• 제목/요약/키워드: Film Form

검색결과 1,082건 처리시간 0.033초

Electrochemical treatment of wastewater using boron doped diamond electrode by metal inter layer

  • KIM, Seohan;YOU, Miyoung;SONG, Pungkeun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.251-251
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    • 2016
  • For several decades, industrial processes consume a huge amount of raw water for various objects that consequently results in the generation of large amounts of wastewater. Wastewaters are consisting of complex mixture of different inorganic and organic compounds and some of them can be toxic, hazardous and hard to degrade. These effluents are mainly treated by conventional technologies such are aerobic and anaerobic treatment and chemical coagulation. But, these processes are not suitable for eliminating all hazardous chemical compounds form wastewater and generate a large amount of toxic sludge. Therefore, other processes have been studied and applied together with these techniques to enhance purification results. These include photocatalysis, absorption, advanced oxidation processes, and ozonation, but also have their own drawbacks. In recent years, electrochemical techniques have received attention as wastewater treatment process that could be show higher purification results. Among them, boron doped diamond (BDD) attract attention as electrochemical electrode due to good chemical and electrochemical stability, long lifetime and wide potential window that necessary properties for anode electrode. So, there are many researches about high quality BDD on Nb, Ta, W and Si substrates, but, their application in effluents treatment is not suitable due to high cost of metal and low conductivity of Si. To solve these problems, Ti has been candidate as substrate in consideration of cost and property. But there are adhesion issues that must be overcome to apply Ti as BDD substrate. Al, Cu, Ti and Nb thin films were deposited on Ti substrate to improve adhesion between substrate and BDD thin film. In this paper, BDD films were deposited by hot filament chemical vapor deposition (HF-CVD) method. Prior to deposition, cleaning processes were conducted in acetone, ethanol, and isopropyl alcohol (IPA) using sonification machine for 7 min, respectively. And metal layer with the thickness of 200 nm were deposited by DC magnetron sputtering (DCMS). To analyze microstructure X-ray diffraction (XRD, Bruker gads) and field emission scanning electron microscopy (FE-SEM, Hitachi) were used. It is confirmed that metal layer was effective to adhesion property and improved electrode property. Electrochemical measurements were carried out in a three electrode electrochemical cell containing a 0.5 % H2SO4 in deionized water. As a result, it is confirmed that metal inter layer heavily effect on BDD property by improving adhesion property due to suppressing formation of titanium carbide.

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즉석편의 식품용 포장재의 전자레인지 가열에 의한 변형 원인 분석 (Analysis of the Causes of Deformation of Packaging Materials Used for Ready-to-Eat Foods after Microwave Heating)

  • 윤찬석;홍승인;조아름;이화신;박현우;이근택
    • 한국식품과학회지
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    • 제47권1호
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    • pp.63-69
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    • 2015
  • 전자레인지 가열조리용 편의식품류는 레토르트 처리되어 장기간 저장 안정성이 부여되는 장점이 있는 반면, 높은 가열 조건으로 인하여 식품의 품질 저하뿐 아니라 내용물의 흡착에 의한 포장재의 착색이나 오렌지필과 같은 물리적 변화가 발생되기도 한다. 일부 매운 소스 제품들의 전자레인지 가열 조리 시 특정 부위에서 심한 포장재의 열 변형 현상이 확인되었다. 열화상카메라와 광섬유온도계를 이용하여 전자레인지 가열 중 포장재 내부의 온도 분포 및 변화 패턴을 관찰한 결과 내용물의 충진 경계인 액위선과 양 모서리 sealing 부위의 온도가 가장 높이 상승하여 hot spot이 형성되는 것을 확인하였고, 이때 온도는 순간적으로 최대 $190^{\circ}C$까지 상승하였다. 반면 내용물의 중심부에서는 온도 상승이 매우 느리게 이루어져 cold spot이 생성되었으며, 700W에서 2분 조리 후 도달 온도는 약 $55^{\circ}C$였다. 특히, 전자레인지 가열 시 내용물의 균일한 가열패턴을 보여주는 hot spot과 cold spot 사이의 온도 상승률은 최대 7,000배까지 차이를 보였다. 따라서 전자레인지 조리 시 내용물의 불균일한 가열로 특정 부위에 열이 집중되는 hot spot의 생성이 포장재 열 변형의 주요 원인으로 판단되었다. 이러한 가열 불균일성은 포장된 내용물에 함유된 당, 염, 수분과 같은 성분들이 점도에 영향을 주는 것에 기인하는 것으로 추측된다. 이러한 점도 변화는 궁극적으로 내용물의 물리적 또는 이온적 특성의 변화를 야기하고, 결과적으로 전자파가 내용물 내부로 침투하는 깊이가 감소되고, 이에 따라 내용물의 유전 특성과 대류 현상에 영향을 주는 것으로 판단된다. 그러나 전자레인지 조리 시 포장재 열 변형 문제의 완전한 해결을 위해서는 향후 포장된 내용물의 세부 성분 별 유전 특성에 대한 보다 세밀한 분석이 필요하며, 아울러 hot spot의 원인이 되는 식품 성분들의 적절한 함량 조절과 함께 포장재, 포장 형태 및 가열 조건 등에 대한 보다 포괄적이고 안정적인 포장시스템 설계와 개발이 필요할 것으로 판단된다.

