• 제목/요약/키워드: Eyring model

검색결과 33건 처리시간 0.022초

REM 모델에 의한 Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체 완화스펙트럼의 pH 영향 (pH Effect on Relaxation Spectra of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers by REM Model)

  • 김남정
    • 폴리머
    • /
    • 제37권2호
    • /
    • pp.135-140
    • /
    • 2013
  • Poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 응력완화 실험은 용매기를 부착한 인장 시험기를 사용하여 여러 온도의 공기 중, 증류수, pH 3, 7, 11 용액에서 실행하였다. Ree-Eyring and Maxwell 모델로부터 얻은 완화스펙트럼 식에 실험적인 응력완화 곡선을 대입하여 poly(methyl acrylate)-poly(acrylonitrile) 공중합체의 완화스펙트럼을 얻었다. 완화스펙트럼의 계산은 Laplace 변환법을 사용한 컴퓨터 프로그램을 이용하였다. 이들 시료의 완화스펙트럼은 유동단위의 분자량과 자체확산 분포와 밀접한 관계가 있음을 알 수 있었다.

CFD를 이용한 분지관 비뉴턴 해석 (PULSATILE FLOW SIMULATION OF A NON-NEWTONIAN FLUID THROUGH A BIFURCATION TUBE USING THE CFD ANALYSIS)

  • 황도연;유성수;박형구
    • 한국전산유체공학회:학술대회논문집
    • /
    • 한국전산유체공학회 2008년도 학술대회
    • /
    • pp.177-180
    • /
    • 2008
  • The objective of this study is to get simulation data about pulsatile flow of a non-Newtonian fluid through a bifurcated tube. All the process was based on CFD method, with a commercial FVM code, SC/Tetra ver. 6.0 for solving, and with CATIA R16 for generating geometries. To define a non-Newtonian fluid, the following viscous models are used; the Powell-Eyring model, the modified Powell-Eyring model, the Cross model, the modified Cross model, the Carreau model, the Carreau-Yasuda model and the modified Power Law model. The flow calculation data using each model were compared with the other data of a existing paper. Finally, the Carreau model was recognized to give the best result with the SC/Tetra code, and the succeeding simulations are made with the model. For the pulsating flow condition, the sine wave type velocity profile is given as the inlet boundary condition. To investigate the effect of geometries and mesh, the pre-test is carried out with various curvature conditions of the bifurcated corner, and then with various mesh conditions. The final process is to calculate flow variables such as the wall shear stress (WSS) and the wall shear stress gradient (WSSG). To validate all the result, the simulation is compared with the existing data of the other papers. Generally speaking, there is a noticeable difference in the maximum and minimum value of WSS. It is not sure that the values in each data are on the exactly same location. However, the overall trend is similar. The next study needs to investigate the same situation by experimental method. Furthermore, if the flow is simulated with more pulsatile conditions, more data of flow field through a bifurcated tube could be achieved.

  • PDF

CFD를 이용한 분지관 비뉴턴 해석 (PULSATILE FLOW SIMULATION OF A NON-NEWTONIAN FLUID THROUGH A BIFURCATION TUBE USING THE CFD ANALYSIS)

  • 황도연;유성수;박형구
    • 한국전산유체공학회:학술대회논문집
    • /
    • 한국전산유체공학회 2008년 추계학술대회논문집
    • /
    • pp.177-180
    • /
    • 2008
  • The objective of this study is to get simulation data about pulsatile flow of a non-Newtonian fluid through a bifurcated tube. All the process was based on CFD method, with a commercial FVM code, SC/Tetra ver. 6.0 for solving, and with CATIA R16 for generating geometries. To define a non-Newtonian fluid, the following viscous models are used; the Powell-Eyring model, the modified Powell-Eyring model, the Cross model, the modified Cross model, the Carreau model, the Carreau-Yasuda model and the modified Power Law model. The flow calculation data using each model were compared with the other data of a existing paper. Finally, the Carreau model was recognized to give the best result with the SC/Tetra code, and the succeeding simulations are made with the model. For the pulsating flow condition, the sine wave type velocity profile is given as the inlet boundary condition. To investigate the effect of geometries and mesh, the pre-test is carried out with various curvature conditions of the bifurcated corner, and then with various mesh conditions. The final process is to calculate flow variables such as the wall shear stress (WSS) and the wall shear stress gradient (WSSG). To validate all the result, the simulation is compared with the existing data of the other papers. Generally speaking, there is a noticeable difference in the maximum and minimum value of WSS. It is not sure that the values in each data are on the exactly same location. However, the overall trend is similar. The next study needs to investigate the same situation by experimental method. Furthermore, if the flow is simulated with more pulsatile conditions, more data of flow field through a bifurcated tube could be achieved.

  • PDF

비선형 곤충 온도발육모형의 특성과 발전과정에 대한 고찰 (A Review for Non-linear Models Describing Temperature-dependent Development of Insect Populations: Characteristics and Developmental Process of Models)

  • 김동순;안정준;이준호
    • 한국응용곤충학회지
    • /
    • 제56권1호
    • /
    • pp.1-18
    • /
    • 2017
  • 곤충의 온도발육모형은 해충의 발생예찰모형을 비롯한 개체군모형에서 기본이 되는 요소이다. 본고에서는 곤충의 온도의존적 비선형 발육모형에 대하여 고찰하였다. 모형의 종류를 크게 경험모형과 생물리적 모형으로 구분하였으며, 수식의 유사성 내지 기원에 대한 유연관계에 따라 세분하였다. 발육률 곡선의 형태적 묘사에 적합한 수식을 적용하는 경험모형은 Stinner-계열, Logan-계열, 수행모형, 그리고 베타 분포모형으로 세분화하여 고찰하였다. 촉매반응을 바탕으로 하고 있는 생물리적 모형은 Eyring-모형, SM-모형, SS-모형, SSI-모형으로 이어지는 단계통으로 분류하였다. 본 연구에 포함된 각 모형의 개발과정과 형태적합 특성에 대하여 기술하였다.

