• Title/Summary/Keyword: FGD process

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Characteristics of Limestone Regeneration in the wet Limestone FGD Process (습식 석회석 배연 탈황 공정에서의 석회석 재생 특성)

  • 손종렬;문경환;모세영
    • Journal of Environmental Health Sciences
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    • v.27 no.4
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    • pp.9-14
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    • 2001
  • This study was performed to develop the modified FGD(Flue Gas Desulfurization) process which can eliminate the possibility of generating secondary pollutants. Limestone was regenerated by adding ammonium hydroxide and carbon dioxide, and reusing it as a absorbent in FGD gypsum Process. A series of the new or modified FGD process which include desulfurization and regeneration limestone from CaSO$_3$. 1/2H20 and CaSO4 . 2H2O, were carried out under various experimental conditions. The results showed that the optimum injection ratio for regeneration of limestone was 0.3 ml/min of CO2 flow rate, 2 ml of NH4OH per 0.01 M of regent grade CaSO4 . 2H20O and the optimum regeneration temperature was 50. The increaser was the number of times of limestone regeneration, the faster was the breakthrough point of desulfurization at the desulfurination process which the regenerated limestone was used. Then the efficiency of desulrurization was decreased. This study can be confirmed the possibility for reuse of regenerated limestone due to the similarity of desulfurization characteries both reagent grade calcium carbonate and regenerated calcium carbonate. Finally, it appeared that the new technology using regenerated 1imestone can be applied to the FGD process.

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A Study on the Desulfurization Efficiency of Limestone Sludge with Various Admixtures

  • Seo, Sung Kwan;Chu, Yong Sik;Shim, Kwang Bo;Lee, Jong Kyu;Song, Hun
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.479-482
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    • 2015
  • The flue gas desulfurization (FGD) process is one of the most effective methods to reduce the amount of $SO_2$ gas (up to 90%) generated by the use of fossil fuel. Limestone is usually used as a desulfurizing agent in the wet-type FGD process; however, the limestone reserves of domestic mines have become exhausted. In this study, limestone sludge produced from the steel works process is used as a desulfurizing agent. Seven different types of additives are also used to improve the efficiency of the desulfurization process. As a result, alkaline additive is identified as the least effective additive, while certain types of organic acids show higher efficiency. It is also observed that the amount of FGD gypsum, which is a by-product of the FGD process, increases with the used of some of those additives.

The Influence of FGD Gypsum Fabricated from Limestone Sludge on Cement Properties

  • Seo, Sung Kwan;Chu, Yong Sik;Shim, Kwang Bo;Lee, Jong Kyu;Song, Hun
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.676-681
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    • 2016
  • For the purpose of reducing the amount of limestone, which is used as a desulfurization agent to absorbing $SO_X$ gas in thermal power plants, and to recycle limestone sludge generated from a steel mill, limestone sludge was utilized as a desulfurization agent. In this study, cement, made of flue gas desulfurization (FGD) gypsum obtained in a desulfurization process using limestone sludge, was manufactured then, experiments were conducted to identify the physical properties of the paste and mortar using the cement. The results of the crystal phase and microstructure analyses showed that the hydration product of the manufactured cement was similar to that of ordinary Portland cement. No significant decline of workability or compressive strength was observed for any of the specimens. From the results of the experiment, it was determined that FGD gypsum manufactured from limestone sludge did not influence the physical properties of the cement also, quality change did not occur with the use of limestone sludge in the flue gas desulfurization process.

