• 한국세라믹학회지
• /
• 제36권5호
• /
• pp.478-482
• /
• 1999

SrTiO3 :Al, Pr phosphor as an oxide compound phosphor is expect to be applied for a field emission display(FED). In this phosphor the excitation spectrum shows a different tendency according to an addition Al3+ and Pr3+ In this excitation spectrum the main peak at 359 nm represent excitation level of Pr3+(1S0longrightarrow1D2 transition) and the absorption characteristic according to Ti/Sr molar ratio is influenced by the structure symmetry. The emission spectrum exhibits the red luminescence with the radiative decay of the 1D2 states(1D2 longrightarrow3H4 transition) The concentration quenching phenomena at 1D2 state shows up as Al3+ and Pr3+ ion concentration increases.

• 음성과학
• /
• 제10권4호
• /
• pp.137-147
• /
• 2003

Speech synthesis can classify by synthesis way, that is waveform coding, source coding and mixture coding. Specially, waveform coding is suitable for high quality synthesis. However, it is not desirable by synthesis techniques of syllable or phoneme unit because it do not separate and handles excitation and formant part. Therefore, there is a need for pitch alteration method applied in synthesis by the rule in waveform coding. This study propose about pitch alteration method that use spectrum scaling after do to flatten spectra by subband linear approximation to minimize spectrum distortion. This paper show evaluation whether show excellency of some measure compared with LPC, Cepstrum, lifter function and method that propose. estimation method seeks distribution of each flattened signal and measured degree of flattened spectra Signal flattened is normalized, So that highest point amounts to zero, and distribution of signal ,whose average is zero, is calculated. this show result that measure the spectrum distortion rate to estimate performance of method that propose. The average spectrum distortion rate was kept below the average 2.12%, so the method that propose is superiors than existent method.

• 한국지진공학회:학술대회논문집
• /
• 한국지진공학회 1998년도 추계 학술발표회 논문집 Proceedings of EESK Conference-Spring 1998
• /
• pp.12-19
• /
• 1998

Response spectrum analysis method is widely used for seismic analysis of building structure. Analysis of structural vibration for equipment, machine and moving loads are executed by time history analysis. This method is very complex, difficult and tedious. In this study, maximum response of structure for this case are simply and fast. calculated by mode shape and response spectrum for excitation. At first, Response spectrum and time history analysis for some earthquake is carried and investigate the error of maximum displacement response for R. S. A. Secondly, The process for response spectrum analysis in excitation are calculated, and maximum model response are combined by CQC (Complete Quadratic Combination) methods. Finally, Combining maximum displacement response is compared with one of time history analysis.

• 한국소음진동공학회논문집
• /
• 제23권7호
• /
• pp.617-623
• /
• 2013

Accurate prediction of the radiated noise is important to reduce the noise of the washing machine. It is also necessary to predict the excitation force accurately because excitation force can induce noise. In order to predict the excitation force acting on the washing machine, this paper conducts source identification method by use of phase reference spectrum. In this method, the transfer function between the cabinet and the motor through FEM and the measured response from the surface of the cabinet is used. The analysis of the radiation noise from the identified exciting force has been investigated. The comparison between the predicted SPL and the measured SPL at 1m apart from the front side of the washing machine showed good tendency.

• 한국전산구조공학회논문집
• /
• 제17권1호
• /
• pp.67-74
• /
• 2004

동적 불안정 좌굴현상에 관한 연구는 다소 발표되고 있으나, 주기성을 가진 하중하에서의 동적 좌굴을 다룬 연구는 그리 많지 않은 편이다. 주기성을 가진 하중하에서의 거동은 STEP 하중하에서의 거동과는 다르리라 예상된다. 본 논문에서는 동적 불안정의 기본 메커니즘을 파악하기 위하여 양단 핀으로 고정된 정현형 아치가 정현형 조화하중을 받았을 때의 얕은 아치를 대상으로 한다. Newmark- β법에 의한 수치적분을 이용하여 비선형 운동 방정식의 변위 응답을 구하고, 얻어진 비선형 변위 응답으로 FFT(Fast Fourier Transform)에 의한 연속 응답 스펙트럼을 구해 동적 불안정 특성에 관해서 분석한다.

• 한국재료학회지
• /
• 제20권7호
• /
• pp.364-369
• /
• 2010

A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2006년도 춘계학술대회논문집
• /
• pp.193-196
• /
• 2006

Vibration overtests have been common problems in aerospace industry. A test item can be overtested at its resonances when it is excited by the traditional spectrum enveloping peaks in the field acceleration spectrum. This paper introduces the method of modifying the excitation specification to alleviate the overtesting problem. A vibration analysis was performed to estimate interface forces and acceleration responses. A finite element model that was verified by an extensive modal test enabled us to shape the acceleration input accurately The produced notched input will be used in the sinusoidal vibration test of the small satellite launch vehicle.

