• Title/Summary/Keyword: Fixed Bed

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Adsorption/Desorption Properties of VOCs on Activated Carbon Fiber (ACF를 이용한 휘발성 유기화합물(VOCs)의 흡착/탈착 특성)

  • Baek, Geun-Ho;Kim, Jung-Su;Jang, Hyen-Tae;Kim, Hyeong-Wan;Kim, Hyeong-Joo;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.5
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    • pp.2439-2444
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    • 2011
  • We investigated the adsorption/desorption property of volatile organic compounds(VOC) by using activated carbon fibers(ACF) instead of activated carbon(AC) which is conventionally used. The adsorption behavior of the fixed bed and the breakthrough characteristics were also studied. As a result, ACFj showed 1.15 times higher adsorption amount as compared to AC. The breakthrough Point and adsorption amount of VOCs were decreased with the increase of temperature. In the case of AC, desorption time having 99% removal efficiency was about as minutes, but that of ACF was about 5 minutes at same condition.

Operation characteristics of partial oxidation reformer for transportation fuels (수송 연료용 부분산화 개질기의 운전특성)

  • Lee, Sangho;Bae, Joongmyeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.159.1-159.1
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    • 2011
  • Partial oxidation reformer was fabricated and operated using commercial transportation fuels. Fuel injector and heating coil were used for fuel atomization and startup, respectively. The reformer was designed to produce syngas for $150{\sim}200W_e$ class solid oxide fuel cell. The reformer was operated in the $O_2$/C range between 0.6 and 0.8 while the capacity was fixed at $150W_e$. The temperature range in catalyst bed was between $500^{\circ}C$ and $900^{\circ}C$. Only 83% fuel was converted to $H_2$, CO, $CO_2$ and $CH_4$ at the operating conditions. The lowest temperature increase to $700^{\circ}C$ when the reformer was operated at $200W_e$, Although the temperature profiles was improved, fuel conversion was 88%. On the other hand, fuel was completely converted when micro-reactor operated at the same condition. This difference maybe due to aromatic compounds formation at homogeneous region. In addition, a significant amount of coke deposition was observed at vent line. Homogeneous reaction depends on the degree of mixing. For this purpose, two fluid nozzle and Ultra sonic injector were compared to investigate the effect of atomization. Sauter mean diameter(SMD) of Ultra sonic injector was lower than two-fluid nozzle at test condition. However, conversion efficiency and fuel conversion were not improved by using two-fluid nozzle. these results imply that the temperature of homogeneous reaction region should be controlled to prevent coke formation.

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Process Optimization of Red Pepper Drying for the Improvement of Drying Efficiency (건조효율 향상을 위한 고추건조공정의 최적화)

  • Chung, Sun-Kyung;Keum, Dong-Hyuk;Lee, Dong-Sun
    • Korean Journal of Food Science and Technology
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    • v.24 no.5
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    • pp.428-439
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    • 1992
  • Drying process in a fixed bed red pepper dryer was modeled and simulated. Drying efficiency describing the effectiveness of energy usage in red pepper drying was defined as a ratio of energy used for moisture evaporation to total energy consumption, and expressed in combination of measurable temperature variables. The efficiency was compared with real evaporative efficiency and tested in the simulated and experimental drying. An overall drying efficiency was derived, and analyzed for various control variables consisting of drying temperature, air recycle ratio and air flow rate. Optimal operation conditions of drying was then searched by Box's complex method by using it as an objective function. Carotenoids retention was simulated and put as a constraint of product quality in the optimization. The optimization results gave that two staged drying operation could improve the ding efficiency compared with single staged drying. As a technique for further energy saving automatic termination of drying appeared feasible by monitoring an exit air temperature from dryer.

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The Effect of Promoters Addition on NOx Removal by $NH_3$ over V$V_2O_5/TiO_2$

