• Title/Summary/Keyword: Fe-As-S system

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Antioxidative Effects of Silymarin and Silybin Purified from Silybum marianum on Lipid Peroxidation (엉겅퀴로부터 분리 정제한 Silymarin 및 Silybin의 지질 과산화에 대한 항산화 효과)

  • 이백천;박종옥;류병호
    • The Korean Journal of Food And Nutrition
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    • v.10 no.1
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    • pp.37-43
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    • 1997
  • This study was undertaken to evaluate as antioxidant activity against lipid peroxidation. Silymarin and silybin extracted from Silybum marianum were successively purified wit solvent fractionation by silica gel column chromatography. These isoflavonoid inhibited superoxide anion production in the xanthine oxidase system. In the rat liver microsomes, silymarin or silybin rapidly inhibited lipid peroxidation which was initiated enzymatically by reduced nicotinamide adenine dinucleotide phosphate(NADPH) or non-enzymatically by ascorbic acid or Fenton's reagent (H2O2+Fe2+). Mitochondrial lipid peroxidation was also inhibited by silymarin and silybin. silymarin and silybin inhibited on terminating radical chain reaction during lipid peroxidation in the enzymatic system of microsomes or in the linoleic acid hydroperoxide induced peroxidation system.

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Development of Flywheel Energy Storage System Using Superconducting Magnetic Bearing (초전도 플라이휠 에너지 저장시스템의 개발)

  • 정환명;연제욱;최재호;고창섭
    • Proceedings of the KIPE Conference
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    • 1999.07a
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    • pp.427-430
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    • 1999
  • This paper presents a S-FES(Superconducting magnetic bearing Flywheel Energy Storage System) for the purpose of replacing battery used to store the energy. Especially, the design elements of FES, such as the bearing, wheel material, and power converter, etc., is described. The design and manufacturing techniques of the controllable power converter are proposed to generate the sinusoidal output current in the high speed operation and to get the constant DC voltage in the regeneration mode. The cylindrical permanent magnet synchronous motor with halbach array of Nd-Fe-B permanent magnet which is the high coercivity material is used as the driver of FES. The proposed S-FES system shows the stable rotation characteristics at high speed range about 10,000 rpm. To verify the validity of proposed system, the comparative study with the conventional ball bearing system is proceeded and it is well confirmed with the result of the lower friction loss of S-FES system.

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A Study about Development of Hydrogen Peroxide Stabilizer in Modified Fenton Reaction Using Anion Surfactant (음이온 계면활성제를 사용한 modified Fenton 반응의 과수안정제 개발에 관한 연구)

  • Kim, Han Ki;Park, Kang Su;Kim, Jeong Hwan;Park, Joo Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4B
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    • pp.377-382
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    • 2011
  • In this study, hydrogen peroxide is stabilized in modified Fenton reaction to improve the soil remediation. Phenanthrene, which is the typical compound in PAHs, was spiked into soil samples to copy the original contaminated site. Anionic surfactant, SDS (Sodium dodecyl sulfate) was used for hydrogen peroxide stabilizer. 4 mM of Fe(II), 5~50 mM of SDS and 102.897 mM of $H_2O_2$ was injected into soil samples which is contaminated by 125 mg/kg of phenanthrene to analyze decomposition rate of phenanthrene in modified Fenton reaction. In condition which SDS was injected 30 mM, decomposition rate of phenanthrene has best efficiency as 95% and in condition which SDS was injected over 30 mM, decomposition rate is lower than SDS 30 mM because SDS enacted as scavenger in the system. Results which assess the change of hydrogen peroxide concentration after injecting hydrogen peroxide stabilizer showed that hydrogen peroxide concentration was 14.6995 mM so that is stabilized at Fe(II) 2 mM condition in 48 hours. On the other hand, hydrogen peroxide is not stable in Fe(III) condition. SDS concentration was fixed and iron concentration was changed 2~8 mM to find out optimize proportion between iron concentration and SDS concentration in modified Fenton reaction. Consequentially, in condition of which Fe(II) 4 mM and SDS 30 mM, reaction has the highest removal rate as 95%.

