• Title/Summary/Keyword: Eyring model

Search Result 33, Processing Time 0.025 seconds

pH Effect on Relaxation Spectra of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers by REM Model (REM 모델에 의한 Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체 완화스펙트럼의 pH 영향)

  • Kim, Nam Jeong
    • Polymer(Korea)
    • /
    • v.37 no.2
    • /
    • pp.135-140
    • /
    • 2013
  • The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples was carried out in air, distilled water, pH 3, 7 and 11 solutions at various temperatures using a tensile tester equipped with a solvent chamber. The relaxation spectra of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the equation of relaxation spectrum derived from the Ree-Eyring and Maxwell model. The determination of relaxation spectra was performed from computer calculation using a Laplace transform method. It was observed that the relaxation spectra of these samples are directly related to the distribution of molecular weights and self-diffusions of flow segments.

PULSATILE FLOW SIMULATION OF A NON-NEWTONIAN FLUID THROUGH A BIFURCATION TUBE USING THE CFD ANALYSIS (CFD를 이용한 분지관 비뉴턴 해석)

  • Hwang, D.;Yoo, S.S.;Park, H.K.
    • 한국전산유체공학회:학술대회논문집
    • /
    • 2008.03a
    • /
    • pp.177-180
    • /
    • 2008
  • The objective of this study is to get simulation data about pulsatile flow of a non-Newtonian fluid through a bifurcated tube. All the process was based on CFD method, with a commercial FVM code, SC/Tetra ver. 6.0 for solving, and with CATIA R16 for generating geometries. To define a non-Newtonian fluid, the following viscous models are used; the Powell-Eyring model, the modified Powell-Eyring model, the Cross model, the modified Cross model, the Carreau model, the Carreau-Yasuda model and the modified Power Law model. The flow calculation data using each model were compared with the other data of a existing paper. Finally, the Carreau model was recognized to give the best result with the SC/Tetra code, and the succeeding simulations are made with the model. For the pulsating flow condition, the sine wave type velocity profile is given as the inlet boundary condition. To investigate the effect of geometries and mesh, the pre-test is carried out with various curvature conditions of the bifurcated corner, and then with various mesh conditions. The final process is to calculate flow variables such as the wall shear stress (WSS) and the wall shear stress gradient (WSSG). To validate all the result, the simulation is compared with the existing data of the other papers. Generally speaking, there is a noticeable difference in the maximum and minimum value of WSS. It is not sure that the values in each data are on the exactly same location. However, the overall trend is similar. The next study needs to investigate the same situation by experimental method. Furthermore, if the flow is simulated with more pulsatile conditions, more data of flow field through a bifurcated tube could be achieved.

  • PDF

PULSATILE FLOW SIMULATION OF A NON-NEWTONIAN FLUID THROUGH A BIFURCATION TUBE USING THE CFD ANALYSIS (CFD를 이용한 분지관 비뉴턴 해석)

  • Hwang, D.;Yoo, S.S.;Park, H.K.
    • 한국전산유체공학회:학술대회논문집
    • /
    • 2008.10a
    • /
    • pp.177-180
    • /
    • 2008
  • The objective of this study is to get simulation data about pulsatile flow of a non-Newtonian fluid through a bifurcated tube. All the process was based on CFD method, with a commercial FVM code, SC/Tetra ver. 6.0 for solving, and with CATIA R16 for generating geometries. To define a non-Newtonian fluid, the following viscous models are used; the Powell-Eyring model, the modified Powell-Eyring model, the Cross model, the modified Cross model, the Carreau model, the Carreau-Yasuda model and the modified Power Law model. The flow calculation data using each model were compared with the other data of a existing paper. Finally, the Carreau model was recognized to give the best result with the SC/Tetra code, and the succeeding simulations are made with the model. For the pulsating flow condition, the sine wave type velocity profile is given as the inlet boundary condition. To investigate the effect of geometries and mesh, the pre-test is carried out with various curvature conditions of the bifurcated corner, and then with various mesh conditions. The final process is to calculate flow variables such as the wall shear stress (WSS) and the wall shear stress gradient (WSSG). To validate all the result, the simulation is compared with the existing data of the other papers. Generally speaking, there is a noticeable difference in the maximum and minimum value of WSS. It is not sure that the values in each data are on the exactly same location. However, the overall trend is similar. The next study needs to investigate the same situation by experimental method. Furthermore, if the flow is simulated with more pulsatile conditions, more data of flow field through a bifurcated tube could be achieved.

