• 전기화학회지
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• 제17권4호
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• pp.237-244
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• 2014

We report novel and simple structure of supercapacitors fabricated by using flexible glass fibre separators as templates. This method does not require separate electrodes, binders and high pressure/temperature to build the supercapacitor unit cells as required by the conventional technology. The supercapacitors were fabricated by drop-casting solution mixtures of carbonaceous active materials/gel electrolytes onto two sides of glass fibre separators. Two carbonaceous materials (nanoscaled activated carbons, multi-walled carbon nanotubes) were investigated as electrode materials. The electrochemical measurements reveal that the separatorbased supercapacitors using ACs successfully demonstrated significant mass specific capacitance ($22.3F\;g^{-1}$) and energy density ($9.7Wh\;kg^{-1}$), indicating this method can be useful in fabricating flexible, wearable and stretchable energy storage devices in more straightforward and cost-effective way than current technology.

• ETRI Journal
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• 제39권6호
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• pp.874-879
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• 2017

This paper challenges the fabrication of a thin film energy storage device on a flexible polymer substrate specifically by replacing most commonly used metal foil current collectors with coated current collectors. Mass-manufacturable spray-coating technology enables the fabrication of two different half-cell electric double layer capacitors (EDLC) with a spray-coated silver paste current collector and a Ni foil current collector. The larger specific capacitances of the half-cell EDLC with the spray-coated silver current collector are obtained as 103.86 F/g and 76.8 F/g for scan rates of 10 mV/s and 500 mV/s, respectively. Further, even though the half-cell EDLC with the spray-coated current collector is heavier than that with the Ni foil current collector, smaller Warburg impedance and contact resistance are characterized from Nyquist plots. For the applied voltages ranging from -0.5 V to 0.5 V, the spray-coated thin film energy storage device exhibits a better performance.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.163.2-163.2
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• 2010

We developed a simple method to synthesis a nitrogen doped graphene, nitrogen plasma treated graphene (NPG) sheets thought nitrogen plasma etching of graphene oxide (GO). X-ray photo electron spectroscopy (XPS) study of NPG sheets treated at various plasma conditions reveal that N-doping is classified to 3 kinds of binding configurations. The nitrogen doping concentration is at least 1.5 at % and up to 3 at% with changing of ratio of nitrogen configuration in NPG. Our group demonstrate ultracapacitor with high capacity and extremely durable using a NPG sheets that are comparable to pristine graphene supercapacitor, and pseudocapacitor using polymer and metal oxide with redox reaction, capacitance that are three-times higher, and a cycle life that are extremely stable. We also realized flexible capacitor by using the paper electrode that are coated by NPG sheets. NPG paper capacitor presented almost same performance compare with NPG on a metal substrate, and durability is much more enhanced than that. To additionally explain that how different kind of atoms in graphene layers can act as the ion absorption sites, we simulated the binding energy between nitrogen in graphene layer and ions in electrolyte. Increasing the energy density and long cycle life of ultracapacitor will enable them to compete with batteries and conventional capacitors in number of applications.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.1-4
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• 2008

Fuel cells have the potential of providing several times higher energy storage densities than those possible using current state-of-the-art lithium-ion batteries, but current energy density of fuel cell system is not better than that of lithium-ion batteries. To achieve the high energy density, volume and weight of fuel cell system need to be reduced by miniaturizing system components such as stack, fuel tank, and balance-of-plant. In this paper, the thin flexible PCB (Printed circuit board) is used as a current collector to reduce the stack volume. Two end plates are made from light weight aluminum alloy plate. The plate surface is wholly oxidized through the anodizing treatment for electrical insulation. The opening rate of cathode plate hole is optimized through unit cell performance measurement of various opening rates. The performances are measured at room temperature and ambient pressure condition without any repulsive air supply. The active area of MEA is 10.08 $cm^2$ and active area per a unit cell is 1.68 $cm^2$. The peak power density is about 210 mW/$cm^2$ and the air-breathing planar stack of 2 Wis achieved as a small volume of 18 cc.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.115-116
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• 2012