Strength Analysis of Mark III Cargo Containment System using Anisotropic Failure Criteria

  • Jeong, Han Koo;Yang, Young Soon
    • Journal of Advanced Research in Ocean Engineering
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    • v.1 no.4
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    • pp.211-226
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    • 2015
  • Membrane type Mark III cargo containment system (CCS) is considered in this study to investigate its strength capability under applied loads due to liquefied natural gas (LNG) cargo. A rectangular plated structure supported by inner hull structure is exemplified from Mark III CCS according to classification society's guidance and it is assumed as multi-layered structure by stacking plywood, triplex, reinforced polyurethane (PU) foam and series of mastic upon inner hull structure. Commercially available general purpose finite element analysis package is used to have reliable FE models of Mark III CCS plate. The FE models and anisotropic failure criteria such as maximum stress, Hoffman, Hill, Tsai-Wu and Hashin taking into account the direction dependent material properties of Mark III CCS plate components and their material properties considering a wide variation of temperature due to the nature of LNG together form the strength analysis procedure of Mark III CCS plate. Strength capability of Mark III CCS plate is understood by its initial failure and post-initial failure states. Results are represented in terms of failure loads and locations when initial failure and post-initial failures are occurred respectively. From the results the basic design information of Mark III CCS plate is given.

An Effect of Fe2O3 Additive on a Seebeck Coefficient and a Power Factor for SmCoO3 Perovskite System (SmCoO3 페롭스카이트 계 열전소재에서 Fe2O3 첨가제가 출력인자에 미치는 영향)

  • Jung, Kwang-Hee;Choi, Soon-Mok;Seo, Won-Seon;Park, Hyung-Ho
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.457-460
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    • 2010
  • $SmCoO_3$ system was investigated for their application to themoelectric materials. All specimens showed p-type semiconducting behavior and their electrical conductivity ($\sigma$), Seebeck coefficient (S) and power factor were measured at high temperature. And the effect of dopant ions on their thermoelectrical properties were also investigated. $Fe^{3+}$ ion doped into $Co^{3+}$ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. The maximum Seebeck coefficient value for 60% doping case reached to 780 ${\mu}V$/K at $240^{\circ}C$. However $Fe^{3+}$ doped system cause an negative effect on power factor value. In case of the pure phase, the maximum Seebeck coefficient value reached to 290 ${\mu}V$/K at $240^{\circ}C$ and the maximum electrical conductivity was obtained 748 1/(ohm$\times$cm) at $960^{\circ}C$. As a result, the maximum power factor was obtained $1.49\times10^{-4}$ W/$mK^2$ at $550^{\circ}C$.

Experimental Investigation of Stannite-Sphalerite System In Relation to Ores (황석석일섬아연석계(黃錫石一閃亞鉛石系)의 실험연구(實驗硏究)와 천연건물(天然鍵物)에의 활용(活用))

  • Lee, Jae Yeong
    • Economic and Environmental Geology
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    • v.8 no.1
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    • pp.1-23
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    • 1975
  • The subject of this study deals with phase relations between stannite ($Cu_2FeSnS_4$) and sphalerite (${\beta}-ZnS$)/wurtzite (${\alpha}-ZnS$). The phase relations were systematically investigated from liquidus temperature to $400^{\circ}C$ under controlled conditions. ${\beta}-stannite$ (tetragonal) is stable up to $706{\pm}5^{\circ}C$, where it inverts to a high-temperature polymorph ${\alpha}-stannite$ (cubic) melting congruently at $867{\pm}5^{\circ}C$. Sphalerite (cubic, ${\beta}-ZnS$) inverts at $1013{\pm}3^{\circ}C$ to wurtzite, which is the hexagonal hightemperature polymorph of ZnS. Between ${\alpha}-stannite$ and sphalerite a complete solid solution series exists above approximately $870^{\circ}C$ up to solidus temperature. The melting temperature of ${\alpha}-stannite$ rises towards sphalerite and reaches a maximum at $1074{\pm}3^{\circ}C$, which is the peritectic with the composition of 91 wt. % sphalerite and 9 wt. % ${\alpha}-stannite$. At this temperature, wurtzite takes only 5wt. % ${\alpha}-stannite$ in solid solution which decreases with increasing temperature. The inverson temperature of ${\alpha}/{\beta}-stannite$ is lowered with increasing amounts of sphalerite in solid solution down to $614{\pm}7^{\circ}C$, which is the eutectoid with the composition of 13 wt. % sphalerite and 87 wt. % ${\alpha}-stannite$. Here, ${\beta}-stannite$ contains only 10wt. % sphalerite in solid solution. With decreasing temperature, the ranges of the solid solution on both sides of the system narrow. The phase relations in the above pure system changed due to the FeS impurities in the sphalerite solid solution. The eutectoid increased from $614{\pm}7^{\circ}C$ up to $695{\pm}5^{\circ}C$ (5 wt. % FeS) and $700{\pm}5^{\circ}C$ (10wt. % FeS), while the peritectic decreased from $1074{\pm}3^{\circ}C$ down to $1036{\pm}3^{\circ}C$ (wt. %FeS) and $987{\pm}3^{\circ}C$ (10wt. %FeS). A most notable change is the appearance of non-binary regions. An important feature is the combination of this study system with the experimental results reported by Sprinfer (1972). If a stannite-kesterite solid solution is used in the place of stannite as a bulk composition, the inversion temperature is lowered to less than $400^{\circ}C$ which belongs to temperatures of the hydrothermal region.