  • PDF

A Review for Non-linear Models Describing Temperature-dependent Development of Insect Populations: Characteristics and Developmental Process of Models (비선형 곤충 온도발육모형의 특성과 발전과정에 대한 고찰)

  • Kim, Dong-Soon;Ahn, Jeong Joon;Lee, Joon-Ho
    • Korean journal of applied entomology
    • /
    • v.56 no.1
    • /
    • pp.1-18
    • /
    • 2017
  • Temperature-dependent development model is an essential component for forecasting models of insect pests as well as for insect population models. This study reviewed the nonlinear models which explain the relationship between temperature and development rate of insects. In the present study, the types of models were classified largely into empirical and biophysical model, and the groups were subdivided into subgroups according to the similarity of mathematical equations or the connection with original idea. Empirical models that apply analytical functions describing the suitable shape of development curve were subdivided into multiple subgroups as Stinner-based types, Logan-based types, performance models and Beta distribution types. Biophysical models based on enzyme kinetic reaction were grouped as monophyletic group leading to Eyring-model, SM-model, SS-mode, and SSI-model. Finally, we described the historical development and characteristics of non-linear development models and discussed the availability of models.

Determination of Self Diffusion Distributions of Molten Polyurethanes by Relaxation Spectra (용융 폴리우레탄의 완화 스펙트럼에 의한 자체확산분포 결정)

  • Kim, Nam-Jeong
    • Journal of the Korean Chemical Society
    • /
    • v.50 no.3
    • /
    • pp.196-202
    • /
    • 2006
  • The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

On the Hydration Numbers and Activity Coefficients of Some Salts Present in Sea Water

  • Sung, Yong Kil;Jhon, Mu Shik
    • 한국해양학회지
    • /
    • v.5 no.1
    • /
    • pp.1-5
    • /
    • 1970
  • The hydration numbers of some salts present in sea water have been calculated by a simple model for the equation of the dielectric constant, and the mean activity coefficients from the theoretical formula proposed by Jhon and Eyring. The validity of the theory for the electrolyte solution is tested by evaluating the hydration numbers and the mean activity coefficients of some 1:1, 1:2, 2:1 and 1:3 electrolytes in sea water. The results show good agreement with the observations.

  • PDF

Significant Structure Theory of Physical Adsorption

  • Yun-liang Wang;Taikyue Ree;Henry Eyring
    • Journal of the Korean Chemical Society
    • /
    • v.15 no.5
    • /
    • pp.265-274
    • /
    • 1971
  • A significant structure theory of monolayer physical adsorption is developed. The theory is tested with the adsorptions on graphite of gases Ar, $N_2$, $CHCl_3$, and $CCl_4$. A restricted rotation model is used for the polyatomic molecules $N_2$, $CHCl_3$, and $CCl_4$. The computed isotherms and heats of adsorption are in good agreement with experiment in all cases studied.

  • PDF

Implementation and Application of Integrated Model for ALT(Accelerated Life Test) (ALT 통합모형의 적용 및 응용)

  • Choi, Sung-Woon
    • Proceedings of the Safety Management and Science Conference
    • /
    • 2008.11a
    • /
    • pp.153-160
    • /
    • 2008
  • This paper presents the log likelihood function for integrated models for ALT such as exponential-general Eyring, Weibull-temperature and specific heat, lognormal-temperature and specific heat. Additionally this paper estimates the system reliability and mean time to failure(MTTF) for series, parallel, k of n, and standby system using ALT linkage parameter. Lastly this study designs three variable reliability acceptance sampling(RAS) plans such as type I, II censored test, sequential test by the use of integrated models for ALT.

  • PDF

Flow Analysis of the Modified Power-Law Non-Newtonian Fluids in the Stenotic Tubes (수정멱법칙 비뉴턴유체의 협착관내 유동장해석)

  • Sub, S.H.;Yoo, S.S.;Chang, N.I.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.6 no.3
    • /
    • pp.227-236
    • /
    • 1994
  • Steady flows of Newtonian and non-Newtonian fluids in the stenotic tubes with various stenotic shapes are numerically simulated. Validity of the modified power-law model as a constitutive equation for the purely viscous non-Newtonian fluid is discussed and the results of the power-law model are compared with those of the Carreau model, the Powell-Eyring model and experimental data for blood. Flow characteristics and reattachment lengths for non-Newtonian fluids in the stenotic tubes are presented extensively. Also, the analysis is extended to predict the influences of diameter ratio, stenosis spacing, number of stenosis and Reynolds number on the flow characteristics in the multiple stenotic tubes.

  • PDF

Bayes factors for accelerated life testing models

  • Smit, Neill;Raubenheimer, Lizanne
    • Communications for Statistical Applications and Methods
    • /
    • v.29 no.5
    • /
    • pp.513-532
    • /
    • 2022
  • In this paper, the use of Bayes factors and the deviance information criterion for model selection are compared in a Bayesian accelerated life testing setup. In Bayesian accelerated life testing, the most used tool for model comparison is the deviance information criterion. An alternative and more formal approach is to use Bayes factors to compare models. However, Bayesian accelerated life testing models with more than one stressor often have mathematically intractable posterior distributions and Markov chain Monte Carlo methods are employed to obtain posterior samples to base inference on. The computation of the marginal likelihood is challenging when working with such complex models. In this paper, methods for approximating the marginal likelihood and the application thereof in the accelerated life testing paradigm are explored for dual-stress models. A simulation study is also included, where Bayes factors using the different approximation methods and the deviance information are compared.