• Fire Science and Engineering
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• v.27 no.6
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• pp.15-20
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• 2013

The convective heat transfer coefficient, emissivity, and flame heat flux on the surface of Duglas fir are estimated by using repulsive particle swarm optimization. The surface temperature, mass loss rate, and ignition time are measured for various incident heat fluxes from a cone heater of the cone calorimeter. The calculated surface temperatures obtained by using the optimized convective heat transfer coefficient, emissivity and flame heat flux on the surface in this study match well with those obtained from the test. The maximum error between the predicted and measured surface temperatures for the three different external heat fluxes is within 2% showing reasonable agreements. The methodology proposed in this study can be used to obtain various values related to heat transfer on a flaming surface that are difficult to measure in experiments.

• Fire Science and Engineering
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• v.21 no.1 s.65
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• pp.74-81
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• 2007

In this study, we have evaluated the hazardous factors of fires such as heat release rate, smoke density, ignition temperature, and flammability of carpet and curtain used in the public facilities. As a result of flame retardant treatment, the heat release rate of materials treated with flame retardant was lower than that of not treated. However, the smoke density of treated materials was higher than that of not treated. Also, we have investigated the fire characteristics of used and unused carpet. As a result, the heat release rate and the smoke density of used for 3 years carpet were higher than those of unused carpet. The distinct differences of flammability and ignition temperature between used and unused carpet were confirmed.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.208-213
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• 2013

In this study, the effect of phosphorus flame retardants on the flame retardancy of the flexible polyurethane foam (PUF) was investigated. Tetramethylene bis(orthophosphorylurea) [TBPU] and phosphinyl alkylphosphate ester [CR-530], resorcinol bis diphenylphosphate [RDP], triethyl phosphate [TEP] were used as flame retardants. The results of thermogravimetric analysis (TGA) indicate that TBPU added PUF produces more charred residues than the other flame retardant added PUF. It was found that TBPU added PUF exhibits low mean heat release rate (HRR), peak HRR, effective heat of combusion (EHC), mass loss rate (MLR), CO yield and $CO_2$ compared to those other flame retardants.

• Fire Science and Engineering
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• v.31 no.4
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• pp.12-19
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• 2017

The present paper is a study on the performance characteristics of organic-inorganic hybrid flame retardants. MDF plywood has been used, that are being used for the interior decoration of building structures, to make the samples for experiment according to the existing or non-existing treatment of organic-inorganic hybrid flame resistants. Later, the experiment on the measurement of flame retardant performance using a $45^{\circ}$ flammability tester and the experiment on the measurement of combustion characteristic using a cone calorimeter have been proceeded to confirm the performance characteristic of organic-inorganic hybrid flame retardants. From the result of experiments, it has been confirmed that both organic-inorganic hybrid flame retardants have merits of inorganic and organic substances, and that heat resistance, durability and adhesiveness have been largely improved. The performance on the flame retardant has also appeared with excellent effect such as the reduced generation of combustion gas and the decreased generation of smoke.

• Fire Science and Engineering
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• v.24 no.3
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• pp.72-77
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• 2010

Honeycomb core structure with its excellent stiffness and strength is being utilized in many fields such as interior building material. Because it is inexpensive and renewable, honeycomb paper production is economically and environmentally helpful. However, the paper needs to be fireproofed because it is vulnerable to fire. In this study, we have undergone the performance evaluation process of the honeycomb paper which is widely used as interior material of a fire door and packing material. Four kinds of honeycomb (a honeycomb made of flame-resistant paper; a honeycomb attached with conventional flame-resistant film made in the laboratory; honeycomb impregnated with flame retardant; a honeycomb attached with flame-resistant film after impregnating fire retardant) were used in the study to compare the fire retardant performance. As a result, the honeycomb with impregnated flame retardant showed the highest performance. The flame-resistant film was effective in delaying the igniting time but had a negative effect on the rate of heat and smoke production.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.178-184
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• 1997

The cone calorimeter as defined by ISO 5660, ASTM 1354, and NFPA 264A is used to assess the reaction to fire of almost any material that must be evaluated in the fire science field. Typical combustion gas analyses include oxygen, CO and CO2. Oxygen consumption is used to determine rate of heat release. Analysis of combustion gases other than oxygen, CO and CO2 has been attempted using filters to remove the solid smoke particles before analysis. This method has generated unreliable results due to the adsorption of many gas components on the active carbon . particles deposited on the filters. A technique using fourier Transform Infrared (FTIB) analysis without filtration will be disclosed and a discussion will be presented of the analytical results of toxic gases produced from various flame retarded polymeric materials. Use of such data in lethal toxic potency determinations is also reviewed.

