• Title/Summary/Keyword: Fiber Dispersion

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Preparation and Properties of Waterborne Polyurethanes Based on Ttiblock Glycol $(CL)_{4.5}$-PTMG-$(CL)_{4.5}$ for Water Vapor Permeable Coatings: Effect of Soft Segment Content

  • Kwak, Yong-Sil;Kim, Han-Do
    • Fibers and Polymers
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    • v.3 no.4
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    • pp.153-158
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    • 2002
  • A series of waterborne polyurethanes (WBPU) were prepared from 4,4-dicyclohexylmethane diisocyanate ($H_{12}$MDI),2,2-bis(hydroxylmethyl) propionic acid (DMPA), othylenediarnine (EDA), triethylamine (TEA), and triblock glycol [TBG, ($\varepsilon$-caprolactone)$_{4.5}$-poly(tetramethylene ether) glycol (MW= 2000)-($\varepsilon$-caprolactone)$_{4.5}$: $(CL)_{4.5}$-PTMG-$(CL)_{4.5}$, MW=3000] as a soft segment. Two melting peaks of TBG at about 14$^{\circ}C$ and 38$^{\circ}C$ were observed indicating the presence of two different crystalline domains composed of CL and PTMG dominant component. The effect of soft segment content (60-75 wt%) on the colloidal properties of dispersion, and thermal and mechanical properties of WBPU films, the water vapor permeability (WVP) and water resistance (WR) of WBPU-coated Nylon fabrics, and the adhesive strength of WBPU- coated layer and Nylon fabrics was investigated. As soft segment contents increased, the water vapor permeability of WBPU- coated Nylon fabrics increased from 3615 to 4502 g/$m^2$day, however, the water resistances decreased from 1300 to 500 mm$H_2$O.O.

유기금속증착법에 의한 $IN_1-x$$Ga_x$$As_y$$P_1-y$/INP의 성장시 성장변수가 에피층의 전기적, 광학적 특성에 미치는 영향

  • Yu, Ji-Beom;Kim, Jeong-Soo;Chang, Dong-Hun;Park, Hyung-Ho;Oh, Dae-Gon;Lee, Yong-Tak
    • ETRI Journal
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    • v.13 no.4
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    • pp.70-79
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    • 1991
  • $In_1-x$$GA_X$$As_y$$P_1-y$ has a very wide range of applications in optoelectronic devices especially for optical communications because $In_1-x$$GA_X$$As_y$$P_1-y$ has the bandgap of the lowest dispersion ($1.3\mum$) and the lowest loss ( $1.55\mum$) of the optical fiber by changing the composition. The quality of $In_1-x$$GA_X$$As_y$$P_1-y$ epitaxial layer is believed to have a significant effect on the performance of device. The OMVPE growth conditions for the latticematched $In_1x$$GA_X$$As_y$$P_1-y$/InP were investigated. Effects of growth conditions such as V/III ratio, growth temperature, and Ga source material on the electrical and optical properties were studied. The composition, electrical and optical properities of $In_1-x$$GA_X$$As_y$$P_1-y$ were characterized using double crystal X-ray diffractometer (DCD), photoluminescence (PL), XPS(ESCA) and Hall measurement.

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A Study on Forward Error Correction of Long-Distance Submarine Optical Communication Systems (장거리 해저 광통신시스템의 순방향에러정정 기술 연구)

  • Jung, Jae-Jin;Lee, Young-Sun;Shin, Hyun-Sik
    • The Journal of the Korea institute of electronic communication sciences
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    • v.3 no.3
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    • pp.170-176
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    • 2008
  • According to the development of Internet, DWDM system needs to improve the performance for long distance transmission international optical signals. For higher the transmission capacity, we have to raise the transmission speed and increase a number of channels. To make qualifications, there are a lot of technologies such as line coding, modulation, precious fiber, broadband amplification, dispersion and forward error correction. Especially, FEC has been considered as a progressive technology for long distance transmission to carry out high speed and large capacity traffic. This paper introduced the progress of each new generation of FEC and the way to employ by current system analyzed the coding gain.

