• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.101-110
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• 2014

Expansion agent is a very effective admixture for prevention of cracking due to autogenous/drying shrinkage and this can induce internal chemical prestress to embedded reinforcement. In this paper, tension-softening and hardening in cement mortar with steel and CSA expansion agent are experimentally evaluated. Cement mortar with steel reinforcement is prepared and tensile strength test is performed for evaluation of cracking and tensile behavior. In spite of slightly reduced strength and elasticity in CSA mortar, significantly increased tension-hardening behavior is evaluated in CSA mortar with induced chemical prestress. Furthermore previous tension softening models are compared with the test results and improvement are proposed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.3
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• pp.125-132
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• 2014

Steel fiber is a effective composite for crack resistance and improve structural performance under tensile loading. This study presents an evaluation of crack resistance and structural performance in cement mortar with steel fiber and expansion agent through internal chemical prestressing. For this work, cement mortar samples with 10% replacement of cement binder with CSA (Calcium-Sulfo-Aluminate) expansion agent and 1% volume ratio of steel fiber are prepared. Including basic mechanical properties, initial cracking load and fracture energy are evaluated in cement mortar beam with notch. Initial cracking load and fracture energy in cement mortar with CSA and steel fiber increase by 1.75 and 1.41~1.53 times compared with those in cement mortar with steel fiber. With optimum mix design for steel fiber and CSA expansive agent, the composite with chemical prestressing can be applied to various members and effectively improve crack resistance to external loading.

• Korean Journal of Materials Research
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• v.23 no.10
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• pp.599-605
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• 2013

CSA, a cement mineral compound that is mainly composed of $3CaO{\cdot}3Al_2O_3{\cdot}CaSO_4$, generates ettringite as a hydration product after a reaction with glass (lime), gypsum and water to speed up the hardening process and enhance the strength and degree of expansion. When used as a cement admixture, there is increased production of ettringite, which can improve the initial strength in the first three days and ameliorate the reduction in the initial strength caused by the use of fly ash in particular. In this study, a hydrate analysis was performed using XRD and SEM after substitution with fly ash (30%) and CSA (8%) with the goal of observing the effect of CSA on the initial strength of a cement mixture containing fly ash. The results of the analysis showed that an addition of CSA promoted the production of ettringite and improved the initial strength, resulting in the generation of hydrates, which can effectively enhance the long-term strength of these materials.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.12
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• pp.157-164
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• 2019

Superabsorbent polymers(SAPs) are powdery material that absorb water several tens or hundreds of times its own mass. It has been reported that when SAPs are incorporated into a high strength cementitious material, the autogenous shrinkage of the material is reduced. Cross-linked sodium polyacrylate type SAPs are relatively safe for human body and low in production cost. In order to apply this type of SAPs to the admixture for total(plastic+autogenous+drying) shrinkage reduction of high strength mortar, the shrinkage behavior of mortar when an expansion agent(EA) and SAPs were mixed together was analyzed. As a result, it was found that the shrinkage was reduced when an EA 5% (mass % of cement) and SAPs 0.4% were mixed together than the mortar containing only an EA 10%. The shrinkage was further reduced when EA 10% and SAPs 0.4% were incorporated into mortar.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.431-436
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• 2002

In this paper, to seek a solution of reducing autogenous shrinkage three types of bar restricted concrete specimens which have similar compressive strength were tested. The three type of concrete were plain concrete-P25 type, $10^{\circ}C$ fly-ash replaced concrete-F10 type, and $1^{\circ}C$ expansion admixture replaced concrete-SP1 type, and with the test result an experimental study was conducted to gain the tensile stress of concrete. From the result of P25, SP1, F10 tests, it was found that by the age of 14 the ratios of tensile stress to tensile strength of three specimens are $75^{\circ}C$, $47^{\circ}C$, $52^{\circ}C$ respectively. so we came to a conclusion that the SP1-type concrete has better capacity to reduce autogenous shrinkage than F10-type concrete at similar compressive strength condition.

