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Recycling of rayon industry effluent for the recovery and separation of Zn/Ca using Thiophosphinic extractant

  • Jha, M.K.;Kumar, V.;Bagchi, D.;Singh, R.J.;Lee, Jae-Chun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.05a
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    • pp.78-85
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    • 2006
  • In textile industries, waste effluent containing zinc is generated during the manufacture of rayon yarn from the wood pulp or cotton linters. Due to the strict environmental regulations and the presence of toxic metallic and other constituents, the discharge of industrial effluents in the sewage or disposal of solid sludge as landfill is restricted. Before recycling of zinc as zinc sulphate solution to the spinning-bath of the rayon manufacturing plant the zinc sulphate solution must be free from calcium, which is deleterious to the process as gypsum precipitates with the increase in concentration and forms scale in the bath. In the present work an attempt has been made to develop a process following solvent extraction technique using thiophosphinic extractants, Cyanex 272 and 302 modified with isodecanol and diluted in kerosene to recover zinc from rayon effluent. Various process parameters viz. extraction of zinc from different concentration of solution, distribution ratio, selective extraction, O/A ratio on extraction and stripping from the loaded organic, complex formation in the organic phase etc. have been studied to see the feasibility of the process. The extractant Cyanex 302 has been found selective for the recovery of 99.99% of zinc from the effluent above equilibrium pH 3.4 maintaining the O/A ratio of 1/30 leaving all the calcium in the raffinate. It selectively extracted zinc in the form of complex $[R_{2}Zn.3RH]_{org}$ and retained all the calcium in the aqueous raffinate. The zinc from the loaded Cyanex 302 can be stripped with 10% sulphuric acid at even O/A ratio of 10 without affecting the stripping efficiency. The stripped solution thus obtained could be recycled in the spinning bath of the rayon plant. The raffinate obtained after the recovery of zinc could be disposed safely without affacting environment.

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A study on lubrication characteristics between piston ring and cylinder bore of bent-axis type piston pump for vehicle (차량용 사축식 피스톤 펌프의 피스톤 링과 실린더 보어간의 윤활특성에 관한 연구)

  • Jung, Jae-Youn;Cho, Ihn-Sung;Song, Kyu-Keun;Baek, Il-Hyun;Oh, Seok-Hyung;Jung, Seok-Hoon;Jeong, Yong-Wook
    • Tribology and Lubricants
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    • v.23 no.5
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    • pp.201-206
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    • 2007
  • The bent-axis type piston pump which is driven by the piston rod works on the way that the piston rod drives the cylinder block, so the taper angle of the piston rod and the swivel angle between the cylinder block and the shaft are very important design factors. If the above factors cannot satisfy the conditions of optimum design, the friction loss between the cylinder bore and the piston increases, and the pump can even fail to work under conditions of severe friction and wear. Since the piston reciprocates in the cylinder bore with high velocity, and at the same time it rotates on its own axis and revolves on the center of the cylinder block, the decrease of the volume efficiency generated on account of the leakage between the cylinder bore and the piston. Therefore, to prevent this case, the piston ring is designed at the end of the piston, and the friction characteristics between the piston ring and the cylinder bore are in need of research due to its great influence on the performance of piston pump. Thus, in this paper, the elastic hydraulic oil's lubrication analyses of the film thickness, the pressure distribution, and the friction force, and so on, have been performed, and the lubrication characteristics between the piston ring and the cylinder bore are explored by the results of the numerical analysis, and it is contributed to realize the higher efficiency and the more advanced performance of the bent-axis type piston pump.

Significance of Armillaria Species in Taxonomy, Forest Ecology and Plant Pathology (뽕나무버섯속 버섯의 분류와 산림생태학적 및 병리학적 중요성)

  • Koo, Chang-Duck;Kim, Jin-Gun;Lee, Hwa-Yong;Park, Yong-Woo;Lee, Hee-Su
    • The Korean Journal of Mycology
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    • v.45 no.1
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    • pp.1-13
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    • 2017
  • Armillaria species are non-obligate root pathogens, as well as facultative parasites. The genus consists of about 40 species with worldwide distribution that are difficult to identify morphologically. Their hosts include conifers, hardwoods, vines, and even herbs. These fungi contribute to natural thinning and succession of vegetation in forests and decompose wood to develop edible fruiting bodies from spring to autumn. Its genets have a lifespan of up to 2000 years and have been found to occupy as much as 960 ha of forest land. Recently, forest tending work such as thinning of forests has resulted in the creation of tree stumps that support the growth of Armillaria, and these mushrooms have become an income source in mountainous areas. Therefore, identification of these species is needed. We review the difficulties in identification, suggest a species identification key for Korean indigenous species, and discuss the significance of Armillaria in terms of forest ecology and plant pathology.

