• Title/Summary/Keyword: Filler contents

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Wear Particulate Matters and Physical Properties of Silica filled ENR/BR Tread Compounds according to the BR Contents

  • Ryu, Gyeongchan;Kim, Donghyuk;Song, Sanghoon;Lee, Hyun Hee;Ha, Jin Uk;Kim, Wonho
    • Elastomers and Composites
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    • v.56 no.4
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    • pp.243-249
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    • 2021
  • The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, we investigated the effect of varying the content of butadiene rubber (BR) on the properties of the rubber compounds and the amount of particulate matter in the TBR tire tread compound. Furthermore, we utilized carbon black in the NR/BR blend compounds owing to its excellent compatibility, and we used silica in the ENR-25/BR blend compounds because it can interact chemically with epoxide groups. The NR/BR blend compounds and the ENR-25/BR blend compounds were evaluated by varying their BR content between 20 phr and 30 phr. The results showed that the ENR-25/BR blend compounds had superior wear resistance than the NR/BR blend compounds. This was caused by the interaction between silica and ENR. In addition, it was confirmed that the increased wear resistance as the BR content increased. Furthermore, compared to the NR/BR blend compounds, ENR-25/BR blend compounds exhibited a lower tan 𝛿 value at 60℃ because silica was used as filler. This indicates a higher fuel efficiency. The measurement results for wear particulate matter showed that as increasing the BR content resulted in generation of less wear particulate matter. This was caused by the increased wear resistance. Moreover, the ENR-25/BR blend compounds with excellent filler-rubber interaction exhibited lower quantities of generated wear particulate matters as compared to the NR/BR blend compounds.

Study on the Curing Safety of Thermosetting Resin Mold Meterial (열경화성수지 성형재료의 경화 안전성에 관한 연구)

  • 최일곤;최재욱;김상렬
    • Journal of the Korean Society of Safety
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    • v.12 no.1
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    • pp.71-76
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    • 1997
  • In this paper, it was described results of study on curing safety of molding meterial, about the variation of phenol resin contents, wood flour contents and moisture of wood flour, under the same condition. The experimental results are summarized as follows ; 1) When the curing temperature was high, the curing time was short in the case of 4~8wt% moisture of wood flour, but in the case of more than l2wt% moisture of wood flour, the curing time was long. 2) The curing time for curing temperature was more short when 6wt% moisture of wood flour than 4wt% moisture of wood flour. 3) The more wood flour content and moisture of wood flour content, the longer curing time and the more mineral filler content, the shorter curing time. 4) When the phenol resin content of main matrix increase, the curing time was short.

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Study on Manufacture and Properties of Polymer Compounds for Cable Sheath (전선피복용 고분자 컴파운드의 제조 및 물성 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.1
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    • pp.42-47
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    • 2019
  • The four different polymer compounds were manufactured to make cable sheath for ship industry. Two kinds of ethylene-vinyl acetate (EVA) were selected as main matrix polymers for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with the contents of fire retardant, silane coated aluminum hydroxide (S-ATH). Rheology, Mooney viscosity, and tensile strength increased with S-ATH contents by reinforcing effect. With increasing fire retardant amount, fire resistance increased, but cold resistance didn't show an obvious enhancement due to polar effect of vinyl acetate in EVA.

Study on Property Change with a Fire Retardant Content in the Manufacture of Polymer Composites for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.118-122
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    • 2019
  • Four different polymer compounds were manufactured to make cable sheaths for the shipping industry. Two kinds of ethylene vinyl acetate (EVA) as the main matrix polymers and EVA-grafted maleic anhydride (EVA-g-MAH) as the coupling agent were selected for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with different contents of the fire retardant, silanecoated magnesium dihydroxide (S-MDH). In the rheology evaluation, the $t_{60}$ and ${\Delta}T$ values increased with increasing S-MDH contents. On the other hand, the tensile strength decreased with increasing S-MDH content due to a relative decrease in binder polymers. With increasing S-MDH content, fire resistance increased, but cold resistance showed no obvious enhancement due to the polar effect of vinyl acetate in EVA.

