• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.289-296
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• 1997

This paper discribes an experimental explosion risk assessment study on refrigerators containing flammable hydrocarbon refrigerant. A refrigerator used in this study is a larder fridge type, 215 liter in volume. The hydrocarbon refrigerant used in the refrigerator is iso-butane(C$_4$H$_{10}$). For the explosion safety assessment of the refrigerator, temperature of compressor, cooling air circulation fan motor, defrost heater and inner lamp were measured during the operation. And to confirm the ignitablity of flammable gas by the electric spark of the switches of the refrigerator, ON-OFF test of all switches were conducted with compulsorily near the stoichiometric concentration atmosphere of iso-butane-air mixture. As the result of experiment above mentioned and another experiment for the explosion safety assessment, we can conclude that explosion hazard in connection with the use of hydrocarbon refrigerant was few.w.

• Fire Science and Engineering
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• v.25 no.2
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• pp.114-119
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• 2011

Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits (UEL) for acids and ketones, the upper flash point of these were measured under the VLE (vaporliquid equilibrium) state by using Setaflash closed cup tester (ASTM D3278). The UELs calculated by Antoine equation by using the experimental upper flash point are usually lower than the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

• International Journal of High-Rise Buildings
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• v.7 no.4
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• pp.363-374
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• 2018

The façade is an important, complex, and costly part of a building, performing multiple objectives of value to the occupants, like protecting from wind, rain, sunlight, heat, cold, and sound. But the frequency of façade fires in large buildings is alarming, and has multiplied by seven times worldwide over the last three decades, to a current rate of 4.8 fires per year. High-performing polymer based materials allow for a significant improvement across several objectives of a facade (e.g., thermal insulation, weight, and construction time) thereby increasing the quality of a building. However, all polymers are flammable to some degree. If this safety problem is to be tackled effectively, then it is essential to understand how different materials, and the façade as a whole, perform in the event of a fire. This paper discusses the drivers for flammability in facades, the interaction of facade materials, and current gaps in knowledge. In doing so, it aims to provide an introduction to the field of façade fires, and to show that because of the drive for thermal efficiency and sustainability, façade systems have become more complex over time, and they have also become more flammable. We discuss the importance of quantifying the flammability of different façade systems, but highlight that it is currently impossible to do so, which hinders research progress. We finish by putting forward an integral framework of design that uses multi-objective optimization to ensure that flammability is minimized while considering other objectives, such as maximizing thermal performance or minimizing weight.

• Clean Technology
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• v.26 no.4
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• pp.279-285
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• 2020

Laboratories and industrial processes typically involve the use of flammable substances. An important property used to estimate fire and explosion risk for a flammable liquid is the flash point. In this study, flash point data at 101.3 kPa were determined using a SETA closed cup flash point tester on the following solvent mixtures: {2,2,4-trimethylpentane + methylcyclohexane}, {2,2,4-trimethylpentane + ethylbenzene}, and {2,2,4-trimethylpentane + p-xylene}. The purpose of this work is to obtain flash point data for binary mixtures of 2,2,4-trimethylpentane with three hydrocarbons (methylcyclohexane, ethylbenzene, and p-xylene), which are representative compounds of the main aromatic hydrocarbon fractions of petroleum. The measured flash points are compared with the predicted values calculated using the GE models' activity coefficient patterns: the Wilson, the Non-Random Two-Liquid (NRTL), and the UNIversal QUAsiChemical (UNIQUAC) models. The non-ideality of the mixture is also considered. The average absolute deviation between the predicted and measured lower flash point s is less than 1.99 K, except when Raoult's law is calculated. In addition, the minimum flash point behavior is not observed in any of the three binary systems. This work's predicted results can be applied to design safe petrochemical processes, such as identifying safe storage conditions for non-ideal solutions containing volatile components.

• The Journal of the Korea institute of electronic communication sciences
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• v.18 no.1
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• pp.195-204
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• 2023

The drone's battery system uses lithium-ion or lithium-polymer batteries, and it is known that the cause of fire during the disposal process after using the drone is combustible gas from the battery being discarded. Most of the batteries in the disposal process generated oxygen, but a small amount of flammable gas was also generated, and a large amount of chlorine ions and sulfates were also detected in the equipment used for treatment. If a system that detects this early is configured, it will be possible to reduce the risk of accidents caused by discarded batteries.

