Browse > Article
http://dx.doi.org/10.4191/kcers.2015.52.6.479

A Study on the Desulfurization Efficiency of Limestone Sludge with Various Admixtures  

Seo, Sung Kwan (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology)
Chu, Yong Sik (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology)
Shim, Kwang Bo (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology)
Lee, Jong Kyu (Energy & Environmental Division, Korea Institute of Ceramic Engineering and Technology)
Song, Hun (Division of Materials Science and Engineering, Hanyang University)
Publication Information
Abstract
The flue gas desulfurization (FGD) process is one of the most effective methods to reduce the amount of $SO_2$ gas (up to 90%) generated by the use of fossil fuel. Limestone is usually used as a desulfurizing agent in the wet-type FGD process; however, the limestone reserves of domestic mines have become exhausted. In this study, limestone sludge produced from the steel works process is used as a desulfurizing agent. Seven different types of additives are also used to improve the efficiency of the desulfurization process. As a result, alkaline additive is identified as the least effective additive, while certain types of organic acids show higher efficiency. It is also observed that the amount of FGD gypsum, which is a by-product of the FGD process, increases with the used of some of those additives.
Keywords
FGD systems; Limestone sludge; Organic acid; Alkali admixture agent; Gypsum;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 J. B. Frandsen, S. Kiil, and J. E. Johnsson, "Optimization of a Wet FGD Pilot Plant Using Fine Limestone and Organic Acids," Chem. Eng. Sci., 56 [10] 3275-87 (2001).   DOI
2 S. K. Seo, Y. S. Chu, K. B. Shim, J. K. Lee, H. Song, and Y. M. Yun, "A Study on the Application with Limestone Sludge at Flue Gas Desulfurizing Process," J. Korean Ceram. Soc., 51 [6] 1-9 (2014).   DOI
3 N. Ukawa, T. Takashina, N. Shinoda, and T. Shimizu, "Effexts of Particle Size Distribution on Limestone Dissolution in Wet FGD Process Applications," Environment Prog., 12 [3] 238-42 (1993).   DOI
4 P. K. Chan and G. T. Rochelle, "Limestone Dissolution: Effects of pH, $CO_2$, and Buffers Models by Mass Transfer," ACS Symposium Ser., 188 75-9 (1982).
5 E. H. Kim, J. C. Lee, H. K. Lee, and I. W. Kim, "Effect of Mixed Organic Acid admixtures on $SO_2$ Absorption in Wet Flue Gas Desulfurizing Process," Hwahak Konghak, 36 [5] 827-31 (1998).
6 J. C. S. Chang and J. D. Mobley, "Testing and Commercialization of Byproduct Dibasic Acid as Buffer Admixtures for Limestone Flue Gas Desulfurizing Systems," J. Air Pollut. Control Assoc., 33 [10] 955-62 (1983).   DOI
7 P. Tesarek, J. Krchalova, J. Kolisko, P. Rovnanikova, and R. Cerny, "Flue Gas Desulfurizing Gypsum: Study of Basic Mechanical, Hydric and Thermal Properties," Construction and Building Materials, 21 1500-9 (2007).   DOI