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Optical VSB Filtering of 12.5-GHz Spaced 64 × 12.4 Gb/s WDM Channels Using a Pair of Fabry-Perot Filters

  • Batsuren, Budsuren;Kim, Hyung Hwan;Eom, Chan Yong;Choi, Jin Joo;Lee, Jae Seung
    • Journal of the Optical Society of Korea
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    • v.17 no.1
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    • pp.63-67
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    • 2013
  • We perform an optical vestigial sideband (VSB) filtering using a pair of Fabry-Perot (FP) filters. The transmittance curve of each FP filter is made to have sharp skirts using an offset between input and output coupling fibers. Moreover, the accurate periodicity of FP filters in the optical frequency domain enables the simultaneous VSB filtering of a large number of optical channels. With this VSB filtering technique, we transmit 12.5-GHz spaced $64{\times}12.4-Gb/s$ wavelength-division-multiplexing channels over a single-mode fiber up to 150 km without any dispersion compensations. When the channel spacing is reduced to 10 GHz, we achieve the spectral efficiency of 1 bit/s/Hz in conventional optical intensity modulation systems up to 125 km.

Mode 1 Fracture Toughness Test of CNT/Epoxy Composites with Different CNT Content (CNT 함량에 따른 CNT/Epoxy 복합재료 제작 및 모드 1 파괴 인성 평가)

  • KWON, DONG-JUN;YOO, HYEONGMIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.86-91
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    • 2021
  • In order to save the energy in vehicles using renewable energy, it is necessary to reduce the weight of parts with polymer matrix composites. Carbon nanotube (CNT) is the nano-scale reinforcement used to increase the interlaminar strength of fiber reinforced composites or enhance the fracture toughness of polymer. However, since the degree of improvement in mechanical properties varies according to the various experimental conditions such as shape of reinforcement, types of matrix and dispersion of reinforcement, research to find the optimal conditions is essentially needed. In this study, CNT/epoxy composites with different CNT concentration were fabricated under the same conditions, and the optimal CNT content (2 wt%) was found through Mode 1 fracture toughness test. Furthermore, through optical microscopy, it was confirmed that the fracture toughness was rather decreased due to the CNT aggregation when the CNT content exceeded 2 wt%.

Physical Properties and Electrical Conductivity of PAN-based Carbon Fiber Reinforced Paper (PAN계 탄소섬유 강화 종이의 물리적 특성 및 전기전도도)

  • Jang, Joon;Lee, Chang-Ho;Park, Kwan-Ho;Ryu, Seung-Kon
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.602-608
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    • 2006
  • Carbon fiber (CF) reinforced papers using polyacrylonitrile (PAN) based CF and wood pulp were prepared by varying the lengths and the concentrations of CF, and the basis weight of paper to investigate adhesive state between CF and pulp, and physical properties and electrical conductivity of the paper. The reinforcement was caused by physical entanglement and adhesion at the interface of the different fibers rather than by chemical bonds. The tear strength and the thickness of the paper increased as increasing the concentration of CF, while the tensile and the burst strength of the paper decreased. The improved dispersion of CF in the paper was obtained from mixing shorter CF, but the maximum electrical conductivity of the paper was gained from mixing 10 mm chopped CF. The electrical conductivity of the paper increased sharply from 2 wt% to 8 wt% of CF showing S-curve, and increased linearly as increasing the basis weight of the paper. Therefore, in order to improve the electrical conductivity and the physical property of the paper, the increase of basis weight of the paper is also important as the increase of CF content in the paper.

Manufacture of Recycled PET E-Textile by Plasma Surface Modification and CNT Dip-Coating (플라즈마 표면 개질과 CNT 함침공정을 통한 고전도성의 재생PET사 전자섬유)

  • Jun-hyeok Jang;Sang-un Kim;Joo-Yong Kim
    • Science of Emotion and Sensibility
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    • v.26 no.1
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    • pp.79-86
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    • 2023
  • This study aims to create a highly conductive E-textile made by recycling PET with a Dip-coating process. PET fiber with hydrophobic properties is characterized by the difficulty in imparting great conductivity when both Virgin and Recycled are made of electronic fibers through a Dip-coating process. To advance the effectiveness of the Dip-coating process, a sample made of recycled PET was surface modified for 50 w 5 minutes and 10 minutes employing a Covance-2mprfq model from FEMTO SCIENCE. After that, the sample was immersed in an SWCNT dispersion (.1 wt%, Carbon Co., Ltd.) for 5 minutes, and then dip coating was conducted to allow the solution to permeate well into the sample through a padder (DAELIM lab). After the procedure was completed, the resistance measurement was measured with a multimeter at both ends and then accurately remeasured with a wider electrode. As a result of this contemplation, it was affirmed that great conductivity might be given through an impregnation process through the plasma surface modification. When the surface modification was performed for 10 minutes, the resistance was reduced by up to 2.880 times. Dependent on the results of this research, E-fibers employed in the smart wearable sector can also be made of recycled materials, improving smart wearable products that can save oil resources and reduce carbon emissions.