  • Lee, Keon-Joo
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E1
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    • pp.29-36
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    • 2002
  • The selective catalytic reduction (SCR) reaction of promoter catalysts was investigated in this study. A pure anatase type of TiO$_2$ was used as support. Activation measurement of prepared catalysts was practiced on a fixed reactor packing by the glass bead after filling up catalysts in 1/4 inch stainless tube. The reaction temperature was measured by K-type thermocouple and catalyst was heated by electric furnace. The standard compositions of the simulated flue gas mixture in this study were as follows: NO 1,780ppm, NH$_3$1,780ppm, $O_2$1% and $N_2$ as balance gas. In this study, gas analyzer was used to measure the outgassing gas. Catalyst bed was handled for 1hr at 45$0^{\circ}C$, and the reactivity of the various catalyst was determined in a wide temperature range. Conversion of NH$_3$/NO ratio and of $O_2$ concentration was practiced at 1,1.5 and 2, respectively. The respective space velocity were as follows . 10,000, 15,000 and 17,000 hr-1. It was found that the maximum conversion temperature range was in a 5$0^{\circ}C$. It was also found toi be very sensitive at space velocity, $O_2$ concentration, and NH$_3$/NO ratio. We also noticed that the maximum conversion temperature of (W, Mo, Sn) -V$_2$O$_{5}$/TiO$_2$ catalysts was broad. Specially WO$_3$-V$_2$O$_{5}$TiO$_2$2 catalyst appeared nearly 100% conversion at not only above 30$0^{\circ}C$ ut also below 25$0^{\circ}C$. At over 30$0^{\circ}C$, NH$_3$ oxidation decreased with decrease of surface excess oxygen. In addition, WO$_3$-V$_2$O$_{5}$TiO$_2$ catalyst did not appear to affect space velocity, $O_2$ concentration, and NH$_3$/NO ratio.ratio.

Solid-State Fermentation for the Production of Meroparamycin by Streptomyces sp. strain MAR01

  • El-Naggar, Moustafa Y.;El-Assar, Samy A.;Abdul-Gawad, Sahar M.
    • Journal of Microbiology and Biotechnology
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    • v.19 no.5
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    • pp.468-473
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    • 2009
  • The antibiotic meroparamycin was produced in the free culture system of Streptomyces sp. strain MAR01. Five solid substrates (rice, wheat bran, Quaker, bread, and ground corn) were screened for their ability to support meroparamycin production in solid-state fermentation. In batch culture, wheat bran recorded the highest antibacterial activity with the lowest residual substrate values. The highest residual substrate values were recorded for both ground corn and Quaker. On the other hand, no antibacterial activity was detected for rice as a solid substrate. The use of the original strength of starch-nitrate medium in the solid-state fermentation gave a lower antibacterial activity compared with the free culture system. Doubling the strength of this medium resulted in the increase in the activity to be equivalent to the free culture. The initial pH (7.0) of the culture medium and 2 ml of spore suspension (1 ml contains $5{\times}10^{9}spores/ml$) were the optima for antibiotic production. The water was the best eluent for the extraction of the antibiotic from the solid-state culture. Ten min was enough time to extract the antibiotic using a mixer, whereas, 60 min was required when shaking was applied. Semicontinuous production of meroparamycin using a percolation method demonstrated a more or less constant antibacterial activity over 4 runs ($450-480{\mu}g/ml$). The semicontinuous production of the antibiotic was monitored in a fixed-bed bioreactor and the maximum activity was attained after the fourth run ($510{\mu}g/ml$) and the overall process continued for 85 days.

Physical Properties and Sulfidation Kinetics of Mn-Based Sorbent for Hydrogen Sulfide Removal (황화수소 제거를 위한 망간계 탈황제의 물리적 특성과 황화반응 속도)

  • Oh, Kwang-Joong;Shon, Byung-Hyun;Choi, Eun-Hwa;Yi, Gang Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2067-2076
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    • 2000
  • The experiments have been made to develop manganese-based sorbent(MT, MFT) for the removal of hydrogen sulfide from simulated hot coal gases. Manganese-based sorbents were tested in an ambient-pressure fixed-bed reactor to calculate H2S removal efficiency. and a three hole jet attrition tester to characterize the sorbent physical properties. According to the experimental results of attrition test. the attrition resistance of 5% bentonite containing sorbent was higher than that of 2% bentonite. The attrition resistances of both sorbents increased with induration temperature. Effects of sulfidation temperature. space velocity. and $H_2S$ concentrations on the $H_2S$ removal efficiency were investigated. Experimental results showed that $H_2S$ could be removed from 5,100ppmv to 20ppmv at $450^{\circ}C$, and to 30~65ppmv at $550{\sim}650^{\circ}C$ for both MT/MFT sorbents. As for the change of space velocity, the breakthrough time was decreased with space velocity.