Dynamics of Microalgae Along the Coastal Areas of Sooyoung Bay, Busan, South Korea

  • Prasad, Binod;Thiyam, General;Lee, Dong-Gyu;Kim, Moo-Sang;Cho, Man-Gi
    • Journal of Marine Bioscience and Biotechnology
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    • v.5 no.4
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    • pp.40-45
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    • 2011
  • Microalgae are one of the major, sustaining components of ecosystem processes and are responsible for biogeochemical reactions that drive our climate changes. Despite this, many marine microalgae are poorly described and little is known of their abundance and distribution along the coastal areas of Sooyoung Bay, Busan, South Korea. The present study has been conducted from November, 2011 to August, 2009 with the objective to provide an overview of the taxonomy diversity and abundance of microalgae along the coastal areas of the Sooyoung Bay. Water samples were collected from different sites, which were located by using a GPS tracker. Chlorophyll fluorescence of the water samples were measured by using ToxY-PAM dual-channel yield analyzer. The chlorophyll fluorescence values were relatively higher during the spring and summer and even in the region near to the sea port. Similarly the abundance of microalgae was higher near the port but diversity index had lower values. The temperature and pH values were same at all the sites. However, only the temperature varied during the sampling period, with higher values during summer and lower in winter. From the preliminary results, the following class of microalgae were found; Bacillariophyceae, Dinophyceae, Silicoflagellate and Cryptophyceae. With a future ongoing work, microalgae are being isolated to establish single cell culture and for identification using light microscopic observations, photography and molecular approaches.

Vibration analysis of nonlocal advanced nanobeams in hygro-thermal environment using a new two-unknown trigonometric shear deformation beam theory

  • Mouffoki, Abderrahmane;Bedia, E.A. Adda;Houari, Mohammed Sid Ahmed;Tounsi, Abdelouahed;Mahmoud, S.R.
    • Smart Structures and Systems
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    • v.20 no.3
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    • pp.369-383
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    • 2017
  • In this work, the effects of moisture and temperature on free vibration characteristics of functionally graded (FG) nanobeams resting on elastic foundation is studied by proposing a novel simple trigonometric shear deformation theory. The main advantage of this theory is that, in addition to including the shear deformation influence, the displacement field is modeled with only 2 unknowns as the case of the classical beam theory (CBT) and which is even less than the Timoshenko beam theory (TBT). Three types of environmental condition namely uniform, linear, and sinusoidal hygrothermal loading are studied. Material properties of FG beams are assumed to vary according to a power law distribution of the volume fraction of the constituents. Equations of motion are derived from Hamilton's principle. Numerical examples are presented to show the validity and accuracy of present shear deformation theories. The effects of hygro-thermal environments, power law index, nonlocality and elastic foundation on the free vibration responses of FG beams under hygro-thermal effect are investigated.

Releasing a Genetically Engineered Microorganism for Bioremediation

  • Sayler, Gary;Burlage, Robert;Cox, Chris;Nivens, David;Ripp, Steven;Ahn, Yeonghee;Easter, Jim;Wrner, Claudia;Jarrell, John
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.153-162
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    • 2000
  • A field study was performed to test effectiveness of a bloluminescent genetically engineered microorganism (GEM) for bioremediation process monitoring and control. The study employed Pseudomonas fluorescens HK44 that was the first strain approved for field application in the U.S. for bioremediation purposes. HK44 contains lux gene fused within a naphthalene degradative pathway, allowing this GEM to bioluminesce as it degrades naphthalene as well as substituted naphthalenes and other polycyclic aromatic hydrocarbons (PAHs) , Results showed that HK44 was maintained in both PAH-contarninated and uncontaminated soils even 660 days after inoculation. HK44 was able to produce bioluminescence in response to PAHs in soil. Although effectiveness of chemical remediation was not assessed due to heterogeneous distribution of contaminants, decreased concentration of naphthalene was shown in the soils, Taken together, HK44 was useful for in situ bioremediation process monitoring and control. This work is so far the only field release of a GEM for bioremediation purposes.

