• Journal of Advanced Marine Engineering and Technology
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• v.22 no.6
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• pp.854-861
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• 1998

The demand of LNG as a cheap and clean energy which does not cause an environmental problem has sharply been increased in Korea. In general LNG is stored in a cargo tank specially designed as a liquid state below $-162^{\circ}C$. The main engine of a LNG carrier is generally a steam boiler because LNG is a highly flammable fluid with the possibility of explosion. The main engine of a cargo ship has to be capable of the propulsion load and various auxiliary loads for the safe navigation since it is the primary energy source. Therefore the evaluation of a main boiler's energy capacity is a key design point in the planning of LNG carrier's construction. This research is to develop the computational program for the analysis of steam boiler Heat balance for LNG carrier.

• Journal of The Korean Astronomical Society
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• v.39 no.4
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• pp.95-105
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• 2006

We have calculated the cosmic ray(CR) acceleration at young remnants from Type Ia supernovae expanding into a uniform interstellar medium(ISM). Adopting quasi-parallel magnetic fields, gasdynamic equations and the diffusion convection equation for the particle distribution function are solved in a comoving spherical grid which expands with the shock. Bohm-type diffusion due to self-excited $Alfv\acute{e}n$ waves, drift and dissipation of these waves in the precursor and thermal leakage injection were included. With magnetic fields amplified by the CR streaming instability, the particle energy can reach up to $10^{16}Z$ eV at young supernova remnants(SNRs) of several thousand years old. The fraction of the explosion energy transferred to the CR component asymptotes to 40-50 % by that time. For a typical SNR in a warm ISM, the accelerated CR energy spectrum should exhibit a concave curvature with the power-law slope flattening from 2 to 1.6 at $E{\gtrsim}0.1$ TeV.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2014.10a
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• pp.268-269
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• 2014

The purpose of this research is to investigate characteristics for way decision of indoor evacuation, when humans are faced on disaster such as fire, earthquake and explosion. As a research, it is found that majority of evacuation behavior characteristics was in a fire, disaster.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1988-1992
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• 2010

4-Amino-1,2,4-triazole copper complex (4-ATzCu) was synthesized, and its thermal behaviors, nonisothermal decomposition reaction kinetics were studied by DSC and TG-DTG techniques. The thermal decomposition reaction kinetic equation was obtained as: $d\alpha$ / dt =$10^{22.01}$ (1-$\alpha$)[-ln(1-$\alpha$)]$^{1/3}$ exp($-2.75\times10^4$ /T). The standard mole specific heat capacity of the complex was determined and the standard molar heat capacity is 305.66 $J{\cdot}mol^{-1}{\cdot}K^{-1}$ at 298.15 K. The entropy of activation $({\Delta}S^{\neq})$, enthalpy of activation $({\Delta}H^{\neq})$, and Gibbs free energy of activation $({\Delta}G^{\neq})$ are calculated as 171.88 $J{\cdot}mol^{-1}{\cdot}K^{-1}$ 225.81 $kJ{\cdot}mol^{-1}$ and 141.18 $kJ{\cdot}mol^{-1}$, and the adiabatic time-to-explosion of the complex was obtained as 389.20 s.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.7
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• pp.677-683
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• 2011

Until now, several empirical models for assessing the damage due to TNT explosions have been proposed. A set of analytical solutions for the time-dependent radius of an expanding fire-ball after detonation of TNT was obtained by solving the continuity, Euler (momentum), and energy equations with a "polytrope" assumption at the fire-ball center. The shock waves developed from the rapid expansion of a fire-ball under water were obtained by using the KirkwoodBBethe hypothesis. The calculated period of bubble oscillation and the maximum radius of the bubble resulting from the fire-ball due to a violent underwater TNT explosion were in good agreement with the experimental data.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2267-2273
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• 2011

A novel energetic material, 1-amino-1-(2,4-dinitrophenylhydrazinyl)-2,2-dinitroethylene (APHDNE), was synthesized by the reaction of 1,1-diamino-2,2-dinitroethylene (FOX-7) and 2,4-dinitrophenylhydrazine in N-methyl pyrrolidone (NMP) at 110 $^{\circ}C$. The theoretical investigation on APHDNE was curried out by B3LYP/6-311+$G^*$ method. The IR frequencies analysis and NMR chemical shifts were performed and compared with the experimental results. The thermal behavior of APHDNE was studied by DSC and TG/DTG methods, and can be divided into two crystal phase transition processes and three exothermic decomposition processes. The enthalpy, apparent activation energy and pre-exponential factor of the first exothermic decomposition reaction were obtained as -525.3 kJ $mol^{-1}$, 276.85 kJ $mol^{-1}$ and $10^{26.22}s^{-1}$, respectively. The critical temperature of thermal explosion of APHDNE is 237.7 $^{\circ}C$. The specific heat capacity of APHDNE was determined with micro-DSC method and theoretical calculation method, and the molar heat capacity is 363.67 J $mol^{-1}K^{-1}$ at 298.15 K. The adiabatic time-to-explosion of APHDNE was also calculated to be a certain value between 253.2-309.4 s. APHDNE has higher thermal stability than FOX-7.

