• Fire Science and Engineering
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• v.30 no.5
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• pp.1-8
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• 2016

Safety management in hazardous areas with potentially explosive gas atmospheres (here in after referred to as hazardous areas) in large scale facilities dealing with combustible or flammable materials at home and abroad is very important (significant) for the coexistence of the company and local society based on business continuity management (BCM) and reliance. For the safety management in hazardous areas, two systems are mainly used: (1) the control system for the prevention of combustible or flammable substances and (2) the explosion proof system for the elimination of ignition sources when flammable gases are leaked to inhibit the transition to fire or explosion accidents. While technology and regulations on explosion proof facilities or devices for electrical ignition sources are well developed and defined, those for thermal ignition sources need to be more developed and established. In this study, the internal combustion engine in hazardous areas was investigated to determine the risk of ignition. For this purpose, document searches were conducted on the relevant international standards and accidents cases and risk analysis reports. In addition, this study assessed the application cases of the diesel engine's safety equipment, such as spark arresters regarding the site of process safety management (PSM) system in central Korea. To practically apply these results to the hydrocarbon industry, the safety management method for explosion prevention in hazardous areas was provided by risk identification for ignition sources of internal combustion engines, such as diesel engines.

• Clean Technology
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• v.20 no.4
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• pp.398-405
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• 2014

In the treatment of spent high energetic materials, the issues such as environmental pollution, safety as well as working capacity should be carefully considered and well examined. In this regard, incineration has been recommended as one of the most promising processes for the disposal of such explosives. Due to the fact that high energetic materials encompass various types and their different characteristics, the technology development dealing with various materials is not an easy task. In this study, rigorous modeling and dynamic simulation was carried out to predict dynamic physico-chemical phenomena for research department explosive (RDX). Plug flow reactor was employed to describe the incinerator with 263 elementary reactions and 43 chemical species. Simulation results showed that safe operations can be achieved mainly by controlling the reactor temperature. At 1,200 K, only thermal decomposition (combustion) occurred, whereas increasing temperature to 1,300 K, caused the reaction rates to increase drastically, which led to ignition. The temperature further increased to 3,000 K which was the maximum temperature recorded for the entire process. Case studies for different operating temperatures were also executed and it was concluded that the modeling approach and simulation results will serve as a basis for the effective design and operation of RDX incinerator.

• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.331-332
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• 2014

Underground power plant is required the strict safety management and safety assessment. Because it is the high risk of explosion by characteristic of enclosed space. In case gas leak of enclosed space, the ventilation facilities is very important in order to prevent explosion by the maintain less than the LEL(lower explosive limit). Thus, Through a safety assessment of ventilation volume is to reduce the risk for ventilation facilities in Underground power plant.

• Journal of Power System Engineering
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• v.8 no.1
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• pp.18-23
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• 2004

The direct injection diesel engine is one of the most efficient thermal engines. For this reason DI diesel engines are widely used for heavy-duty applications. But the world is faced with very serious problems related to the air pollution due to the exhaust emissions of diesel engine. So, that is air pollution related to exhaust gas resulted from explosive combustion should be improved. Exhaust Gas Recirculation(EGR) is a proven method to reduce NOx emissions. In this study, the experiments-were performed at various engine loads while the EGR rates were set from 0% to 20%. The emissions trade-off and combustion of diesel engine are investigated. Hot and cooled EGR are achieved without cooling and with cooling respectively. It was found that the exhaust emissions with the EGR system resulted in a very large reduction in oxides of nitrogen at the expense of higher smoke emissions. Also, the reduction rates of NOx emissions for hot and cooled EGR are similar at load 20%.

• Journal of the Korean Ceramic Society
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• v.34 no.5
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• pp.473-482
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• 1997

Titanium carbide(TiC) has a poor sinterability due to the strong covalent bond. Thus, it is generally fabricated by either hot pressing or pressureless-sintering at elevated temperature by the addition of sintering aids such as nickel(Ni), molybdenum(Mo) and cobalt(Co). However, these sintering methods have the following disadvantages; (1) the complicated process, (2) the high energy consumption, and (3) the possibility of leaving inevitable impurities in the product, etc. In order to reduce above disadvantages, we investigated the optimum conditions under which dense titanium carbide bodies could be synthesized and sintered simultaneously by high pressure self-combustion sintering(HPCS) method. This method makes good use of the explosive high energy from spontaneous exothermic reaction between titanium and carbon. The optimum conditions for the nearly full-densification were as follows; (1) The densification of sintered body becomes high by increasing the pressing pressure from 400kgf/$\textrm{cm}^2$ upto 1200 kgf/$\textrm{cm}^2$. (2) Instead of adding the coarse graphite or activated carbon, the fine particles of carbon black should be added as a carbon source. (3) The optimum molar ratio of carbon to titanium (C/Ti) was unity. In reality, titanium carbide body which were prepared under optimum conditions had relatively dense textures with the apparent porosity of 0.5% and the relative density of 98%.

