• Polymer(Korea)
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• v.35 no.6
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• pp.593-598
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• 2011

The IPA-co-HDO-co-(TPA/MA) copolymers for all-vanadium redox flow battery were synthesized by melt condensation polymerization using isophthalic acid(IPA), 1,6-hexandiol (HDO), terephthalic acid(TPA) and maleic anhydride(MA). The amination of chloromethylated IPA-co- HDO-co-(TPA/MA)(CIHTM) copolymer was carried out using trimethylamine, and the anion exchange membrane was also prepared by UV crosslinking reaction. The structure and thermal stability of IHTM copolymers were confirmed by FTIR, $^1H$ NMR, and TGA analysis. The anion membrane properties such as water uptake, ion exchange capacity, electric resistance and electrical conductivity, were measured by gravimetry, titration and LCR meter. The efficiency of the all-vanadium redox flow battery was analyzed. The ion exchange capacity, electric resistance and electrical conductivity were 1.10 meq/g, $1.98{\Omega}{\cdot}cm^2$, and 0.009 S/cm, respectively. The efficiency of charge-discharge, voltage, and energy for the allvanadium redox flow battery were 96.5, 74.6, 70.0%, respectively.

• 한국전산유체공학회:학술대회논문집
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• 2005.10a
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• pp.239-243
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• 2005

Fully three-dimensional Large Eddy Simulation calculations of the flow past 2D cavity are conducted to study the purging of neutrally buoyant or dense miscible contaminants introduced instantaneously inside the cavity. The length to depth ratio(L/D) is 2 and Reynolds number based on the depth is 3,360. Fully developed turbulent inflow are fed at the inlet from precursor simulation of channel flow. Mean flow pattern and unsteady features are investigated based on the experimental data of Pereira and Sousa. From the study of mass exchange processes, it is found that the mechanism of removal of the contaminant is very different between the non-buoyant and buoyant cases. In the buoyant case, internal wave motion which interacts with a strong cavity vortex is dominant in the ejection mechanism of the contaminants.

• Solar Energy
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• v.5 no.2
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• pp.35-45
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• 1985

A solar hot water storage tank was designed and constructed to examine the heat exchange performances on load side for the solar thermal storage in a single loop solar water heating system. In the tank helically coiled tube was immersed. The hot water was circulated from either top or bottom. The circulation flow rate was varied from 500 ml/min to 20,000 ml/min. The effect of flow rate was observed. The thermal performances according to the flow rate and flow direction were examined. The temperature distributions in the tank and inside of the tubes were plotted along the process of cooling.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2002.03a
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• pp.205-218
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• 2002

Recently, the water pollution of coastal sea area including harbor, bay and inland sea has been very serious and it causes various environmental impacts. In this study, water flow system of Danghang Bay, which has the narrow and long topographical characteristics with the narrow bay mouth and its flow is influenced principally by the tidal current, is investigated experimentally and numerically. In order to understand the tidal system of Danghang Bay, harmonic analysis is performed based on measured tidal range and flow velocity In addition, numerical model for tidal exchange is developed considering conditions of Danghang Ray. Calculated results show good agreement with measurements. Lastly. based on the proposed numerical model, exchange ratio of seawater volume in Danghang Bay is predicted.

• Journal of the Korean Association of Geographic Information Studies
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• v.11 no.1
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• pp.138-154
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• 2008

Geo-special technologies are being adopted in variety fields since the 3rd NGIS plan that was started at 1996. However, the required system or structure to guarantee the up-to-date validity and accuracy of the geospatial data - the most fundamental elements of the technology - was not constructed yet. All the activities related to geospatial data, including topographical map and numerical base map, are all implemented in separate way; from change of geographical objects and features, data gathering, and database construction to distribution, transfer and sharing of these data. The data model that links all the activities are required that enables consistent data-flow and effective and systematic work-flow. In this study, economic data renewal and exchange method was proposed, and benefit-cost analysis was implemented by comparing the conventional work-flow to newly proposed work-flow. The case study was implemented using the model that was adopted in Daegu metropolitan city, and the model was developed by reflecting these results.

• Journal of the Korean Electrochemical Society
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• v.11 no.1
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• pp.51-58
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• 2008

Many researches for effects of different flow configurations on performance of Proton Exchange Membrane Fuel Cell have extensively been done but the effects of flow direction at the same flow channel shape should be considered for optimal operation of fuel cell as well. In this paper a numerical computational methode for simulating entire reactive flow fields including anode and cathode flow has been developed and the effects of different flow direction at parallel flow was studied. Pressure drop along the flow channel and density distribution of reactant and products and water transport, ion conductivity across the membrane and I-V performance are compared in terms of flow directions(co-flow or counter-flow) using above numerical simulation method. The results show that the performance under counter-flow condition is superior to that under co-flow condition due to higher reactant and water transport resulting to higher ion conductivity of membrane.

• Proceedings of the SAREK Conference
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• 2005.06a
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• pp.97-97
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• 2005

• Journal of Mechanical Science and Technology
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• v.17 no.9
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• pp.1358-1370
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• 2003

The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

• Journal of the Korean Electrochemical Society
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• v.19 no.1
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• pp.14-20
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• 2016

Vanadium redox flow battery (VRFB) is an energy conversion device in which charging and discharging are alternatively carried out by oxidation and reduction reactions of vanadium ions with different oxidation states. VRFB consists of electrolyte, electrode, ion-exchange membrane, etc. The role of ion-exchange membranes in VRFB separates anolyte and catholyte and provides a high conductivity to hydrogen ions. Recently much attention has been devoted to develop ideal ion-exchange membranes for VRFB. A number of developed ion-exchange membranes should be evaluated to find out ideal ion-exchange membranes for VRFB. Long-term durability test is a crucial characterization of ion-exchange membranes for commercialization, but is very time-consuming. In this study, the life time prediction protocol of ion-exchange membranes in VRFB cell tests was developed through short-term single cell performance evaluation (real total operation time, 87.5 hrs) at three different current densities. We confirmed a decrease in test time up to 96.2% of real durability tests (expected total operation time, 2,296 hrs) and 5~6% of relative error discrepancy between the predicted and the real life time in a unit cell.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.11-12
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• 2008

본 논문에서는 전력IT 국책과제로 선정된 한국형 에너지 관리시스템(Korean Energy Management System, K-EMS)의 네트워크 해석 프로그램 중 하나인 급전원 조류계산(Dispatcher Power Flow, DPF) 프로그램의 구축 및 통합에 대해서 다룬다. 여기에서는 조류계산의 기본기능 보다는 실시간 운영을 위한 DB, 프로세스, 화면 간 연계방법을 설명하고, 기존 Off-line 검토용 조류계산 프로그램과의 차이점 및 급전원 조류계산 환경에 대해 서술한다. 본 논문에 소개된 급전원 조류계산 프로그램은 K-EMS의 중간 결과물인 Baseline 단계의 성과이며, 국내 실계통 데이터를 취득하여 성공적으로 실증시험을 마친 결과임을 밝혀둔다.