• Journal of the Korean Wood Science and Technology
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• v.46 no.2
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• pp.189-201
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• 2018

Intumescent system is a highly effective flame retardant technology that takes advantage of the mechanism of foaming and carbonization. In order to materialize Intumescent system, it is necessary to use reinforcement material to improve the strength of the material. In this study, we used kenaf as a natural fiber to manufacture intumescent/EVA (ethylene vinyl acetate) composites to improve mechanical and flame retardant performance. Finally two materials with different particle shape are applied to one system. Therefore, the influence factors of the particles with different shapes on the composite material were analyzed based on the tensile test. For this purpose, we have used the tensile strength analysis model and confirmed that it can only act as a partial strength reinforcement due to weak binding force between the matrix and particles. In the combustion characteristics analysis using cone calorimeter and UL 94, the combustion characteristics were enhanced as the content of Intuemscent was increased. As the content of kenaf increased, combustion characteristics were strengthened and carbonization characteristics were weakened. Through the application of kenaf, it can be confirmed that elastic modulus improvement and combustion characteristics can be strengthened, which confirmed the possibility of development of environmentally friendly flame retardant materials.

• Fire Science and Engineering
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• v.25 no.3
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• pp.57-62
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• 2011

The combustion characteristic was evaluated for Pinus densiflora, used as a building material in Hanok, which were treated with two different flame retardant method. The specimen was brushed with flame retardant liquid two or three times and then let the specimen dehydrated during 24 h for spreaded treating. And the other specimen was soaked in the liquid for 72 h. The test methods were inflammability test using meker burner and heat release rate test using cone calorimeter. As a result for the tests, flame retardant treated specimens met the requirements of the inflammability and the spreaded treated method was more efficient than immersed method. The spreaded treated specimen had lower combustive properties than immersed specimen in TTI (time to ignition), PHRR (peak heat release rate), MLR (mass loss rate) and THR (total heat release).

• Journal of the Korean Society of Safety
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• v.28 no.3
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• pp.39-43
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• 2013

The present study has been conducted to investigate the fire combustion properties and fire behavior of an IEEE-383 qualified flame retardant cable. The reference reaction rate and reference temperature which are commonly used in pyrolysis model of fire propagation process was obtained by the thermo-gravimetric analysis of the cable component materials. The mass fraction of FR-PVC sheath abruptly decreased near temperature range of $250{\sim}260^{\circ}C$ and its maximum reaction rate was about $2.58{\times}10^{-3}$[1/s]. For the XLPE insulation of the cable, the temperature causing maximum mass fraction change was ranged about $380{\sim}390^{\circ}C$ and it has reached to the maximum reaction rate of $5.10{\times}10^{-3}$[1/s]. The flame retardant cable was burned by a pilot flame meker buner and the burning behavior of the cable was observed during the fire test. Heat release rate of the flame retardant cable was measured by a laboratory scale oxygen consumption calorimeter and the mass loss rate of the cable was calculated by the measured cable mass during the burning test. The representative value of the effective heat of combustion was evaluated by the total released energy integrated by the measured heat release rate and burned mass. This study can contribute to study the electric cable fire and provide the pyrolysis properties for the computational modeling.

• Polymer(Korea)
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• v.24 no.6
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• pp.777-786
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• 2000

Fire resistance and thermal stability of polypropylene composite systems were investigated by using several halogenated fire-retardants such as decabromodiphenyl oxide (DBDPO) and chlorinated paraffin wax (CPW). The fire resistance of composite systems was thoroughly examined by measuring limited oxygen index (LOI, ASTM D2863, ISO 4589) and characteristic properties of cone calorimetry(ASTM E1354, ISO 5660) heat release rates (HRR), time to ignition (TTI), total heat release (THR), effective heat of combustion (EHC), mass loss rates, etc. Comparing the cone calorimetry experimental results of the halogen flame retardants, DBDPO exhibited twice higher efficiency than CPW in polypropylene systems, and the LOI also showed similar trends to cone calorimetry. The thermo-oxidative stability of the composite systems was increased about 30-5$0^{\circ}C$ in thermogravimetry analysis.Collectively, the combustion, extinction and thermally-stable characteristics of flame retardants were identified in this study.