The demand for flexible electronic systems such as wearable computers, E-paper, and flexible displays has increased due to their advantages of excellent portability, conformal contact with curved surfaces, light weight, and human friendly interfaces over present rigid electronic systems. This seminar introduces three recent progresses that can extend the application of high performance flexible inorganic electronics. The first part of this seminar will introduce a RRAM with a one transistor-one memristor (1T-1M) arrays on flexible substrates. Flexible memory is an essential part of electronics for data processing, storage, and radio frequency (RF) communication and thus a key element to realize such flexible electronic systems. Although several emerging memory technologies, including resistive switching memory, have been proposed, the cell-to-cell interference issue has to be overcome for flexible and high performance nonvolatile memory applications. The cell-to-cell interference between neighbouring memory cells occurs due to leakage current paths through adjacent low resistance state cells and induces not only unnecessary power consumption but also a misreading problem, a fatal obstacle in memory operation. To fabricate a fully functional flexible memory and prevent these unwanted effects, we integrated high performance flexible single crystal silicon transistors with an amorphous titanium oxide (a-TiO2) based memristor to control the logic state of memory. The $8{\times}8$ NOR type 1T-1M RRAM demonstrated the first random access memory operation on flexible substrates by controlling each memory unit cell independently. The second part of the seminar will discuss the flexible GaN LED on LCP substrates for implantable biosensor. Inorganic III-V light emitting diodes (LEDs) have superior characteristics, such as long-term stability, high efficiency, and strong brightness compared to conventional incandescent lamps and OLED. However, due to the brittle property of bulk inorganic semiconductor materials, III-V LED limits its applications in the field of high performance flexible electronics. This seminar introduces the first flexible and implantable GaN LED on plastic substrates that is transferred from bulk GaN on Si substrates. The superb properties of the flexible GaN thin film in terms of its wide band gap and high efficiency enable the dramatic extension of not only consumer electronic applications but also the biosensing scale. The flexible white LEDs are demonstrated for the feasibility of using a white light source for future flexible BLU devices. Finally a water-resist and a biocompatible PTFE-coated flexible LED biosensor can detect PSA at a detection limit of 1 ng/mL. These results show that the nitride-based flexible LED can be used as the future flexible display technology and a type of implantable LED biosensor for a therapy tool. The final part of this seminar will introduce a highly efficient and printable BaTiO3 thin film nanogenerator on plastic substrates. Energy harvesting technologies converting external biomechanical energy sources (such as heart beat, blood flow, muscle stretching and animal movements) into electrical energy is recently a highly demanding issue in the materials science community. Herein, we describe procedure suitable for generating and printing a lead-free microstructured BaTiO3 thin film nanogenerator on plastic substrates to overcome limitations appeared in conventional flexible ferroelectric devices. Flexible BaTiO3 thin film nanogenerator was fabricated and the piezoelectric properties and mechanically stability of ferroelectric devices were characterized. From the results, we demonstrate the highly efficient and stable performance of BaTiO3 thin film nanogenerator.

• 한국산학기술학회논문지
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• 제18권12호
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• pp.26-31
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• 2017

전력계통의 과도안정도를 향상시키기 위해 종래에는 무효전력 보상장치를 설치하는 방법을 주로 사용하였다. 전통적인 무효전력 보상장치 중 SVC(Static Var Compensator), 변압기의 탭 변환기는 값이 싸고 기계적 스위칭으로 동작하여 속도가 느리다는 단점이 있고, 전력전자기술을 바탕으로 하는 STATCOM(Static Synchronous Compensator)은 고속으로 동작할 수 있는 장점이 있어 최근에 각광을 받고 있지만 고가의 장치라는 단점이 있다. 또한, 무효전력 보상장치에 기반한 전통적인 방법은 무효전력만을 공급하여 과도안정도를 향상시키기에 대형 전동기의 트립에 의한 급격한 전압붕괴를 막을 수 없다. 반면에 에너지 저장시스템은 무효전력과 유효전력을 동시에 공급할 수 있다. 즉, 선로사고로 인하여 부하에 유효전력의 공급이 감소하는 것을 ESS을 통한 유효전력을 공급함과 동시에 적절한 무효전력의 공급을 통하여 과도안정도를 향상시킬 수 있다. 전력계통의 사고 시 유효전력의 빠른 공급은 과도안정도 향상에 매우 중요한 역할을 한다. 본 논문에서는 대형 전동기 부하와 같은 큰 동적부하를 가지는 전력계통에 대하여 에너지저장시스템을 사용한 과도안정도 향상방법을 제시한다. 또한, 유효전력과 무효전력을 보상하는 방법이 기존의 방법보다 더 효과적으로 과도안정도를 향상시킴을 확인하였다.