사회적 쟁점에 대한 발언으로서 다큐멘터리의 수사학 연구: EBS-TV <지식채널(e)>를 중심으로 (The Study of Documentaries' 'Rhetoric' as a Statement on Social Issues: Focused on EBS-TV )

  • 김남일;이규정
    • 한국언론정보학보
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    • 제53권
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    • pp.53-72
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    • 2011
  • 이 연구는 2004년 방송 이후, EBS의 대표적인 프로그램으로 자리 잡은 <지식채널(e)>를 미디어 텍스트로 보고, 그 구성방법과 사회적 의미를 분석하기 위해 빌 니콜스의 '수사학'에 관한 논의를 바탕으로 연구를 수행하였다. 결과적으로 첫째, <지식채널(e)>는 한국 사회의 시의성 있는 주요 이슈를 대상으로 이와 관련된 '지식'을 동원하여 다큐멘터리라는 형식을 빌려 현실사회에 대한 적극적인 발언을 하고 있음을 알 수 있었다. 둘째, 이 프로그램은 의미발생과정에서 '수사학'이 중요한 역할을 하고 있는데, 비교적 짧은 텍스트임에도 불구하고 의미생산을 위한 '수사학적 과정'이 충실하게 반영되어 있다. 더구나 이 프로그램은 현실사회 이슈에 대한 적극적인 문제제기와 독특한 영상구성 방식을 채택하여 감성적 충격을 강화함으로써 새로운 의미생산 구조를 성공적으로 구현하고 있었다. 셋째, 이를 심층적으로 사회 문화적인 맥락에서 분석하면 <지식채널(e)>는 우리 사회의 지배적 이데올로기를 극복하고 새로운 이데올로기를 생성하는 이데올로기적 투쟁의 장을 형성하고 있을 뿐 아니라, 시청자들에게는 지배적 이데올로기를 뒤엎는 전복적 즐거움까지 주고 있음을 알 수 있었다. 그런 배경에서 이 연구는 흔히 접할 수 있는 우리 주변의 '지식'이 나름대로의 정치성을 띠고 있으며, 특히 이 프로그램은 한국 방송 문화에서 중요한 문화정치적인 의미를 지닌 미디어 텍스트라는 점을 알 수 있었다. 결론적으로 이 프로그램은 '지식'을 매개로 '수사학적 과정'을 통해 현실 사회에 적극적인 발언을 수행함으로써 '지식저널리즘'의 역할을 하고 있음을 알 수 있었다.