• Bulletin of the Korean Chemical Society
• /
• 제17권5호
• /
• pp.461-463
• /
• 1996

The laser-induced fluorescence excitation spectrum of 7-amino-4-(trifluoromethyl)coumarin in a supersonic jet has been recorded in the 340-352 nm region. The electronic band origin was observed at 28622.8 cm-1. Vibrational assignments for the three fundamental low-frequency modes and eight combination bands have been made for the S1 electronic excited state. The out-of-plane vibrations of this molecule have been characterized from the low-frequency assignments of the spectrum. The periodic potential energy function for the CF3 torsion, which satisfactorily fits the observed data, were also determined to be V(Φ)=95X(1-cos3Φ)-32X(1-cos6Φ) where Φ is the torsional angle. The relatively low torsional barrier of 99 cm-1 in S1 state could be explained by the small steric interactions between the functional groups attached to a bicyclic ring.

• Bulletin of the Korean Chemical Society
• /
• 제19권5호
• /
• pp.575-579
• /
• 1998

The 77 K luminescence and excitation spectra, and 298 K infrared and absorption spectra of $cis-{\Alpha}-[Cr(trien)Cl_2]Cl{\cdot}H_2O$ (trien=triethylenetetramine) have been measured. Ligand field electronic transitions due to spin-allowed and spin-forbidden are assigned. The zero-phonon line in the excitation spectrum splits into two components by $198\; cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the trien ligand have a strong σ-donor character, but chloride ligand has weak σ- and π -donor properties toward chromium(III) ion.

• 한국해양환경ㆍ에너지학회지
• /
• 제18권4호
• /
• pp.304-309
• /
• 2015

해양에서 기름 유출 사고로 인한 오염도를 정량적으로 평가하기 위해서, 사고 현장에서 기름을 직접 탐지할 수 있는 센서의 적용이 필요하다. 여러 형태의 기름 탐지 센서 중에서, 기름 성분에 의한 형광 현상(fluorescence)을 탐지 원리로 하는 센서는 해수 중에 존재하는 기름의 농도를 측정할 수 있으므로 효용성이 높은 장점을 갖고 있다. 그러나 이런 종류의 센서는 기름의 형광 현상을 야기시키기 위해서, 수은 램프(mercury lamp)와 같은 자외선 광원(ultraviolet light source)이 필요하고 다양한 종류의 광학 필터와 광전증배관(photomultiplier tube, PMT)과 같은 광학 센서가 주로 사용된다. 이러한 이유로 형광 측정을 기반으로 하고 있는 센서는 측정 플랫폼의 크기가 크기 때문에 현장에서 원활히 사용하기에 한계가 있으며, 고가의 부품들이 집적되어 있어, 센서의 가격이 높은 단점을 갖고 있다. 이러한 단점을 극복하기 위해서, 본 논문에서는 소형의 크기와 가격 경쟁력을 갖고 있는 형광 광도계 기반의 기름 탐지 센서를 설계하는 방법에 대해서 제시하였다. 형광 광도계의 설계 인자를 파악하기 위한 방법으로, 본 연구에서는 5종의 원유 샘플과 3종의 정제유를 이용하여, 기름의 여기 스펙트럼(excitation spectrum)과 발광 스펙트럼(emission spectrum)을 측정하였다. 여기 스펙트럼과 발광 스펙트럼의 측정을 위해서는 형광 분광기(fluorescence spectrometer)를 이용하였고, 측정된 스펙트럼 자료를 분석하여 형광 광도계(fluorimeter) 설계에 필요한 유종에 따른 공통 스펙트럼 파장 대역을 도출하였다. 본 실험을 통해서 모든 종류의 기름 샘플의 경우, 여기 스펙트럼과 발광 스펙트럼의 최고 값을 갖는 파장의 차이는 약 50 nm인 것으로 파악되었다. 실험 중에서, 여기광의 파장을 365 nm와 405 nm로 고정하였을 경우, 280 nm와 325 nm로 고정하였을 경우에 비해서 최대 발광(emission)의 세기가 작아지는 것을 확인할 수 있었다. 따라서 형광 광도계의 광원 파장을 365 nm 또는 405 nm로 사용할 경우, 광학 센서의 민감도(sensitivity)가 발광되는 빛의 세기를 측정할 수 있도록 설계에 반영해야 할 것으로 판단된다. 본 연구의 실험에서 도출된 결과를 통해서, 기름 탐지를 위한 형광 광도계의 광원, 광학 센서 그리고 광학 필터의 유효 파장 대역을 선택하는데 필요한 설계 인자를 파악할 수 있었다.