• 한국산학기술학회논문지
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• 제20권6호
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• pp.592-597
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• 2019

전력계통의 과도안정도를 향상시키기 위한 종래의 방법은 STATCOM(Static Synchronous Compensator), SVC(Static Var Compensator)와 같은 무효전력 보상장치를 이용하는 것이다. 하지만 무효전력 보상장치에 기반한 전통적인 방법은 대형 전동기의 트립에 의한 급격한 전압붕괴를 막을 수 없다. 반면에 에너지 저장시스템은 무효전력과 유효전력을 동시에 공급할 수 있다. 전력계통의 사고 시 유효전력의 빠른 공급은 과도안정도 향상에 매우 중요한 역할을 한다. 본 논문에서는 대형 전동기부하와 같은 큰 동적부하를 가지는 전력계통에 대하여 에너지저장시스템을 사용한 과도 안정도 향상방법을 제시한다. 또한 유효전력과 무효전력을 보상하는 방법이 기존의 방법보다 더 효과적으로 과도 안정도를 향상시킴을 확인하였다.

• 반도체디스플레이기술학회지
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• 제4권2호
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• pp.15-19
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• 2005

The organic light-emitting devices(OLEDs) based on fluorescence have low efficiency due to the requirement of spin-symmetry conservation. By using the phosphorescent material, the internal quantum efficiency can reach 100$\%$, compared to 25$\%$ in case of the fluorescent material [1]. Thus recently phosphorescent OLEDs have been extensively studied and showed higher internal quantum efficiency than conventional OLEDs. In this study, we have applied a new Ir complex as a red dopant and fabricated a red phosphorescent OLED on a flexible PC(Polycarbonate) substrate. Also, we have investigated the electrical and optical properties of the devices with a structure of A1/LiF/Alq3/(RD05 doped)BAlq/NPB/2-TNAIA/ITO/PC substrate. Our device showed the lightening efficiency of > 30 cd/A at an initial brightness of 1000 cd/$m^{2}$. The CIE(Commission Internationale de L'Eclairage) coordinates for the device were (0.62,0.37) at a current density of 1 mA/$cm^{2}$. In addition, although the sheet resistance of ITO films on PC substrate is higher than that on glass substrate, the flexible OLED showed much better lightening efficiency without much increase in operating voltage.

• 한국재료학회지
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• 제27권5호
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• pp.248-254
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• 2017

In the present work, graphene powder was synthesized by laser scribing method. The resultant flexible light-scribed graphene is very appropriate for use in micro-supercapacitors. The effect of the laser scribing process in reducing graphene oxide (GO) was investigated. GO was synthesized using a chemical mixture of GO solution; then, it was coated onto a LightScribe DVD disk and laser scribed to reduce GO and create laser-scribed graphene (LSG). The CV curves of pristine rGO at various scan rates showed that the ultimate product possesses the ability to store energy at the supercapacitor level. Charge-discharge curves of pristine rGO at two different current densities indicated that the specific capacitance ($C_m$) increases due to the reduction of the discharge current density. Finally, the long-term charge-discharge stability of the LSG was plotted and indicates that the specific capacitance decreases very slightly from its primary capacitance of ${\sim}10F\;cm^{-3}$ and that the cyclic stability is favorable over 1000 cycles.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 C
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• pp.1059-1062
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• 1998

This paper which can simulate FRIENDS(Flexible Reliable Intelligent Electrical eNergy Delivery System) model of distribution electrical system presents a new algorithm. In the operation of FRIENDS model, dispersed energy storage(DES) systems have an important role. We can use the active and reactive power of DES to control customer's voltage. In this, the former means load levelling operation and the later means voltage control operation of DES. We focus our research on load levelling operation of DES. We develope an algorithm to get an optimal capacity and operation schedule of DES and then apply it to the FRIENDS model. The results show the effectiveness of the proposed method.