• Nuclear Engineering and Technology
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• v.28 no.2
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• pp.103-117
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• 1996

A mathematical model of vapor explosion propagation is presented. The model predict two-dimensional, transient flow fields and energies of the four fluid phases of melt drop, fragmented debris, liquid coolant and vapor coolant by solving a set of governing equations with the relevant constitutive relations. These relations include melt fragmentation, coolant-phase-change, and heat and momentum exchange models. To allow thermodynamic non-equilibrium between the coolant liquid and vapor, an equation of state for oater is uniquely formulated. A multiphase code, TRACER, has been developed based on this mathematical formulation. A set of base calculations for tin/water explosions show that the model predicts the explosion propagation speed and peak pressure in a reasonable degree although the quantitative agreement relies strongly on the parameters in the constitutive relations. A set of calculations for sensitivity studies on these parameters have identified the important initial conditions and relations. These are melt fragmentation rate, momentum exchange function, heat transfer function and coolant phase change model as well as local vapor fractions and fuel fractions.

• Structural Engineering and Mechanics
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• v.51 no.5
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• pp.755-771
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• 2014

Environmental changes, especially global climate change, are creating new challenges to the development of the Arctic regions, which have substantial energy resources. And attention to offshore structures has increased with oil and gas development. The structural impact response of an explosion-resistant profiled blast walls normally changes when it operates in low temperatures. The main objectives of this study are to investigate the structural response of blast walls in low temperature and suggest useful guidelines for understanding the characteristics of the structural impact response of blast walls subjected to hydrocarbon explosions in Arctic conditions. The target temperatures were based on the average summer temperature ($-20^{\circ}C$), the average winter temperature ($-40^{\circ}C$) and the coldest temperature recorded (approximately $-68^{\circ}C$) in the Arctic. The nonlinear finite element analysis was performed to design an explosion-resistant profiled blast wall for use in Arctic conditions based on the behaviour of material properties at low temperatures established by performing a tensile test. The conclusions and implications of the findings are discussed.

• Resources Recycling
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• v.28 no.4
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• pp.51-58
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• 2019

Dismantlement of lithium primary batteries without explosion is required to recycle the lithium primary batteries which could be exploded by heating too much or crushing. In the present study, the optimum discharging condition was investigated to dismantle the batteries without explosion. When the batteries were discharged with $0.5kmol{\cdot}m^{-3}$ sulfuric acid, the reactivity of the batteries decreased after 4 days at $35^{\circ}C$ and after 1 day at $50^{\circ}C$, respectively. This result shows that higher temperature removed the high reactivity of the batteries. Because loss of metals recycled increases when the batteries are discharged only with the sulfuric acid, discharging process using acid solution and water was newly proposed. When the batteries were discharged with water during 24 hours after discharging with $0.5kmol{\cdot}m^{-3}$ sulfuric acid during 6 hours, the batteries discharged were dismantled without explosion. Because decrease in loss of metals was accomplished by new process, the recycling process of the batteries could become economic by the 2-step discharging process.

• Journal of the Korean Institute of Gas
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• v.28 no.2
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• pp.76-83
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• 2024

In the semiconductor manufacturing process, the Diffusion process generates various reactive by-products. These by-products are deposited inside the pipes of post-processing and exhaust treatment systems, posing a potential risk of substantial dust explosions. In this study, three methods material verification, selection of analysis samples, and risk analysis were employed to address the substances produced during the Diffusion process. Among the materials handled in the Diffusion process, ZrO₂, TEOD, and E-DEOS were identified as raw material capable of generating by-product dust. Test for Minimum Ignition Energy and dust explosion were conducted on the by-products collected from each processing facility. The results indicated that, in the case of MIE, none of the by-products ignited. However, the dust explosion test revealed that ZrO₂ exhibited a maximum pressure of 7.6 bar and K_st value of 73.3 bar·m/s, its explosive hazard. Consequently, to mitigate such risks in semiconductor processes, it is excessive buildup.