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Natural Dyeing of Silk Fabrics with Undaria Pinnatifida Extracts (미역 추출물을 이용한 견직물의 천연염색)

  • Kim, Sangyool;Jeon, Soonduk
    • Journal of Fashion Business
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    • v.18 no.5
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    • pp.69-81
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    • 2014
  • Fabric made of 100% silk was dyed with Undaria pinnatifida extracts under different conditions such as varing colorant concentration, temperature, time and dyebath pH. The dye uptake (K/S, value), CIE L*,a*,b* and Munsell values of the dyed samples and mordanted samples were measured. Colorfastness, antibacterial property and UV protection property were also evaluated. As colorants concentration increased, the dye uptake increased progressively and maximum color strength was obtained at 100% V/V. Dye uptake also increased with increasing temperature and time, and the maximum color strength was obtained at $80^{\circ}C$ and 60min. With pre-mordanting, the color of the Al and Fe mordanted silk fabrics was yellow on the Munsell color system, while the Cu mordanted fabric was a greenish color. Al and Fe post-mordanted fabrics had a yellow tone, and the Cu post-mordanted fabric had a yellow greenish tone. The light fastness property of the Cu mordanted silk fabric was relatively good, The effect of Al and Fe mordanting on fastness was insignificant. The antibacterial activity of dyed and unmordanted silk fabric was excellent, whereas fabric dyed and mordanted with Undaria pinnatifida extract demonstrated superior ultraviolet protection.

Development of Press Forming Technology for the Multistage Fine Tooth Hub Gear (다단 미세 치형 허브 기어의 프레스 성형기술개발)

  • Kim D.H.;Lee J.M.;Lee S.H.;Byun H.S.;Kim B.M.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.769-772
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    • 2005
  • This paper deals with the aspects of die design for the multistage fine tooth hub gear in the cold forging process. In order to manufacture the cold forged product fur the precision hub gear used as the ARD 370 system of bicycle, it examines the influences of different designs on the metal flow through experiments and FE-simulation. To find the combination of design parameters which minimize the damage value, the low gear length, upper gear length and inner diameter as design parameters are considered. An orthogonal fraction factorial experiment is employed to study the influence of each parameter on the objective function or characteristics. The optimal punch shape of fine tooth hub gear is designed using the results of FE-simulation and the artificial neural network. To verify the optimal punch shape, the experiments of the cold forging of the hub gear are executed.

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Effects of Various Post-Treatments of Carbon Nanotube Films for Reliable Field Emission

  • Han, Jae-Hee;Lee, Su-Hong;Berdinsky, Alexander S.;Yoo, Ji-Beom;Park, Chong-Yun;Choi, Jin-Ju;Jung, Tae-Won;Han, In-Taek;Kim, Jong-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1462-1465
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    • 2005
  • In this report, the FE characteristics of carbon nanotubes (CNTs) treated using both thermal annealing and mechanical coatings on the as-grown CNTs system atically studied. It was found that in the high temperature annealed samples, CNTs were attacked at its root during annealing due to a small amount of oxygen, and were pulled out of the substrate in places after FE measurements because of the contact resistance. However, for the mechanically coated samples both with spin on glass (SOG) and polymethyl methacrylate (PMMA), CNTs were found to be nearly intact after FE measurements and showed reliable FE characteristics over repeatable voltage scan. The reliability of CNTs during FE could be owing to the strong adhesion of CNTs to the substrate both by SOG and PMMA coatings.

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The Effects of Current Adjustment on the Preparation of Fe-Al Intermetallic Compounds by Field-Activated Combustion Synthesis (FACS법에 의한 Fe-Al계 금속간화합물의 제조시 통전방식의 영향)

  • Yun, Gi-Seok;Jeong, Jung-Chae;Won, Chang-Hwan
    • Korean Journal of Materials Research
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    • v.9 no.7
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    • pp.680-687
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    • 1999
  • Fe-Al intermetallic compounds were manufactured by using the field-activated combustion synthesis process. Effects of chemical composition(Fe:Al= 3: 1,2:1, 1:1, 1:2, 1:3), Compaction pressure(150, 250, 350MPa) and electrical resistance on the reaction were investigated in this system. As the molar ratio of Al, compaction pressure and electric field increased, the combustion temperature and velocity were increased. The influences for reaction with current adjust way were investigated in this system. But in the absence of a electric field, the reaction could sustain a nonsteady combustion wave and was not completed. The reaction products were characterized with X-ray, SEM and EDXS to determine the structure and composition.

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