Mass Transfer of Sulfur Dioxide in Flue Gas Desulfurization Process Utilizing a Jet Bubbling Scrubber (기포분사반응기를 사용한 배연탈황공정의 아황산가스 물질전달)

  • 동종인;나진균;홍지형
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.4
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    • pp.262-268
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    • 1992
  • The trend of international concerns on environmental conservation and domestic demand of ambient air quality improvement, specially on sulfur dioxide level has resulted in the establishment of mid-term strategy of environmental improvement and stepwise strengthening of emission regulations in this decade in Korea. Development of flue gas desulfurization(FGD) process is becoming an essential task to be accomplished especially for the power plants and large industrial facilities. This study is an initial stage researc focusing on the mass transfer principles in wet type FGD process and the effects of operating variables of a jet bubbling scrubber utilizing limestone slurry on sulfur dioxide removal efficiency. Experimental results showed this type of scrubbing system has some advantages in terms of mass transfer mechanism and removal efficiency. More rigorous research is needed for the reaction system and the comparison with existing FGD processess for the possible development of a process which is compatative in view of installation cost and treatment of by-products.

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Suggestion of Product Planning Process for Small and Medium Sized Design Company : Focused on the Case of Baby Bathtub Design Concept Development (중소 디자인 기업을 위한 제품 기획 프로세스 제안 : 유아욕조 디자인 콘셉트 개발 사례를 중심으로)

  • Yoon, Woo-Lahm;Go, Jung-Wook
    • The Journal of the Korea Contents Association
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    • v.19 no.8
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    • pp.205-213
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    • 2019
  • A number of small and medium design companies in Korea are making efforts to develop distinguished products with an aim to survive and prosper. However, it is quite difficult to succeed due to insufficient experience in product planning and the challenges in applying known methodologies, which are based on a large amount of data presented as best practices in designing process, in the actual small and medium enterprise operations. To this end, this study suggested the usefulness of the user participation process as the methodology for small and medium design companies and chose the user FGD method implemented by Company P which is a small design company as an empirical case study. The following are the processes used in the case study; First, the problems of existing baby bath were derived through user FGD. Second, opinions were collected from various classes of users through in-depth interviews. Third, the ideas derived were analyzed with the KJ method and grouped based on similar elements, through which six design directions and detailed design concepts covering size, material, safety, purchase factors of existing product, direction of improvement, additional elements were derived. Through the case study, this study verified that the FGD method of Company P could improve the practical verification, integration and promptness of the product planning process in small and medium enterprises. This is valuable as a realistic process that small and medium enterprises with limited capital and manpower may adopt.

Quality of High Volume Blast Furnace Slag Mortar Depending on Desulfurization Gypsum Treating Methods and Fine Aggregate Type (탈황석고의 가공법 및 잔골재종류 변화에 따른 고로슬래그 미분말 다량 치환 모르타르의 품질 특성)

  • Han, Cheon-Goo;Lee, Dong-Yun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.157-164
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    • 2016
  • In this research, based on the condition of using desulfurization gypsum(FGD) as a stimulator for high-volume blast furnace slag cement mortar, sieving and heating process methods of removing activated carbon in FGD were compared with the non-processed FGD and recycled and natural fine aggregates were compared for suitable aggregate to be used. According to the result of experiment, sieving with 0.3mm was more efficient than $500^{\circ}C$ heating for processing the FGD, and recycled fine aggregate showed more favorable result than natural fine aggregate at the FGD content was 5 to 10%. On the other hand, the mortar mixture including recycled fine aggregate had a high drying shrinkage, and absorption ratio, and thus specific limitations on applying recycled fine aggregate should be required.

A Study on the Application Limestone Sludge to the Flue Gas Desulfurization Process (제철 산업부산물인 석회석 슬러지의 배연탈황 공정 적용에 관한 연구)

  • Seo, Sung Kwan;Chu, Yong Sik;Shim, Kwang Bo;Lee, Jong Kyu;Song, Hun;Yun, Young Min
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.575-583
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    • 2014
  • The flue gas desulfurization (FGD) process is currently the most effective process utilized to remove sulfur dioxide from stack gases of coal-fired plants. However, FGD systems use a lot of limestone as desulfurizing agent. In this study, we use limestone sludge, which is a by-product of the steel industry, to replace the desulfurizing agent of the FGD system. The limestone particle size is found to be unrelated to the desulfurizing rate; the gypsum purity, however, is related. Limestone sludge mixes with limestone slurry delivered at a constant rate in a desulfurizing agent with organic acid are expected to lead to a high desulfurization efficiency and high quality by-product (gypsum).