Effect of organoclay on the dynamic properties of SBR compound reinforced with carbon black and silica (유기화 클레이의 첨가가 실리카 및 카본블랙를 함유한 SBR 복합체의 동적 특성에 미치는 영향)

  • Son, M.J.;Kim, W.
    • Elastomers and Composites
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    • v.41 no.4
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    • pp.260-267
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    • 2006
  • SBR (styrene-butadiene rubber; 25 wt% of solid contents) nanocomposites reinforced with OLS(organically modified layered silicates) were manufactured via the latex method. Two types of OLS are prepared, i.e. dodecylamine (primary amine) modified montmorillonite (DA-MMT) and N, N-dimethyldodecylamine (tertiary amino) modified MMT (DDA-MMT). X-ray diffraction (XRD) and transmission electron microscopy (TEM) were employed to characterize the layer distance of OLS and the morphology of the nanocomposites. SBR nanocomposites reinforced with ternary phase filler (carbon black/silica/OLS) systems also manufactured. Dynamic mechanical thermal analysis (DMTA) was performed on these composites to determine the loss factor (tan $\delta$) over a range of temperature($-20^{\circ}C{\sim}80^{\circ}C$). The results showed that there was significant changes on the values or tan $\delta$ with the addition of small amount of the OLS. By increasing the contents of OLS, the values of tan $\delta$ at $0^{\circ}C$ increased but those of tan $\delta$ at $60^{\circ}C$ decreased with increasing OLS contents.

Electromagnetic Interference Shielding Effectiveness Properties of Ag-Coated Dendritic Cu Fillers Depending on pH of Galvanic Displacement Reaction for Ag Seed Layer and Contents of Deposited Ag Layer (은 코팅 구리 덴드라이트 필러 제조 시 은 시드층 형성을 위한 갈바닉 치환반응 pH 제어 및 은함량에 따른 전자파 차폐 특성)

  • Im, Dongha;Park, Su-Bin;Jung, Hyunsung
    • Journal of the Korean institute of surface engineering
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    • v.51 no.5
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    • pp.263-270
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    • 2018
  • Ag-coated Cu dendrites were prepared as a filler for an electromagnetic interference shielding application. Ag layers on the Cu dendrites was coated by two approaches. One is a direct autocatalytic plating with a reducing agent. The other approach was achieved by two-step plating, a galvanic displacement reaction to form Ag seed layers on Cu following by an autocatalytic plating with a reducing agent. The procedure-dependent average particle size and tap density of Ag-coated Cu dendrites were characterized. The electrical resistance and electromagnetic interference shielding effect (EMI SE) were analyzed with the Ag-coated Cu dendrites prepared in the two approaches. Additionally, the content of the Ag coated on Cu dendrites was controlled from 2% to 20%. The electrical resistance and EMI SE were critically determined by Ag contents coated on Cu.

Chip Equalizer using Tap Selection Algorithm for Satellite Digital Multimedia Broadcasting (DMB) (위성 DMB용 탭 선택적 칩 등화 수신기)

  • Lee Sang-Joon;Lee Goon-Seop;Lee Dong-Hahk;Yu Jae-Hwang;Seo Jong-Soo;Byeon Jeong-Ho
    • Journal of Broadcast Engineering
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    • v.11 no.3 s.32
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    • pp.302-310
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    • 2006
  • ITU-R B.O. 1130-4 Digital System E adopted for Korean satellite DMB service is a multimedia broadcasting system based on DS-CDM-QPSK technique which broadcasts audio and video contents via the satellite or terrestrial gap-filler. However, Digital System E can not provide full loading services because the multi-channel interference (MCI) is increased due to the loss of orthogonality between signature waveforms in multipath fading channels. In this paper a chip equalizer using tap selection algorithm that enhances the receiving performance is proposed and compared to the conventional rake receiver for the satellite DMB system.

