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http://dx.doi.org/10.4218/etrij.2017-0086

Thin Film Energy Storage Device with Spray-Coated Sliver Paste Current Collector  

Yoon, Seong Man (Printed Electronics Institute, PEMS Co., Ltd.)
Jang, Yunseok (Department of Printed Electronics, KIMM)
Jo, Jeongdai (Department of Printed Electronics, KIMM)
Go, Jeung Sang (School of Mechanical Engineering, Pusan National University)
Publication Information
ETRI Journal / v.39, no.6, 2017 , pp. 874-879 More about this Journal
Abstract
This paper challenges the fabrication of a thin film energy storage device on a flexible polymer substrate specifically by replacing most commonly used metal foil current collectors with coated current collectors. Mass-manufacturable spray-coating technology enables the fabrication of two different half-cell electric double layer capacitors (EDLC) with a spray-coated silver paste current collector and a Ni foil current collector. The larger specific capacitances of the half-cell EDLC with the spray-coated silver current collector are obtained as 103.86 F/g and 76.8 F/g for scan rates of 10 mV/s and 500 mV/s, respectively. Further, even though the half-cell EDLC with the spray-coated current collector is heavier than that with the Ni foil current collector, smaller Warburg impedance and contact resistance are characterized from Nyquist plots. For the applied voltages ranging from -0.5 V to 0.5 V, the spray-coated thin film energy storage device exhibits a better performance.
Keywords
Current collector; Electric double layer capacitor; Energy storage; Spray coating;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 M. Kaempgen et al., "Printable Thin Film Supercapacitors Using Single-Walled Carbon Nanotubes," Nano Lett., vol. 9, no. 5, 2009, pp. 1872-1876.   DOI
2 Q. Wang, Z. Wen, and J. Li, "Carbon Nanotubes/$TiO_2$Nanotubes Hybrid Supercapacitor," J. Nanosci. Nanotechnol., vol. 7, no. 9, Sept. 2007, pp. 3328-3331.   DOI
3 M. Deng et al., "Studies on CNTs-$MnO_2$ Nanocomposite for Supercapacitors," J. Mater. Sci., vol. 40, no. 4, Feb. 2005, pp. 1017-1018.   DOI
4 L.B. Kong et al., "MWNTs/PANI Composite Materials Prepared by In-situ Chemical Oxidative Polymerization for Supercapacitor Electrode," J. Mater. Sci., vol. 43, no. 10, May 2008, pp. 3664-3669.   DOI
5 J. Lin et al., "Supercapacitors Based on Pillared Graphene Nanostructures," J. Nanosci. Nanotechnol., vol. 12, no. 3, Mar. 2012, pp. 1770-1775.   DOI
6 S. Lee et al., "Fabrication of Polypyrrole Nanorod Arrays for Supercapacitor: Effect of Length of Nanorods on Capacitance," J. Nanosci. Nanotechnol., vol. 8, no. 10, Oct. 2008, pp. 5036-5041.   DOI
7 Y. Qiu et al., "Preparation of Activated Carbon Paper Through a Simple Method and Application as a Supercapacitor," J. Mater. Sci., vol. 50, no. 4, Feb. 2015, pp. 1586-1593.   DOI
8 K.M. Kim et al., "Supercapacitive Properties of Composite Electrode Consisting of Activated Carbon and Di(1-Aminopyrene)quinine," ETRI J., vol. 38, no. 8, Apr. 2016, pp. 252-259.   DOI
9 S. Lee et al., "New Strategy and Easy Fabrication of Solid-State Supercapacitor Based on Polypyrrole and Nitrile Rubber," J. Nanosci. Nanotechnol., vol. 8, no. 9, Sept. 2008, pp. 4722-4725.   DOI
10 H. Tamai et al., "Preparation of Polyaniline Coated Activated Carbon and Their Electrode Performance for Supercapacitor," J. Mater. Sci., vol. 42, no. 4, Feb. 2007, pp. 1293-1298.   DOI
11 C. Portet et al., "Influence of Carbon Nanotubes Addition on Carbon-Carbon Supercapacitor Performances in Organic Electrolyte," J. Power Sources, vol. 139, no. 1-2, Jan. 2005, pp. 371-378.   DOI
12 A. Lewandowski et al., "Supercapacitors Based on Activated Carbon and Polyethylene Oxide-KOH-$H_2O$ Polymer Electrolyte," Electrochim. Acta, vol. 46, no. 18, May 2001, pp. 2777-2780.   DOI
13 D. Kalpana, Y.S. Lee, and Y. Sato, "New, Low-Cost, High-Power Poly(o-Anisidine-co-Metanilic Acid)/Activated Carbon Electrode for Electrochemical Supercapacitors," J. Power Sources, vol. 190, no. 2, May 2009, pp. 592-595.   DOI
14 S. Zhou et al., "Effect of Activated Carbon and Electrolyte on Properties of Supercapacitor," Trans. Nonferrous Metals Soc. China, vol. 17, no. 6, Dec. 2007, pp. 1328-1333.   DOI
15 V. Ruiza et al., "Effects of Thermal Treatment of Activated Carbon on the Electrochemical Behaviour in Supercapacitors," Electrochim. Acta, vol. 52, no. 15, Apr. 2007, pp. 4969-4973.   DOI
16 Q. Wang et al., "Activated Carbon Coated with Polyaniline as an Electrode Material in Supercapacitors," New Carbon Mater., vol. 23, no. 3, Mar. 2008, pp. 275-280.   DOI
17 S.M. Yoon et al., "Fabrication and Characterization of Flexible Thin Film Super-Capacitor with Silver Nano Paste Current Collector," J. Nanosci. Nanotechnol., vol. 13, no. 12, Dec. 2013, pp. 7844-7849.   DOI
18 Y.J. Lee et al., "Nano-Sized Ni-Doped Carbon Aerogel for Supercapacitor," J. Nanosci. Nanotechnol., vol. 11, no. 7, July 2011, pp. 6528-6532.   DOI
19 Z. Jin et al., "Activated Carbon Modified by Coupling Agent for Supercapacitor," Electrochim. Acta, vol. 59, Jan. 2012, pp. 100-104.   DOI
20 I. Kim et al., "Effect of Ink Cohesive Force on Gravure Offset Printing," Microelectron. Eng., vol. 98, Oct. 2012, pp. 587-589.   DOI
21 Y. Jang et al., "Activated Carbon Nanocomposite Electrodes for High Performance Supercapacitors," Electrochim. Acta, vol. 102, July 2013, pp. 240-245.   DOI
22 T. Takamura, Y. Sato, and Y. Sato, "Capacitance Improvement of Supercapacitor Active Material Based on Activated Carbon Fiber Working with a Li-Ion Containing Electrolyte," J. Power Sources, vol. 196, no. 13, July 2011, pp. 5774-5778.   DOI