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병(病)-의원(醫院)의 X선촬영업무(線撮影業務)에 관한 실태조사(實態調査) (Survey on Radiographic Works in Hospitals and Clinics)

  • 최종학;전만진;박성옥;임한영;김건중;허준;최종운
    • 대한방사선기술학회지:방사선기술과학
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    • 제7권1호
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    • pp.3-11
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    • 1984
  • The major findings of this investigation on radiographic works in 125 medical institutions around Seoul and Kyung-Ki area, from March 1983 to February 1984, are summarized as follows. 1. The number of references provided on radiographic techniques were 3 to 5 in general hospitals (52.1%), in hospitals (58.5%), and clinics (44.5%), and only the 10.4% of general hospitals had 11 or more. 2. The relatively high percentages of 75.0% of general hospitals and 68.3% of hospitals have established the standardized radiographic methods for regions examined, but most clinics (61.1%) have not. 3. As a log system for the radiographic request, the method of "routine study, or all the x-ray examinations are marked as 0 on a printed form" was most commonly used by general hospitals (62.5%) and hospitals (51.2%), and "the doctors employ their own methods" in most clinics (44.6%). 4. In the 85.4% of general hospitals, the 68.3% of hospitals and the 38.9% of clinics, the data such as diagnosis, clinic history, purpose of x-ray examination were recorded on a radiographic request at all times, or at least in part. 5. On a scale of hardness and easiness of order of doctors, the greatest response was "fairly easy to understand", and the 37.5% of general hospitals responded as "sometimes hard". 6. In determining the standards for radiographic factors, the general hospitals (62.5%) and hospitals (65.9%) adapted mostly "a departmental check list", and the clinics (61.1%) used mainly "a personal decision". 7. In using the immobilizing devices, angligner, and radiographic accessories, the Percentages were high in general hospitals and hospitals on the one hand, and were low in clinics on the other. 8. A consideration with regard to the devices for an improvement of examination of the same patients was totally ignored by the 50.0% of clinics, the 26.8% of hospitals and the 20.8% of general hospitals. 9. The causes of re-examination were due largely to patients (33.6%), and followed proportionately by incorrect exposure (22.8%), errors in positioning (22.0%), film processing faults (9.2%), conditions of x-ray equipments (8.8%), and quality of x-ray films (3.6%). 10. The conference on radiography was conducted regularly or irregularly by the 87.5% of general hospitals, the 56.1% of hospitals, and the 27.7% of clinics, and the meeting was proceeded only by radiologic technologists.

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후면 형상에 따른 결정질 실리콘 태양전지의 후면전계 형성 및 특성 (Back Surface Field Properties with Different Surface Conditions for Crystalline Silicon Solar Cells)

  • 김현호;김성탁;박성은;송주용;김영도;탁성주;권순우;윤세왕;손창식;김동환
    • 한국재료학회지
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    • 제21권5호
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    • pp.243-249
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    • 2011
  • To reduce manufacturing costs of crystalline silicon solar cells, silicon wafers have become thinner. In relation to this, the properties of the aluminium-back surface field (Al-BSF) are considered an important factor in solar cell performance. Generally, screen-printing and a rapid thermal process (RTP) are utilized together to form the Al-BSF. This study evaluates Al-BSF formation on a (111) textured back surface compared with a (100) flat back surface with variation of ramp up rates from 18 to $89^{\circ}C$/s for the RTP annealing conditions. To make different back surface morphologies, one side texturing using a silicon nitride film and double side texturing were carried out. After aluminium screen-printing, Al-BSF formed according to the RTP annealing conditions. A metal etching process in hydrochloric acid solution was carried out to assess the quality of Al-BSF. Saturation currents were calculated by using quasi-steady-state photoconductance. The surface morphologies observed by scanning electron microscopy and a non-contacting optical profiler. Also, sheet resistances and bulk carrier concentration were measured by a 4-point probe and hall measurement system. From the results, a faster ramp up during Al-BSF formation yielded better quality than a slower ramp up process due to temperature uniformity of silicon and the aluminium surface. Also, in the Al-BSF formation process, the (111) textured back surface is significantly affected by the ramp up rates compared with the (100) flat back surface.