• Journal of the Korean Ceramic Society
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• v.27 no.3
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• pp.437-443
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• 1990

The resistivity of cement paste and mortar for freezing and thawing was investigated for densifying the structure of cement paste and mortor, slag, diatomaceous earth and fly ash as blending materials and superplasticizer were used, and air entraining agent was added to absorb the volume expansion by freezing and thawing reaction. And then the specimens were subjected to freeze-thaw in water. When both of air entraining agent and superplasticizer as additives were mixed to specimens, their freeze-thaw resistance was enhanced by the air entraining effect and the water reduction effect. When 4% of slag were added to cement, freeze-thaw resistance was especially excellent. In addition, it was found that the specimens with blending materials were more influenced by curing periods than those without admixture. It is assumed that the curing periods contribute to exibit the potential hydraulicity and pozzolanic reactivity of blending materials and to densify their texture.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.323-324
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• 2010

The purpose of this study was to investigate alkali-silica reaction of accelerating agents in shotcrete. The test was performed with accelerating agents (aluminate, alkali-free, cement based mineral admixture) in the Type I cement. As a test result, using the nonreactive aggregates, detrimental expansion due to alkali-silica reaction doesn't occurred regardless of equivalent alkali contents of accelerating agent.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.190-195
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• 1997

The purpose of this study was to use daily waste incinerated ash, which was reclaimed worthlessly, as substitutes of fine aggregates in concrete. Various kinds of admixture was utilized to strengthen the cement mortar mixed with waste incinerated ash, and altered the curing condition to diminish the rate of expansion. By the results of this experiment, it was possible to produce the lightweight concrete, charactered with the gravity below 1.5 and over 160kg/$\textrm{cm}^2$ compressive strength by replacing all fine aggregates with waste incinerated ash. It was also observed that the low temperature curing condition, lessoned gas exhausts, was effective to increase the strength of cement mortar.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.921-924
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• 2000

The purpose of this paper is to investigate the effects of admixture such as AE water reducing agent and Flyash on properties of cement mortar for floor. As for the effects of AE water reducing agent kinds, fluidity and air content increase in order for melamine type, lignine type and naphtalene type. As Flyash contents increase, fluidity shows high, but air content shows decline tendency. compressive strength according to AE water reducing agent kinds increase in order for melamine type, lignine type and naphtalene type. As AE water reducing agent content increases, it shows to be decreased. As for the effects of Flyash, it retards at early age but at later age it gains high with increase of Flyash contents due to pozzanic reaction. Drying shrinkage shows to be docreased slightly with increase of AE water reducing agent.

• Journal of the Korean Ceramic Society
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• v.53 no.2
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• pp.215-221
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• 2016

In this study, the utilization of the by-products of various industries was examined using raw materials of CSA high-functional cement such as coal bottom ash, red mud, phosphate gypsum, etc. Technology to improve energy efficiency and reduce $CO_2$ was developed as part of the manufacturing process; this technology included lower temperature sintering ($150{\sim}200^{\circ}C$) than is used in the OPC cement manufacturing process, replacement of CSA cement with the main raw material bauxite, and a determination of the optimum mix condition. In order to develop CSA cement, a manufacturing system was established in the Danyang plant of the HANIL Cement Co. Ltd., in Korea. About 4,200 tons of low purity expansion agent CSA cement (about 16%) and about 850 tons of the lime-based expansion agent dead burned lime (about 8%) were produced at a rate of 60 tons per hour at the HANIL Cement rotary kiln. To improve the OPC cement properties, samples of 10%, 13%, and 16% of CSA cement were mixed with the OPC cement and the compressive strength and length variation rate of the green cement were examined. When green cement was mixed with each ratio of CSA cement and OPC cement, the compressive strength was improved by about 30% and the expansibility of the green cement was also improved. When green cement was mixed with 16% of CSA cement, the compressive strength was excellent compared with that of OPC cement. Therefore, this study indicates the possibility of a practical use of low-cost CSA cement employing industrial wastes only.