• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 1995년도 추계 학술대회논문집
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• pp.76-81
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• 1995

A numerical procedure for the analysis of transient behavior in a monolithic catalytic converter is presented. The thermal behavior of a monolithic catalytic converter is fully coupled with mass transfer and exothermic reaction between exhaust gases and the catalytic converter. In the present study, all these processes are solved simultaneously. The heat transfer process is approximated by combinging one dimensional convection and conduction and the chemical reaction is also simply modelled by using the concepts of reaction rate and reaction heat. All the partial diffenrential equations for the heat transfer, mass transfer and chemical reactions are appximated by using finite volume method. Resulting algebraic equations are solved using the Newton's method. To see the workability of present numerical method, two well known problems, say step increase and step decrease in the gas inlet temperature, have been calculated. Comparion of present solutions with previous solutions shows a good agreement.

• 폴리머
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• 제31권5호
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• pp.385-392
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• 2007

Poly (N-vinylpyrrolidone) (PVP) groups were grafted onto a poly(3-hydroxybutyrate-co-3-hydroryvalerate) (PHBV) backbone in order to modify its properties and synthesize a novel biocompatible copolymer. The crystallization behavior of PHBV and grafted PHBV was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). During the cooling-induced crystallization process, the crystallization temperature and the crystallization rate of the grafted PHBV decreased with increasing PVP weight fraction. On the heating scans of all grafted PHBV samples, a new crystallization exothermic peak appeared at almost the same temperature, suggesting the operation of a recrystallization process, while the melting temperature ($T_m$) and the apparent enthalpy of fusion (${\Delta}H_f$) were not affected by graft modification. During the isothermal crystallization process at the same temperature, the presence of side PVP groups decreased the spherulitic growth rate and the spherulitic band spacing with increasing PVP weight fraction in samples.

• 한국입자에어로졸학회지
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• 제10권4호
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• pp.177-182
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• 2014

In this study, nickel-coated aluminum (Ni/Al) powders were synthesized for the utilization of energetic applications. Oxide materials present at the surface of Al powders of $45{\mu}m$ in averaged size were removed by using sodium hydroxide(NaOH) solution which is used for controlling pH. Nickel material is coated into the surface of oxide-removed Al powders by electroless-plating process. The microstructure of fabricated Ni/Al powders shows that nickel layers with a few hundreds nm were very homogeneously formed onto the surface of Al powders. The oxidation behavior of Ni/Al exihibit somewhat faster oxidation rate than that of pure Al with surface oxidation. Also, the higher exothermic reaction was observed from the Ni/Al powders. From the result of this, nickel coating is very promising method to obtain highly reactive and safe Al powders for energetic applications.

• Journal of Photoscience
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• 제10권2호
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• pp.209-214
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• 2003

A series of coupled-hemicyanine dyes with alkylene spacer were successfully synthesized by a reaction of coupled aldehydes with corresponding salts, respectively. These coupled dyes had more excellent thermal properties (high decomposition temperature, stiff decomposition behavior) and higher molar absorption properties than an uncoupled dye. The coupled dyes with perchlorate anions showed the strongest exothermic decomposition while those with hexafluorophosphorate anions showed endothermic decomposition. As the coupling length (n=3, 4, 5, 6) increased, thermal properties decreased and dyes with even spacer was more thermally stable than dyes with odd spacer. Among several coupled dyes, C4-NP-ClO4 and C4-Cl-ClO4 exhibited the best recording properties with the lowest jitter value of 7.5∼9.5% in authoring disc.

• 한국포장학회지
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• 제21권3호
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• pp.107-113
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• 2015

This work focused on the study of thermal properties and kinetic behavior of LDPE-nanoclay composite films. The effect of nanoclay content (0.5, 1, 3, and 5 wt%) on thermal stability and crystallization characteristics of the nanocomposites were investigated by Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). The results from endothermic curve showed that the nanoclay played an important role in the crystallization of nanocomposites by acting as nucleating agent. From exothermic curve, there was a crystallization temperature shift which was attributed to crystallization process induced by nanoclay. The TGA results showed that the addition of nanoclay significantly increased the thermal stability of LDPE matrix, which was likely due to the characteristic of layered silicates/clays dispersed in LDPE matrix as well as the formation of multilayered carbonaceous-silicate char. A well-known Coats-Redfern method was used to evaluate the decomposition activation energy of nanocomposite. It was demonstrated that introducing of nanoclay to LDPE matrix escalated the activation energy of nanocomposite decomposition resulting in thermal stability improvement.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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• pp.47-54
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• 1999