다층구조박막으로부터 $PbTiO_3$ 박막 제조시 요소층이 상형성 및 유전특성에 미치는 영향 (An effect of component layers on the phases and dielectric properties in $PbTiO_3$ thin films prepared from multilayer structure)

  • Do-Won Seo;Song-Min Nam;Duck-Kyun Choi
    • 한국결정성장학회지
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    • 제4권4호
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    • pp.378-387
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    • 1994
  • 선행연구[1] 즉, $Ti0_2/Pb/TiO_2(900{\AA}/900{\AA}/900{\AA}/)$ 3층구조박막으로부터 열확산에 의해 상형성이 가능하였던 $PbTiO_3$ 박막의 특성을 개선하기 위하여 스퍼터링법을 이용하여 Si기판위에 각 요소층의 두께를 $200~300 {\AA}$으로 얇게하고 적층수를 3,5,7,9,11층$(TiO_2/Pb/.../Tio_2)$으로 변화시켜가며 다층구조박막을 형성한 후 이를 RTA 처리하여 $PbTiO_3$ 박막을 제조하였다. 그 결과 $500^{\circ}C$ 이상에서 단일상의 $PbTiO_3$가 형성되었다. 또한 요소층의 두께를 얇게하고 적층수를 늘려서 열처리한 결과 Pb-silicate 및 void 생성이 억제되어 우수한 계면상태를 유지하였으며 조성도 보다 균일해지는 양상을 나타내었다. $PbTiO_3$ 박막의 MiM구조에 C-V 특성으로부터 측정된 유전상수는 열처리 조건에 따른 경향을 나타내지 않았으나 적층수가 많아져 박막의 두께가 증가 할수록 유전상수가 증가하였다. MIS 구조의 $PbTiO_3$ 박막의 I-V 특성 측정 결과 절연파괴강도는 최고 150kV/cm이었다.

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Simultaneous Transfer and Patterning of CVD-Grown Graphene with No Polymeric Residues by Using a Metal Etch Mask

  • 장미;정진혁;;이내응
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.642-642
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    • 2013
  • Graphene, two dimensional single layer of carbon atoms, has tremendous attention due to its superior property such as high electron mobility, high thermal conductivity and optical transparency. Especially, chemical vapor deposition (CVD) grown graphene has been used as a promising material for high quality and large-scale graphene film. Unfortunately, although CVD-grown graphene has strong advantages, application of the CVD-grown graphene is limited due to ineffective transfer process that delivers the graphene onto a desired substrate by using polymer support layer such as PMMA(polymethyl methacrylate). The transferred CVD-grown graphene has serious drawback due to remaining polymeric residues generated during transfer process, which induces the poor physical and electrical characteristics by a p-doping effect and impurity scattering. To solve such issue incurred during polymer transfer process of CVD-grown graphene, various approaches including thermal annealing, chemical cleaning, mechanical cleaning have been tried but were not successful in getting rid of polymeric residues. On the other hand, lithographical patterning of graphene is an essential step in any form of microelectronic processing and most of conventional lithographic techniques employ photoresist for the definition of graphene patterns on substrates. But, application of photoresist is undesirable because of the presence of residual polymers that contaminate the graphene surface consistent with the effects generated during transfer process. Therefore, in order to fully utilize the excellent properties of CVD-grown graphene, new approach of transfer and patterning techniques which can avoid polymeric residue problem needs to be developed. In this work, we carried out transfer and patterning process simultaneously with no polymeric residue by using a metal etch mask. The patterned thin gold layer was deposited on CVD-grown graphene instead of photoresists in order to make much cleaner and smoother surface and then transferred onto a desired substrate with PMMA, which does not directly contact with graphene surface. We compare the surface properties and patterning morphology of graphene by scanning electron microscopy (SEM), atomic force microscopy(AFM) and Raman spectroscopy. Comparison with the effect of residual polymer and metal on performance of graphene FET will be discussed.