• Journal of the Society of Disaster Information
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• v.16 no.4
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• pp.701-711
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• 2020

Purpose: In this study, the risk of flammability of a liquid mixture was experimentally confirmed because the purpose of this study was to confirm the increase or decrease of the flammability risk in a mixture of two substances (combustible+combustible) and to present the risk of the mixture. Method: Flash point test method and result processing were tested based on KS M 2010-2008, a tag sealing test method used as a flash point test method for crude oil and petroleum products. The manufacturer of the equipment used in this experiment was Japan's TANAKA. The flash point was measured with a test equipment that satisfies the test standards of KS M 2010 with equipment produced by the company, and LP gas was used as the ignition source and water as the cooling water. In addition, when measuring the flash point, the temperature of the cooling water was tested using cooling water of about 2℃. Results: First of all, in the case of flammable + combustible mixtures, there was little change in flash point if the flash point difference between the two substances was not large, and if the flash point difference between the two substances was low, the flash point tended to increase as the number of substances with high flash point increased. However, in the case of toluene and methanol, the flash point of the mixture was lower than that of the material with a lower flash point. Also, in the case of a paint thinner, it was not easy to predict the flash point of the material because it was composed of a mixture, but as a result of experimental measurement, it was measured between -24℃ and 7℃. Conclusion: The results of this study are to determine the risk of mixtures through experimental studies on flammable mixtures for the purpose of securing the effectiveness of the details of the criteria for determining dangerous goods in the existing dangerous goods safety management method and securing the reliability and reproducibility of the determination of dangerous goods Criteria have been presented, and reference data on experimental criteria for flammable liquids that are regulated in firefighting sites can be provided. In addition, if this study accumulates know-how on differences in test methods, it is expected that it can be used as a basis for research on risk assessment of dangerous goods and as a basis for research on dangerous goods determination.

• Fire Science and Engineering
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• v.31 no.3
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• pp.1-10
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• 2017

This study examined the risk of accidents when handling hazardous materials in hazardous materials storage facilities without safety facilities. In the case of illegal dangerous cargo containers, the burning rate is very fast in the case of fire, which leads to explosions, that are damaging and difficult to control. In addition, accidents that occur in flammable liquid hazardous materials are caused mostly by accidents that occur in the space due to leakage. Therefore, the variables that affect these accidents were derived and the influence of these variables was investigated. Numerical and computational fluid dynamics programs were used to obtain the following final results. First, when a flammable liquid leaks into a specific space, it is influenced by temperature and relative humidity until a certain concentration (lower limit of combustion) is reached. In the case of temperature, it was found that the reaching time was shorter than the flash point In addition, the effect of variables on pool fire accidents of leakage tanks is somewhat different, but the variables that have the largest influence are the wind speed. Therefore, it is expected that the results of this study will be used as basic data for similar numerical analysis and it will provide useful numerical information about the accidental leakage of hazardous materials under various research conditions.

• Journal of the Korean Institute of Gas
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• v.24 no.3
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• pp.33-39
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• 2020

In general, in a batch reaction process in which products are made using flammable liquids, splash filling is used to clean the walls of the reactor by spraying flammable liquids, which are raw materials used for product, during cleaning of the reactor after work. During this process, mist of flammable liquid is generated, the lower limit of explosion is lowered, and fire·explosion may occur due to discharges caused by various types of complex charges, such as flow charge, collision charge, and ejection charge. Therefore, based on the recent accident case, to identify the risk when working in the form of splash filling with toluene in a batch process and perform an explosion impact analysis using the TNT equivalent method After that, we will analyze the accident results and suggest preventive measures such as constant purge system, improvement of cleaning method, and use of tantalum to prevent such accident.

• Journal of the Korean Electrochemical Society
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• v.12 no.3
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• pp.203-218
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• 2009

The development of lithium-ion battery (LIB) technologies and their application in the field of large-scale power sources, such as electric vehicles (EVs), hybrid EVs, and plug-in EVs require enhanced reliability and superior safety. The main components of LIBs should withstand to the inevitable heating of batteries during high current flow. Carbonate solvents that contribute to the dissociation of lithium salts are volatile and potentially combustible and can lead to the thermal runaway of batteries at any abuse conditions. Recently, an interest in nonflammable materials is greatly growing as a means for improving battery safety. In this review paper, novel approaches are described for designing highly safe electrolytes in detail. Non-flammability of liquid electrolytes and battery safety can be achieved by replacing flammable organic solvents with thermally resistive materials such as flame-retardants, fluorinated organic solvents, and ionic liquids.

• Fire Science and Engineering
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• v.33 no.3
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• pp.105-111
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• 2019

In Korea, the results of a field survey on the construction of flammable exterior materials implemented in 2018 revealed that 147,559 buildings belong to this category. It was found that the fire spreading cases in upper and adjacent constructions are about 3,500 per year, the fires of starting in flammable exterior material are about 1,500 per year. In this study, we investigated the repair method of buildings constructed by flammable exterior material and conducted performance verification of each repair materials for prevention of similar fire. In the case of the repair method, a method of reinforcing with a repair material after removing the existing building finishing material and a method of attaching the repair material after performing the face finishing are proposed. In addition, we conducted cone calorimeter tests of 6 materials such as fireproof gypsum board, mineral wool, hard urethane foam, ceramic board and ALC panel as dryvit and repairing materials, and investigated basic combustion performance of that materials.