogravimetric analysis. Bubbling fluidized bed reactor were use to study gasification characteristics, and the effects of reaction temperature, residence time and feedstocks on gas yields and selectivities were investigated. With increasing temperature from $750^{\circ}C$ to $850^{\circ}C$, the yield of char decreased, whereas the yield of gas increased. The gaseous products consisted of mostly CO, CO2, H2 and a small fraction of C1-C4 hydrocarbons.

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Synthesis Gas Production from Gasification of Woody Biomass (목질계 바이오매스로부터 가스화에 의한 합성가스 제조 연구)

  • Cho, Won-Jun;Mo, Yong-Gi;Song, Taek-Yong;Baek, Young-Soon;Kim, Seung-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.587-594
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    • 2010
  • Hydrogen is an alternative fuel for the future energy which can reduce pollutants and greenhouse gases. Synthesis gas has played an important role of synthesizing the valuable chemical compounds, for example methanol, DME and GTL chemicals. Renewable biomass feedstocks can be potentially used for fuel and chemicals. Current thermal processing techniques such as fast pyrolysis, slow pyrolysis, and gasification tend to generate products with a large slate of compounds. Lignocellulose feedstocks such as forest residues are promising for the production of bio-oil and synthesis gas. Pyrolysis and gasification was investigated using thermogravimetric analyzer (TGA) and bubbling fluidized bed gasification reactor to utilize forest woody biomass. Most of the materials decomposed between $320^{\circ}C$ and $380^{\circ}C$ at heating rates of $5{\sim}20^{\circ}C$/min in thermogravimetric analysis. Bubbling fluidized bed reactor was used to study gasification characteristics, and the effects of reaction temperature, residence time and feedstocks on gas yields and selectivities were investigated. With increasing temperature from $750^{\circ}C$ to $850^{\circ}C$, the yield of char decreased, whereas the yield of gas increased. The gaseous products consisted of mostly CO, $CO_2$, $H_2$ and a small fraction of $C_1-C_4$ hydrocarbons.

Pyrolysis Reaction Characteristics of Biomass Fluidized Bed Reactor (기포(氣泡) 유동층(流動層) 반응기(反應器)에서 바이오매스 열분해(熱分解) 반응특성(反應特性))

  • Lee, Sun-Hoon;Yoo, Kyung-Seun;Lee, See-Hoon;Lee, Jae-Goo;Kim, Jae-Ho
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.75-82
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    • 2005
  • Pyrolysis of biomass is one of the promising methods to obtain energy and valuable chemical stocks. Fast pyrolysis of Q. acutissima and L. letolepis has been carried out in a bubbling fluidized bed reactor to determine the optimum operating conditions of the pyrolyzer. Effects of reaction temperature, Uo/Umf, L/D ratio, and feed rate have been determined and the optimum conditions are as follows: $T\;=\;400^{\circ}C,\;U_o/U_{mf}\;=\;3.0,\;L/D\;=\;2.0$. Maximum yield of bio-oil was about 55% and the main compositions were carbohydrates, guaiacols, furans, phenols, and syringols. Product gas was consists of CO, $CO_2$, light hydrocarbons and the measured gas yield using the compositions agreed with the calculated value.

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Axial Solid Holdup in a Circulating Fluidized Bed Plasma Reactor under Reduced Pressure (감압 순환유동층 플라즈마 반응기의 축방향 고체체류량)

  • Park, Sounghee
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.527-532
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    • 2016
  • The effects of gas velocity and solid circulation rate on the axial solid holdup distribution have been determined in a 10 mm-I.D. ${\times}$ 800 mm-high circulating fluidized bed plasma reactor under reduced pressure (1torr). Polystyrene polymer powder and nitrogen gas are used as solid and gas materials respectively. The change of solid circulation rate by a large gas flow rate of the riser (40~80 sccm) is also possible by a relatively small gas flow rate of the solid recirculation part (6.6~9.9 sccm). The solid circulation rate in the reactor under reduced pressure increases with increasing aeration velocity in the solid recirculation part. The axial solid holdup in the riser decreases from the dense at the bottom to the dilute phase at the top section of the riser. Solid holdups at the axial positions in the riser increase linearly with increasing solid circulating velocity. From these results, we could determine the position of plasma load for good plasma ignition, maintain and plasma reaction.

Fast pyrolysis of Medium-Density Fiberboard Using a Fluidized Bed Reactor (유동층 반응기를 이용한 Medium-Density Fiberboard의 급속 열분해)

  • Park, Young-Kwon;Park, Kyung-Seon;Park, Sung Hoon
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.672-675
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    • 2013
  • Fast pyrolysis of medium-density fiberboard was carried out using a fluidized-bed reactor under various conditions to find an optimum pyrolysis condition. When the pyrolysis temperature was varied between $425^{\circ}C$ and $575^{\circ}C$, the maximum bio-oil yield of 52 wt% was obtained at $525^{\circ}C$. The quality of the bio-oil product increased with increasing pyrolysis temperature. Pyrolysis at a high temperature removed significant amounts of oxygenates and acids, producing more valuable species such as aromatics and phenolics. The main gaseous products were CO and $CO_2$. The yields of CO and $C_1-C_4$ hydrocarbons increased with increasing the pyrolysis temperature.