• Journal of the Korean Crystal Growth and Crystal Technology
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• v.26 no.1
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• pp.1-7
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• 2016

RE : YAG ($RE=Nd^{3+}$, $Er^{3+}$) single crystals are laser diodes and generally grown by Czochralski method with controlling the various growth parameter. Since the defects occurred by temperature gradient or the rotation speed of solid-liquid growth interface act as the decline of crystal optical property during the growth procedure, crystalline quality improvement via defects analysis is necessary. The etch pit density (EPD) analysis was used to confirm the surface defect of grown RE : YAG single crystal and to select the area of transmission electron microscopy (TEM) analysis. Defects in the specimen produced by tripod polishing method such as buckling, rod shaped, bend contours by internal stress, segregation and others were observed by using 200 kV TEM and 300 kV FE-TEM.

• Journal of the Korean Chemical Society
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• v.27 no.6
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• pp.424-482
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• 1983

Determination for $Ta_2O_5$,$Nb_2O_5$ and $SnO_2$ in tin slags was investigated by X-ray spectrometric method. Standard addition-dilution method was attempted and showed a comparable accuracy with standard calibration curve method. Pure chemicals($Ta_2O_5$,$Nb_2O_5$ and $SnO_2$) were added to the samples and diluted with silica or ferric oxide. For the determination of $Ta_2O_5$and$SnO_2$ , silica was more suitable than ferric oxide while the latter was more preferable than the former for $Nb_2O_5$.

• Journal of the Korean Electrochemical Society
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• v.3 no.1
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• pp.5-10
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• 2000

In the present work, corrosion rate W and corrosion potential tow were simultaneously measured as a function of relative humidity RH employing the electrochemical wet and dry method as an accelelated atmospheric corrosion method. The W versus (vs.) RH curve is classified into .three regions, namely, the first W plateau region, the second region of the linear relationship between logarithmic W and RH, finally, followed by an abrupt decay region. Based upon the atmospheric corrosion mechanism of mild steel, we introduced another diagram of $\varepsilon_{corr}$ vs. RH which is divided into three regions. In the first region, the corrosion scales are composed of single lepidocrocite-phase $(\gamma-FeOOH)$; in the second region, $\gamma-FeOOH$-phase coexists with magnetite-phase $(Fe_3O_4)$ in the scales and finally the oxide scales change into a single Fe304-phase in the third region. The three distinct regions of both representations share almost each other, which is validated by FT-IR (Fourier transform infra-red) analysis and surface observation. Both representations prove to be convenient and complementary for surveying the spectrum of the atmospheric corrosion of mild steel.

• Journal of Conservation Science
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• v.37 no.6
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• pp.738-747
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• 2021

This study attempted to investigate the metallurgical characteristic through material scientific analysis of hammer scale produced as a direct smelting method restoration experiment for each raw material of iron. To this end, four hammer scale groups were set up, respectively, by experimenting with Gyeongju-Gampo Iron sand and Yangyang Iron ore. For the analysis, principal component analysis, compound analysis, microstructure observation, and chemical composition were confirmed. As a result of principal component analysis, as forging and refining progressed, the content of Fe increased and the content of non-metallic objects decreased. As a result of compound analysis, iron oxide-based compounds were identified. As a result of confirming microstructure and chemical composition, Wüstite and Fayalite were observed overall, and agglomerated Wüstite were observed in some. Magnetite on shape of polygon and pillar was observed. In addition, it was confirmed that internal defects, impurities, and non-metallic interventions gradually decreased. In the future, it is necessary to investigate the metallurgical characteristic through material scientific analysis of hammer scale produced through restoration experiments using various raw material of iron, and compare them with those excavated from Iron manufacture ruins.

• Journal of the Korean Chemical Society
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• v.44 no.4
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• pp.322-327
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• 2000

A new absorption spectrometric method for the determination of the Cr$_2O_7^{2-}$ ionin acidic media has been developed. The new method is based on the oxidation-reduction reaction of the HCr$O_4^-$ ion with H$_2$O$_2$forming a deep blue CrO(O$_2$) $_2$ andis coupled with a technique of flow injection analysis(FIA). The new method provides a linear calibration curve which accurately follows the Beer's law over a wide range of the analytical concentrations(2.0 ${\times}$ $10^{-6}$M~8.0 ${\times}$ $10^{-3}$M) of K$_2$Cr$_2$O$_2$. The sensitivity of the new method is approximately two times greater than the current method and the effects of the interfering substances such as V, Co, Ni, Fe, and Mn are almost negligible except Cu.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.5
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• pp.524-531
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• 2004

To investigate relevance of the definition of the reference stress to estimate J and $C^{*}$ for surface crack problems, this paper compares FE J and $C^{*}$ results for surface cracked pipes with those estimated according to the reference stress approach using various definitions of the reference stress. Pipes with part circumferential inner surface crack and finite internal axial crack are considered, subject to internal pressure and global bending. The crack depth and aspect ratio are systematically varied. The reference stress is defined in four different ways using (i) the local limit load, (ii) the global limit load, (iii) the global limit load determined from the FE limit analysis, and (iv) the optimized reference load. It is found that the reference stress based on the local limit load gives overall excessively conservative estimates of J and $^{*}$. Use of the global limit load clearly reduces the conservatism, compared to that of the local limit load, although it can provide sometimes non-conservative estimates of J and $^{*}$. The use of the FE global limit load gives overall non-conservative estimates of J and $^{*}$. The reference stress based on the optimised reference load gives overall accurate estimates of J and $^{*}$, compared to other definitions of the reference stress. Based on the present finding, general guidance on the choice of the reference stress for surface crack problems is given.