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Adsorption of Textile Wastewater on Sawdust (톱밥에 의한 염색폐수의 흡착처리)

  • Kim, Tak-Hyun;Park, Chul-Hwan;Kim, Sang-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.439-445
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    • 2008
  • Sawdust is considered one of the cheapest and abundantly available adsorbents, and it is not necessary to regenerate. The spent sawdust can be incinerated or reused as a fuel. The sawdust adsorption can be applied to the removal of color and metal cations from the wastewater. The aim of this study was to evaluate the adsorptive capacities of sawdust with respect to color, COD, SS, turbidity, metal cation from textile wastewater. Langmuir, Freundlich, BET and Sips adsorption isotherm were obtained for the sawdust adsorption of Fe(III). The effects of particle size and amount of sawdust on the adsorption of Fe(III) were also studied. COD, SS, color, turbidity and Fe(III) removal efficiencies were examined at the continuous fixed-bed adsorption test. It was showed the removal efficiencies of SS 50.0%, Fe(III) 25.0%, turbidity 79.4%, color 48.6% and COD 50.9%. In addition, the changes of surface structure between before and after adsorption were investigated through SEM analysis. It is confirmed that the waste sawdust can be successfully used as an adsorbent for wastewater treatment.

Flow Simulation in a Meandering Channel using a 2-dimensional Numerical Model (이차원 수치모형을 이용한 사행하도 흐름모의)

  • Lee, Haegyun;Lee, Namjoo
    • The Journal of the Korea Contents Association
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    • v.13 no.5
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    • pp.485-492
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    • 2013
  • The point sand bars of Hahoi Village on Nakdong River have undergone considerable changes including fluvial and vegetation characteristics due to flood regulation by the dams constructed upstream. In this study, the numerical fluvial/sediment and water quality model, KU-RLMS, is applied to the aquatic area near Hahoi Village (middle/upper region of the Nakdong River) for clarifying the mechanisms of changes in hydraulic and aquatic characteristics. The fixed-bed hydraulic experiment was carried out for horizontal two-dimensional numerical model. The numerical simulation reveals that flow is accelerated near the left bank of Booyongdae downstream of the Hahoi Village area. Circulatory flow pattern was observed at the right bank downstream of Hahoi Village. The simulation was in good agreement with the hydraulic/physical experiment. For the discharge of design flood, at the area of circulatory flow pattern, the superelevation of about 1.0 m at the right bank was predicted compared to the left bank of high flow velocity, which is also in good agreement with hydraulic experiment.

Activity Changes of Supported Nickel Catalysts with Respect to Ni Loading (니켈 담지촉매의 니켈 담지량에 따른 활성 변화)

  • Kim, Sang-Bum;Park, Eun-Seok;Cheon, Han-Jin;Kim, Young-Kook;Kim, Myung-Soo;Park, Hong-Soo;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.3
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    • pp.230-236
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    • 2003
  • Synthesis gas is commercially produced by a steam reforming process. However, the process is highly endothermic and energy-consuming. Thus, this study was conducted to produce synthesis gas by the partial oxidation of methane to decrease the energy cost. Supported Ni catalysts were prepared by the impregnation method. To examine the activity of the catalysts, a differential fixed bed reactor was used, and the reaction was carried out at $750{\sim}850^{\circ}C$ and 1 atm. The fresh and used catalysts were characterized by XRD, XPS, TGA and AAS. The highest catalytic activity was obtained with the 13wt% Ni/MgO catalyst, with which methane conversion was 81%, and $H_2$ and CO selectivities were 94% and 93%, respectively. 13wt% Ni/MgO catalyst showed the best $MgNiO_2$ solid solution state, which can explain the highest catalytic activity of the 13wt% Ni/MgO catalyst.

A Study on User Behavior Analysis for Deriving Smart City Service Needs (스마트시티 서비스 니즈 도출을 위한 사용자 행위 분석에 관한 연구)

  • An, Se-Yun;Kim, So-Yeon
    • The Journal of the Korea Contents Association
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    • v.18 no.7
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    • pp.330-337
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    • 2018
  • Recently, there has been a growing interest in user-centered smart city services. In this study, user behavior analysis was performed as a preliminary study for user - centered smart city service planning. In particular, we will use GIS based location analysis data and video ethonography methodology to derive smart city service direction and needs. In this study, the area of Daejeon Design District selected as the Smart City Test bed was selected as the survey area and the location analysis data of the traffic accident analysis system of the road traffic corporation and the fixed camera We observed user's behavior type and change with image data extracted through the technique. Location analysis data is classified according to the type of accident, and image data is classified into 11 subdivided types of user activities. The problems and specificities observed were analyzed. The user behavior characteristics investigated through this study are meaningful to provide a basis for suggesting user - centered smart city services in the future.