A method is developed to include the effect of volume expansion in the description of the flame dynamics using G-equation. Line volume-source is used to represent the effect of the exothermic process of combustion with source strength assigned by the density difference between the burned and the unburned region. The present model provides good agreement with the experimental results by using realistic volume expansion ratio which was not reached in the previous researches. Including volume expansion, the flow predicts the same behavior of measured velocity field qualitatively. The flame propagation in varying flow field due to volume expansion provides a promising way to represent the wrinkled turbulent premixed flames in a numerically efficient manner.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제13권2호
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• pp.73-86
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• 2009

The problem of thermal stability of an exothermic reactive viscous fluid between two parallel walls in the plane Poiseuille and Couette flow configurations is investigated for different thermal boundary conditions. Neglecting reactant consumption, the closed-form solutions obtained from the momentum equation was inserted into the energy equation due to dissipative effect of viscosity. The resulting energy equation was analyzed for criticality using the variational method technique. The problem is characterized by two parameters: the Nusselt number(N) and the dynamic parameter($\Lambda$). We observed that the thermal and dynamical boundary conditions of the wall have led to a significant departure from known results. The influence of the variable pre-exponential factor, due to the numerical exponent m, also give further insight into the behavior of the system and the results expressed graphically and in tabular forms.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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• pp.394-401
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• 1996

This paper persents the crack control of mass concrete in massive machine foundation. The dimension of the machine foundation is 52.6m$\times$14.4m$\times$8.5m. The one distinctive characteristic of mass concrete is thermal behavior. Since the cement-water reaction is exothermic by nature, the temperature rises inside the massive concrete structure. When the heat is not quickly dissipated, it can be quite high. Significant tensile stresses may develop from the volume change associated with the increase of decrease of temperature within the mass concrete structure. To avoid occurrence of harmful cracks due to hydration heat, special attention shall be given to the construction of mass cnocrete structures. The temperature control system of mass concrete is proposed in this paper. This system contains a discussion of materials and concrete mix proportioning, thermal analysis, curing method, temperature control, and measurement of hydration heat. As will be seen throughout the paper, the proposed temperature control system have a great effect on the temperature-related cracks on mass concrete structures.

• Fibers and Polymers
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• 제4권4호
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• pp.195-198
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• 2003

Epoxidized polybutadiene (EPB) was prepared by polybutadiene (PB) with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. EPB was blended with poly(3-hydroxybutyrate) (PHB) up to 30 wt% by solution-precipitation procedure. The thermal decomposition of PHB/EPB blends was studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and differential thermal analysis (DTA). The thermograms of PHB/EPB blends contained a two-step degradation process, while that of pure PHB sample exhibited only one-step degradation process. This degradation behavior of PHB/EPB blends, which have a higher thermal stability as measured by maximum decomposition temperature and residual weight, is probably due to crosslinking reactions of the epoxide groups in the EPB component with the carboxyl chain ends of PHB fragments during the degradation process, and the occurrence of such reactions can be assigned to the exothermic peaks in their DTA thermograms.

• 대한기계학회논문집B
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• 제22권12호
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• pp.1669-1680
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• 1998

A method is developed to include the effect of volume expansion in the description of the flame dynamics using G-equation. Line volume-source is used to represent the effect of the exothermic process of combustion with source strength assigned by the density difference between the burned and the unburned region. The present model provides good agreement with the experimental results. Including volume expansion, the flow field is adjusted to accommodate the increased volume flow rate which crossing the flame front and the result predicts the same behavior of measured velocity field qualitatively. The effect of increasing volume expansion does not change the initial growth rate of flame area but increase the residence time. Consequently this effect increases the maximum area of flame front. The flame propagation in varying flow field due to volume expansion provides a promising way to represent the wrinkled turbulent premixed flames in a numerically efficient manner.