• Structural Engineering and Mechanics
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• v.81 no.3
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• pp.293-303
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• 2022

As infrastructure ages and traffic load increases, serious public concerns have arisen for the well-being of bridges. The current health monitoring practice focuses on large-scale bridges rather than short span bridges. However, it is critical that more attention should be given to these behind-the-scene bridges. The relevant information about the construction methods and as-built properties are most likely missing. Additionally, since the condition of a bridge has unavoidably changed during service, due to weathering and deterioration, the material properties and boundary conditions would also have changed since its construction. Therefore, it is not appropriate to continue using the design values of the bridge parameters when undertaking any analysis to evaluate bridge performance. It is imperative to update the model, using finite element (FE) analysis to reflect the current structural condition. In this study, a FE model is established to simulate a concrete culvert bridge in New South Wales, Australia. That model, however, contains a number of parameter uncertainties that would compromise the accuracy of analytical results. The model is therefore updated with a neural network (NN) optimisation algorithm incorporating Monte Carlo (MC) simulation to minimise the uncertainties in parameters. The modal frequency and strain responses produced by the updated FE model are compared with the frequency and strain values on-site measured by sensors. The outcome indicates that the NN model updating incorporating MC simulation is a feasible and robust optimisation method for updating numerical models so as to minimise the difference between numerical models and their real-world counterparts.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.17-25
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• 2001

This paper briefly describes the new engineering method, called the enhanced reference stress method, to estimate J (or $C^*$) for non-linear fracture mechanics analysis of defective components, recently proposed by authors. The proposed method offers significant advantages over existing methods in terms of its accuracy, simplicity and robustness. Examples of application of the proposed method to typical piping integrity problems such as through-wall cracked pipes under combined loading, and surface cracked pipes under internal pressure and bending are given. Excellent agreements between the FE J and $C^*$ results and those of the proposed method provide sufficient confidence in the use of the proposed method. One notable point is that the proposed method can be used to estimate J (or $C^*$) along the crack front of surface cracks. Moreover simplicity of the proposed method makes it easy to extend to more complex problems. Thus the proposed method is attractive to assess the significance of defects under practical situations.

• Advances in nano research
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• v.9 no.1
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• pp.1-13
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• 2020

In this work, the electrical potential (EP) technique with an artificial neural networks (ANNs) for monitoring of nanostructures are used for the first time. This study employs an expert system to identify size and localize hidden nano-delamination (N.Del) inside layers of nano-pipe (N.P) manufactured from Basalt Fiber Reinforced Polymer (BFRP) laminate composite by using low-cost monitoring method of electrical potential (EP) technique with an artificial neural networks (ANNs), which are combined to decrease detection effort to discern N.Del location/size inside the N.P layers, with high accuracy, simple and low-cost. The dielectric properties of the N.P material are measured before and after N.Del introduced using arrays of electrical contacts and the variation in capacitance values, capacitance change and node potential distribution are analyzed. Using these changes in electrical potential due to N.Del, a finite element (FE) simulation model for N.Del location/size detection is generated by ANSYS and MATLAB, which are combined to simulate sensor characteristic, therefore, FE analyses are employed to make sets of data for the learning of the ANNs. The method is applied for the N.Del monitoring, to minimize the number of FE analysis in order to keep the cost and save the time of the assessment to a minimum. The FE results are in excellent agreement with an ANN and the experimental results available in the literature, thus validating the accuracy and reliability of the proposed technique.

• International Journal of Internet, Broadcasting and Communication
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• v.7 no.2
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• pp.96-104
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• 2015

Fischer Tropsch reaction is one of the interesting topic for renewable and clean energy. Polymerization of carbon monoxide or carbon dioxide with hydrogen over metal supported catalyst can produce long chain hydrocarbons. Synthetic liquid hydrocarbons are promising alternative to fossil fuels. This research work has been focused on the synthesis of Fe based catalyst for Fischer Tropsch reaction. Mesoporous silica (MS) support prepared by a precipitation method using two different washing solution, distilled water (DW) and acid in ethanol solution (ET), and different calcination temperature. Then, Fe/MS was prepared by an incipient wetness impregnation method. All of samples were systematically characterized using various physical and chemical techniques. TEM and XRD analysis were used to ensure that the cubic Ia3d mesostructure is stable after calcination. FTIR spectra are useful to ascertain the existence of template in the support. TPR studies were also used to understand the nature of Fe species and their reducibility. The results reveal that washing the support with distilled water and calcination at $550^{\circ}C$ can efficiently remove the triblock copolymer templates. The existence of template in the support affects the textural properties of all catalyst investigated.