Performance evaluation of SFRC for tunnel segments based on large beam test (대형보 실험을 통한 TBM 터널 세그먼트용 강섬유보강콘크리트 성능평가)

  • Moon, Do-Young;Roh, Hwasung;Chang, Soo-Ho;Lee, Gyu-Phil;Bae, Gyu-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.16 no.3
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    • pp.287-298
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    • 2014
  • In order to develop SFRC TBM tunnel segment, evaluating the SFRC mixture was conducted through flexural tests of SFRC beams without ordinary steel reinforcement in this study. Considered variables were compressive strengths of SFRC, aspect and mix ratio of steel fibers and total 16 specimens were fabricated and tested until failure. The load-vertical displacement results demonstrates that the effect of aspect ratio is minor when compared to results form small beam test(Moon et al, 2013). A SFRC beam resists the vertical load until the width of crack reaches to 7 mm due to steel fibers across cracked surfaces. Moreover, it is found that flexural moment estimated by equation of TR No. 63(Concrete Society, 2011) is useful for prediction of nominal strength for SFRC structure. From the investigation of fiber distribution in cracked section, it is found that dispersion improved in actual size beam compared to in standard small beam for evaluation of flexural strength.

Preparation and Characterization of Polymer Coated BaTiO3 and Polyimide Nanocomposite Films (고분자로 표면 코팅된 BaTiO3와 이를 이용한 폴리이미드 나노복합필름의 제조 및 특성)

  • Han, Seung San;Han, Ji Yun;Choi, Kil-Yeong;Im, Seung Soon;Kim, Yong Seok
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.527-531
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    • 2006
  • We have prepared organophilic inorganic particles and polyimide (PI) nanocomposite having excellent thermal stability and high dielectric constant that can be used for electronic application such as capacitor. We have chosen barium titanate (BT), a high dielectric constantmaterial and its surface was coated with nylon 6 to improve the affinity with PI. The FT-IR and TEM studies showed that the organophilic inorganic particle (BTN) has a polymer shell with thickness of 5 nm. We have suggested that it is possible to control the thickness of coating surface and also indicated the relationship between the ratio of inside and outside radius of BTN and the weight fraction of BT. The PI nanocomposite films based on poly(amic acid) and BTN were prepared by cyclodehydration reaction. The homogeneous dispersion of BTN in PI matrix was identified by using SEM. We have investigated the effect of BTN content on the coefficient of thermal stability, integral procedural decomposition temperature (IPDT), and dielectric constant of PI nanocomposite films.

Effect of Carboxylic Acid Group of Functionalized Carbon Nanotubes on Properties of Electrospun Polyacrylonitrile (PAN) Fibers (기능화된 탄소나노튜브의 카르복실산이 전기방사된 폴리아크릴로니트릴 섬유의 물성에 미치는 영향)

  • Park, Ok-Kyung;Kim, Ju-Hyung;Lee, Sung-Ho;Lee, Joong-Hee;Chung, Yong-Sik;Kim, Jun-Kyung;Ku, Bon-Cheol
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.472-477
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    • 2011
  • To study the effects of the acid group of functionalized MWNT (multiwalled carbon nanotube) on the thermal and mechanical properties of polyacrylonitrile(PAN) nanofibers, acid ($H_2SO_4/HNO_3$) treated MWNT (O-MWNT) were further functionalized by diazonium salt reaction with 5-aminoisophthalic acid (IPA). Compared to O-MWNT, IPA-MWNT with isophthalic acid group showed a better dispersion stability in polar solvents and IPA-MWNT/PAN composite film displayed lower heat of reaction (${\Delta}H$) than that of homo PAN when stabilized under air atmosphere. The continuous electrospun fibers were prepared using a conductive water bath. PAN fibers containing 1 wt% of IPA-MWNT showed an increase of tensile strength by 100% and tensile modulus by 240% compared to the PAN fibers without IPA-MWNT.