Study on the Properties of UV Curing Thermal Conductive and Pressure Sensitive Adhesive Using Inorganic Fillers

  • Oh, Ji-Hwan;Choi, Jin-Yeong;Kim, Su-Hwan;Jang, Se-Hoon;Shin, Yoo-Jin;Kim, Dae-Hyun;Yoo, Hwan-Kyu;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.22-26
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    • 2017
  • The thermal conductivity and the adhesive properties were measured, after synthesis of thermal conductive composite which was obtained as a result of mixing alumina or graphite with acrylic adhesive synthesized by UV polymerization. The adhesive properties of the composite were evaluated measuring the peel strength at 180 degrees, the retention, and the initial tack;the thermal conductivity was estimated using laser flash analysis. As the filler contents increased, a decrease in peel strength and initial tack and an increase in retention and thermal conductivity were observed. When compared to alumina, the adhesion of graphite showed a dramatic decrease, whereas the thermal conductivity was further enhanced. It was found out that the small size of graphite increased the mechanical interlocking between the polymer and the filler, and it was easier for graphite to come into contact with other graphite in the matrix.

Preparation of Urethane Nanocomposites with Inorganic Nano Fillers and Their Physical Properties (무기계 나노분말 충전 폴리우레탄 나노복합재료의 제조 및 물성)

  • Yang Yun-Kyu;Hwang Taek-Sung;Hwang Eui-Hwan
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.129-134
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    • 2006
  • Nanocomposites of polyurethane were prepared from inorganic nano particles, $Na^+-montmorillonite$ (MMT), silica, $CaCO_3$, and surface modified MMT and their properties were investigated. It was shown that the molecular weight and polydispenity of nanocomposites of polyurethane were 20000 to 28000 and 1.0 to 2.0, respectively. d-Spacing for nanocomposites of MMT were increased than that of pure MMT. Initial degradation temperature of nanocomposites were 250 to $280^{\circ}C$. And also, the range of weight loss for nanocomposites were decreased and the end of thermal degradation was observed at higher temperatures about $50^{\circ}C$. The elongation at break for $CaCO_3$ filled nanocomposites were the highest among the nanocomposites used in this study. studied. It was found that the tensile strength increased with increasing the filler contents while the silica nanocomposite exhibited the lowest increase and the $CaCO_3$ nanocomposite the highest.

Effect of Ball Milling on Photosensitive Carbon Nanotube Pastes and Their Field Emission Properties (감광성 CNT paste에 대한 저에너지 Ball Milling 처리 효과)

  • Jang, Eun-Soo;Lee, Han-Sung;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.154-154
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    • 2008
  • Although the screen printing technology using photosensitive carbon nanotube (CNT) paste has many advantages such as low cost, simple process, uniform emission, and capability of mass production, the CNT paste needs to be improved further in CNT dispersion, printability, adhesion, electrical conductivity, population of CNT emitters, etc. Ball milling has been frequently employed to prepare the CNT paste as ball milling can mix its ingredients very well and easily cut the long, entangled CNTs. This study carried out a parametric approach to fabricating the CNT paste in terms of low-energy ball milling and a paste composition. Field emission properties of the CNT paste was characterized with CNT dispersion and electrical conductivity which were measured by a UV-Vis spectrophotometer and a 4-point probe method, respectively. Main variables in formulating the CNT paste include a length of milling time, and amounts of CNTs and conductive inorganic fillers. In particular, we varied not only the contents of conductive fillers but also used two different sizes of filler particles of ${\mu}m$ and nm ranges. Among many variations of conductive fillers, the best field emission characteristics occurred at the 5 wt% fillers with the mixing ratio of 3:1 for ${\mu}m$-and nm-sizes. The amount and size of fillers has a great effect on the morphology, processing stability, and field emission characteristics of CNT emitter dots. The addition a small amount of nm-size fillers considerably improved the field emission characteristics of the photosensitive CNT paste.

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