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1960년대 일본의 실험적 애니메이션 (Japanese Experimental Animation in 1960s)

  • 박기령
    • 만화애니메이션 연구
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    • 통권29호
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    • pp.37-60
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    • 2012
  • 본 논문은 1960년 일본에서 "애니메이션 3인의 회" 결성이 계기가 되어 이후 새로운 흐름을 형성한 애니메이션의 경향을 실험적 애니메이션으로서 규정하고 그 양상을 논한 것이다. 실험적 애니메이션은 대개 전통적인 애니메이션과 상반되는 경향을 보여준다. "애니메이션 3인의 회"는 종래의 만화 영화의 형식을 타파하는 다양한 시도를 통해 애니메이션의 개념을 새롭게 제시하고자 했다. 당시 일본에서 만화 영화 형식의 주류를 이룬 토에이 동화의 장편 작품과 "애니메이션 3인의 회"의 중심적인 역할을 한 쿠리 요지의 작품을 비교할 때 움직임의 표현과 소재 선택에서 상반된 특징이 나타난다. 이것은 주류의 대안적인 방법이었다. 한편 또 다른 멤버인 야나기하라 료헤이와 마나베 히로시는 각각 디자인과 일러스트를 애니메이션에 접목시켰다. "애니메이션 3인의 회"가 주최한 상영회 및 애니메이션 페스티발에 참여한 여러 장르 출신의 인디펜던트 작가들은 타 장르와 서로 교류하면서 창작 활동을 했다. 그들의 작품에 나타난 인터미디어적 특성은 애니메이션에서 움직임의 대상을 확대하여 새로운 표현의 가능성을 모색하고자한 시도로 볼 수 있겠다. 이렇게 3인을 비롯한 인디펜던트 작가들의 소재와 움직임의 표현 및 대상에 대한 탐구는 전통적인 애니메이션의 경향을 타파한 것으로서 실험적 애니메이션에 속하는 것이었다. 3인의 시도는 1960년대 일본의 실험적 애니메이션이 성립하는 바탕이 되었으며 그들의 실험 정신은 이후 시대별로 변용하여 최근 일본 애니메이션의 인디펜던트 작가들의 참신하고 진보적인 표현에 계승되고 있다고 여겨진다. 1960년대의 양상이 이러한 표현의 역사상의 출발점이라는 것을 강조한 데에 본 고찰의 의의가 있다고 하겠다.

Aluminum Powder Metallurgy Current Status, Recent Research and Future Directions

  • Schaffer, Graham
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2001년도 추계학술강연 및 발표대회
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    • pp.7-7
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    • 2001
  • The increasing interest in light weight materials coupled to the need for cost -effective processing have combined to create a significant opportunity for aluminum P/M. particularly in the automotive industry in order to reduce fuel emissions and improve fuel economy at affordable prices. Additional potential markets for Al PIM parts include hand tools. Where moving parts against gravity represents a challenge; and office machinery, where reciprocating forces are important. Aluminum PIM adds light weight, high compressibility. low sintering temperatures. easy machinability and good corrosion resistance to all advantages of conventional iron bm;ed P/rv1. Current commercial alloys are pre-mixed of either the AI-Si-Mg or AL-Cu-Mg-Si type and contain 1.5% ethylene bis-stearamide as an internal lubricant. The powder is compacted in closed dies at pressure of 200-500Mpa and sintered in nitrogen at temperatures between $580~630^{\circ}C$ in continuous muffle furnace. For some applications no further processing is required. although most applications require one or more secondary operations such as sizing and finishing. These sccondary operations improve the dimension. properties or appearance of the finished part. Aluminum is often considered difficult to sinter because of the presence of a stable surface oxide film. Removal of the oxide in iron and copper based is usually achieved through the use of reducing atmospheres. such as hydrogen or dissociated ammonia. In aluminum. this occurs in the solid st,lte through the partial reduction of the aluminum by magncsium to form spinel. This exposcs the underlying metal and facilitates sintering. It has recently been shown that < 0.2% Mg is all that is required. It is noteworthy that most aluminum pre-mixes contain at least 0.5% Mg. The sintering of aluminum alloys can be further enhanced by selective microalloying. Just 100ppm pf tin chnnges the liquid phase sintering kinetics of the 2xxx alloys to produce a tensile strength of 375Mpa. an increilse of nearly 20% over the unmodified alloy. The ductility is unnffected. A similar but different effect occurs by the addition of 100 ppm of Pb to 7xxx alloys. The lend changes the wetting characteristics of the sintering liquid which serves to increase the tensile strength to 440 Mpa. a 40% increase over unmodified aIloys. Current research is predominantly aimed at the development of metal matrix composites. which have a high specific modulus. good wear resistance and a tailorable coefficient of thermal expnnsion. By controlling particle clustering and by engineering the ceramic/matrix interface in order to enhance sintering. very attractive properties can be achicved in the ns-sintered state. I\t an ils-sintered density ilpproaching 99%. these new experimental alloys hnve a modulus of 130 Gpa and an ultimate tensile strength of 212 Mpa in the T4 temper. In contest. unreinforcecl aluminum has a modulus of just 70 Gpa.