용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정 (Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra)

  • 김남정
    • 대한화학회지
    • /
    • 제50권3호
    • /
    • pp.196-202
    • /
    • 2006
  • 점탄성 용융 폴리우레탄의 자체확산분포가 완화스펙트럼과 자체확산분포 관계식으로부터 얻어졌다. ester, PCL PCL dyed 형의 용융 폴리우레탄의 완화스펙트럼은 실험적인 응력완화 곡선을 Ree-Eyring and Maxwell non-Newtonian model(REM 모델)이론식에 적용시켜서 얻는다. 용융폴리우레탄의 응력완화 실험은 온도조절 장치가 있는 physica 레오메타를 이용하여 여러 온도에서 수행되었다. 이론적인 완화스펙트럼은 REM model로부터 유도한 이론적인 완화스펙트럼식을 프로그램화한 컴퓨터 계산에서 구하였다. 폴리우레탄 시료의 자체확산과 비결정 영역의 홀거리가 응력완화 실험에 의해서 연구 조사되었다. 비결정 영역에서의 유동단위의 확산을 연구하기 위해서 확산계수와 홀부피가 유변학적인 파라메타와 결정크기로부터 계산되었다. 폴리우레탄 시료의 완화스펙트럼과 자체확산은 유동 단위의 분자량분포, 점도, 홀부피, 활성화에너지와 밀접한 관계가 있는 것을 알 수 있다.

On the Hydration Numbers and Activity Coefficients of Some Salts Present in Sea Water

  • Sung, Yong Kil;Jhon, Mu Shik
    • 한국해양학회지
    • /
    • 제5권1호
    • /
    • pp.1-5
    • /
    • 1970
  • The hydration numbers of some salts present in sea water have been calculated by a simple model for the equation of the dielectric constant, and the mean activity coefficients from the theoretical formula proposed by Jhon and Eyring. The validity of the theory for the electrolyte solution is tested by evaluating the hydration numbers and the mean activity coefficients of some 1:1, 1:2, 2:1 and 1:3 electrolytes in sea water. The results show good agreement with the observations.

  • PDF

Significant Structure Theory of Physical Adsorption

  • Yun-liang Wang;Taikyue Ree;Henry Eyring
    • 대한화학회지
    • /
    • 제15권5호
    • /
    • pp.265-274
    • /
    • 1971
  • A significant structure theory of monolayer physical adsorption is developed. The theory is tested with the adsorptions on graphite of gases Ar, $N_2$, $CHCl_3$, and $CCl_4$. A restricted rotation model is used for the polyatomic molecules $N_2$, $CHCl_3$, and $CCl_4$. The computed isotherms and heats of adsorption are in good agreement with experiment in all cases studied.

  • PDF

ALT 통합모형의 적용 및 응용 (Implementation and Application of Integrated Model for ALT(Accelerated Life Test))

  • 최성운
    • 대한안전경영과학회:학술대회논문집
    • /
    • 대한안전경영과학회 2008년도 추계학술대회
    • /
    • pp.153-160
    • /
    • 2008
  • This paper presents the log likelihood function for integrated models for ALT such as exponential-general Eyring, Weibull-temperature and specific heat, lognormal-temperature and specific heat. Additionally this paper estimates the system reliability and mean time to failure(MTTF) for series, parallel, k of n, and standby system using ALT linkage parameter. Lastly this study designs three variable reliability acceptance sampling(RAS) plans such as type I, II censored test, sequential test by the use of integrated models for ALT.

  • PDF

수정멱법칙 비뉴턴유체의 협착관내 유동장해석 (Flow Analysis of the Modified Power-Law Non-Newtonian Fluids in the Stenotic Tubes)

  • 서상호;유상신;장남일
    • 설비공학논문집
    • /
    • 제6권3호
    • /
    • pp.227-236
    • /
    • 1994
  • Steady flows of Newtonian and non-Newtonian fluids in the stenotic tubes with various stenotic shapes are numerically simulated. Validity of the modified power-law model as a constitutive equation for the purely viscous non-Newtonian fluid is discussed and the results of the power-law model are compared with those of the Carreau model, the Powell-Eyring model and experimental data for blood. Flow characteristics and reattachment lengths for non-Newtonian fluids in the stenotic tubes are presented extensively. Also, the analysis is extended to predict the influences of diameter ratio, stenosis spacing, number of stenosis and Reynolds number on the flow characteristics in the multiple stenotic tubes.

  • PDF

Bayes factors for accelerated life testing models

  • Smit, Neill;Raubenheimer, Lizanne
    • Communications for Statistical Applications and Methods
    • /
    • 제29권5호
    • /
    • pp.513-532
    • /
    • 2022
  • In this paper, the use of Bayes factors and the deviance information criterion for model selection are compared in a Bayesian accelerated life testing setup. In Bayesian accelerated life testing, the most used tool for model comparison is the deviance information criterion. An alternative and more formal approach is to use Bayes factors to compare models. However, Bayesian accelerated life testing models with more than one stressor often have mathematically intractable posterior distributions and Markov chain Monte Carlo methods are employed to obtain posterior samples to base inference on. The computation of the marginal likelihood is challenging when working with such complex models. In this paper, methods for approximating the marginal likelihood and the application thereof in the accelerated life testing paradigm are explored for dual-stress models. A simulation study is also included, where Bayes factors using the different approximation methods and the deviance information are compared.