A Study on the Application with Limestone Sludge at Limestone-Gypsum Wet Flue Gas Desulfurization Process (석회석 슬러지의 석회석-석고 습식 배연탈황 공정적용에 관한 연구)

  • Seo, Sung Kwan;Chu, Yong Sik;Shim, Kwang Bo
    • Resources Recycling
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    • v.25 no.5
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    • pp.44-49
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    • 2016
  • Flue gas desulfurization(FGD) is an effective technique to remove $SO_2$ gases of coal-fired plants. Limestone is usually used as desulfurizing agent. In this study, we use the limestone sludge which is a by-product of steel industry in order to replace desulfurizing agent of FGD process. Physical and chemical characteristics analysis of desulfurizing agent was conducted. Desulfurizing agent using limestone sludge was fabricated by pre-treatment process and, then the agent was used on FGD process. Consequently, the tendency on the $SO_2$ concentration did not appear. And limestone sludge was considered as possible alternative agent for flue gas desulfurization process through absorber control system.

Integrated Manufacturing Systems Design : Integrated Approach to Process Plan Selection and AGV Guidepath Design (통합 제조 시스템 설계 : 공정 계획과 AGV 경로 설계의 통합 접근)

  • Seo, Yoon-Ho
    • Journal of Korean Institute of Industrial Engineers
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    • v.20 no.3
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    • pp.151-166
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    • 1994
  • The manufacturing environment on which this research is focused is an FMS in which AGVs are used for material handling and each part type has one or more process plans. The research aims at developing a methodology whereby, given a part and volume mix for production during any production session, the best set of process plans including one plan per part type is selected and the best unidirectional AGV guidepath can be dynamically reconfigured in response to changes in parts and lot sizes combination. For the integrated PPS/FGD problem in which two functions of process plan selection (PPS) and flexible AGV guidepath design (FGD) are integrated, a zero-one integer programming model is developed. The integrated problem is decomposed into two subproblems, process plan selection given a directed AGV layout and AGV guidepath design with a fixed process plan per part type. A heuristic algorithm that alternately and iteratively solves these two subproblems is developed. The effectiveness of the heuristic algorithm is tested by solving various randomly generated sample problems and comparing the heuristic solutions with those obtained by an exact procedure. From the test results, the following conclusions are drawn: 1) For a reasonable size problem, the heuristic is very effective. 2) By integrating the two functions of PPS and FGD, a remarkable benefit in total production time for a given part and volume mix is gained.

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Application of Cathodic Protection on Metallic Structure in Extremely Acidic Fluids

  • Chang, H.Y.;Yoo, Y.R.;Jin, T.E.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.140-146
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    • 2005
  • Fossil fired power plant produces the electric energy by using a thermal energy by the combustion of fossil fuels as like oil, gas and coal. The exhausted flue gas by the combustion of oil etc. contains usually many contaminated species, and especially sulfur-content has been controlled strictly and then FGD (Flue Gas Desulfurization) facility should be installed in every fossil fired power plant. To minimize the content of contaminations in final exhaust gas, high corrosive environment including sulfuric acid (it was formed during the process which $SO_2$ gas combined with $Mg(OH)_2$ solution) can be formed in cooling zone of FGD facility and severe corrosion damage is reported in this zone. These conditions are formed when duct materials are immersed in fluid that flows on the duct floors or when exhausted gas is condensed into thin layered medium and contacts with materials of the duct walls and roofs. These environments make troublesome corrosion and air pollution problems that are occurred from the leakage of those ducts. The frequent shut down and repairing works of the FGD systems also demand costs and low efficiencies of those facilities. In general, high corrosion resistant materials have been used to solve this problem. However, corrosion problems have severely occurred in a cooling zone even though high corrosion resistant materials were used. In this work, a new technology has been proposed to solve the corrosion problem in the cooling zone of FGD facility. This electrochemical protection system contains cathodic protection method and protection by coating film, and remote monitoring-control system.