• Journal of the Korean Institute of Gas
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• v.10 no.1 s.30
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• pp.19-25
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• 2006

Explosion limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosion limits are used to classify flammable materials according to their relative flammability. Such a classification is important for the safe handling, storage, transportation of flammable substances. In this study, the lower explosion limits(LEL) of the flammable mixtures predicted with the appropriate use of the vapor composition and the heat of combustion of the individual components which constitute mixture. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the explosive properties of flammable mixtures with improved accuracy and the broader application for other flammable substances.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.5
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• pp.188-194
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• 2005

The direct injection diesel engine is one of the most efficient thermal engines. For this reason DI diesel engines are widely used for heavy-duty applications. But the world is faced with very serious problems related to the air pollution due to the exhaust emissions of diesel engine. So, that is air pollution related to exhaust gas resulted from explosive combustion should be improved. Exhaust Gas Recirculation(EGR) is a proven method to reduce NOx emissions. In this study, the experiments were performed at various engine loads while the EGR rates were set from $0\%$ to $30\%.$ The emissions trade-off and combustion of diesel engine are investigated. The brake specific fuel consumption rate is very slightly fluctuated with EGR in the range of experimental conditions. The ignition delay increased with increasing EGR rate. The maximum value of premixed combustion for the rate of heat release is increased with increasing EGR rate. NOx emissions are decreased with increasing EGR rate at high load and high speed. It was found that the exhaust emissions with the EGR system resulted in a very large reduction in oxides of nitrogen at the expense of higher smoke emissions.

• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2257-2262
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• 2014

$C_{60}$ is widely investigated because of its unique structure. But its applications in solid propellant seem to be relatively neglected. $C_{60}$ has more outstanding features than carbon black which is widely used as a catalyst ingredient of solid propellant. To combine the advantages of fullerene and lead salts, another good composite in propellant catalysts, we synthesized a kind of fullerene phenylalanine lead salt (FPL) and explored its thermal performances by differential thermal analysis (DTA) and thermogravimetry analysis (TGA). The results show it undergoes four exothermic processes started from 408 K. Combined TGA and X-ray diffractometer (XRD), the decomposition mechanism of FPL was derived by TG-IR and comparing IR spectra of FPL and its residues after burned to $327^{\circ}C$, $376^{\circ}C$ and $424^{\circ}C$, respectively. Effect of FPL on the decomposition characteristic of hexogen (RDX), a type of explosive in propellant, has been investigated using DTA at different heating rate, which shows the decomposition temperatures of the explosive are all reduced by more than 20 K. The corresponding activation energy ($E_a$) is decreased by $30kJ{\cdot}mol^{-1}$. So FPL has potential application as a combustion catalyst in solid propellant.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.617-621
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• 2017

The performance characteristics of aluminized high explosive are considered by varying the aluminum(Al) concentration in a two-phase model. Since the time scales of the characteristic combustion process of high explosives and Al particles differ, the process of energy release behind the leading detonation wave front occurs over an extended period of time. Two cardinal observations are reported: a decrease in detonation velocity with an increase in Al concentration and a double front detonation (DFD) feature when anaerobic Al reaction occurs behind the front. In the current study, a series of confined rate sticks are considered for characterizing the performance of aluminized HMX with a maximum Al concentration of 50%. The simulated results are compared with the experimental data for 5%-25% concentrations.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.423-425
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• 2017

When many space launchers and rockets need to be separated, the pyrotechnic separators have been widely used because of their high reliability and high energy generation. However, intensive pyroshock and debris from the high-explosive type separator may cause fatal damage to the equipment inside of the space launchers or rockets. To solve this problem, a pressure-cartridge type low-impact separator has been developed. In this study, one of the low-impact separators, the split-type pyrolock, was used. We established a mathematical model for the split-type pyrolock that simulates the state of combustion gas and the separation behavior of four independent internal components and verified the mathematical model through comparing with experiment results.