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프로리포솜을 이용한 클렌부테롤의 경피흡수 제제화 (Proliposomal Clenbuterol Patch for Transdermal Delivery)

  • 이영주;정석재;이민화;심창구
    • Journal of Pharmaceutical Investigation
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    • 제27권4호
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    • pp.303-311
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    • 1997
  • Proliposomal patch of clenbuterol, ${\beta}_2-agonist$ bronchodilator, was prepared and its feasibility as a novel transdermal drug delivery system was examined. Proliposomal granules containing clenbuterol was prepared by a standard method using sorbitol and lecithin with (Rx 2) or without cholesterol (Rx 1). The porous structure of sorbitol in the proliposomes was maintained allowing tree flowability of the granules. Following contact with water, the granules were converted probably to liposomes almost completely within several minutes. It indicates that proliposomes may be hydrated, when they are applied on the skin under occlusive condition in vivo, by the sweat to form liposomes. Clenbuterol release from Rx 1 and Rx 2 proliposomes to pH 7.4 isotonic phospate buffer (PBS) across cellulose membrane (mol. wt. cut-off of 12000-14000) was retarded significantly compared with that from the mixture of clenbuterol powder and blank proliposomes. Interestingly, proliposomes prepared with lecithin and cholesterol (i.e., Rx 2 proliposomes) showed much more retarded release of clenbuterol than proliposomes prepared only with lecithin (i.e.. Rx 1 proliposomes), indicating that clenbuterol release from proliposomes can be controlled by the addition of cholesterol to the proliposomes. Proliposomal patches were prepared using PVC film as an occlusive backing sheet, two sides adhesive tape (urethane, 1.45 mm thickness) as a reservoir for proliposome granules and Millipore MF-membrane (0.45 mm pore size) as a drug release-controlling membrane. Rx 1 or Rx 2 proliposomes containing 4.6 mg of clenbuterol were loaded into the reservoir of the patch. Clenbuterol release from the patches to pH 7.4 PBS was determined using USP paddle (50 rpm)-over-disc release method. Clenbuterol release from the proliposomal patches was much more retarded even than from a matrix type clenbuterol patch (Boehringer Ingelheim ltd). Being consistent with clenbuterol release from the proliposomal granules, the release from the patches was highly dependent on the presence of cholesterol in the proliposomes : Patches containing Rx 2 proliposomes showed several fold slower drug release than patches containing Rx 1 proliposomes. When the patch containing Rx 1 proliposomes was applied on to the back of a hair-removed rat, clenbuterol concentration in the rat blood was maintained during 6-72 hrs. Transdermal absorption of clenbuterol from the patch was accelerated when the patch was prehydrated with 50 ml of pH 7.4 PBS before topical application. Above results indicate that sustained transdermal delivery of clenbuterol is feasible using proliposomal patches if the cholesterol content and pore size of the release rate-controlling membrane of patches, for example, are appropriately controlled.

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