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Paradigm Shifts in the Regional Policy of the UK National Government and the Implications for the Korean Context (영국 지역정책 변화 동향과 우리나라에의 시사점)

  • Byun, Pill-Sung;Lee, Dong-Woo
    • Journal of the Economic Geographical Society of Korea
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    • v.11 no.1
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    • pp.111-129
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    • 2008
  • This study discusses the paradigm shifts in the regional policies of national governments which many countries have witnessed since the 1990s. Particularly, the study examines the historical trajectory which the regional policy of the UK national government has experienced until the 2000s since 1928 when the regional policy was implemented for the first time in the world, focusing on the recent trends after the mid-1990s. In the recent decade, the UK national government has shifted the focus of its regional policy towards the regional competitiveness and the devolved approach to regional development, from the interventionist top-down transformation of the spatial distribution of businesses and population via regulations and incentives for reducing regional disparities. Even in the midst of such a shift, the government has constantly sought to lessen the regional disparities in UK. Additionally, our work presents the policy implications for the future direction of regional policy which the national government of Korea should set in the face of the changing context.

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Gray-level Image Watermarking using Wavelet Transform (웨이브렛 변환을 이용한 그레이-레벨 영상 워터마킹)

  • Min, Sun-Jin;Chung, Hoon;Kim, Chung-Hwa
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.10a
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    • pp.487-490
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    • 2001
  • With the establishment of the optimized copyright, digital image watermarking technique is demended to identify the owner of a certain image and to avoid the unauthorized distribution of digital image copies. Also, a robust watermarking approach should survive several possible attacks, such as image processing and lossy image compession. The proposed scheme distributes the 256 gray-level signature information in discrete wavelet transform domain of the host image where is very little visible distortion. While much of the privious work used signature data that is a small fraction of th e host images the proposed approach can easily handle gray-scale Images. As the result, stable reconstruction can be obtained even when the images are transformed, JPEG lossy compression or otherwise modified by low-pass filtering operations.

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Bending analysis of porous microbeams based on the modified strain gradient theory including stretching effect

  • Lemya Hanifi Hachemi Amar;Abdelhakim Kaci;Aicha Bessaim;Mohammed Sid Ahmed Houari;Abdelouahed Tounsi
    • Structural Engineering and Mechanics
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    • v.89 no.3
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    • pp.225-238
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    • 2024
  • In this paper, a quasi-3D hyperbolic shear deformation theory for the bending responses of a functionally graded (FG) porous micro-beam is based on a modified couple stress theory requiring only one material length scale parameter that can capture the size influence. The model proposed accounts for both shear and normal deformation effects through an illustrative variation of all displacements across the thickness and satisfies the zero traction boundary conditions on the top and bottom surfaces of the micro-beam. The effective material properties of the functionally graded micro-beam are assumed to vary in the thickness direction and are estimated using the homogenization method of power law distribution, which is modified to approximate the porous material properties with even and uneven distributions of porosity phases. The equilibrium equations are obtained using the virtual work principle and solved using Navier's technique. The validity of the derived formulation is established by comparing it with the ones available in the literature. Numerical examples are presented to investigate the influences of the power law index, material length scale parameter, beam thickness, and shear and normal deformation effects on the mechanical characteristics of the FG micro-beam. The results demonstrate that the inclusion of the size effects increases the microbeams stiffness, which consequently leads to a reduction in deflections. In contrast, the shear and normal deformation effects are just the opposite.

Evaluation of Buckling Strength of Non-structured Plates by Using the Deformation Energy (변형에너지에 기반한 비정형 판부재의 좌굴강도 평가기법)

  • Zi, Goangseup;Kim, Hong-hyun;Ahn, Jin-young;Oh, Min-Han
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.3
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    • pp.102-113
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    • 2017
  • A new index for the buckling strength of non-structured plates is proposed. The external work or the deformation energy caused by the external loads or the boundary displacement controled by a load parameter is calculated along an equilibrium path of the member under consideration. If the second variation of the energy with respect to the parameter loses its positiveness, it defined as the limit of the stability. In contrast to the current method given in codes where the stability limit is evaluated by using only representative internal forces, the evaluation of the stability limit is always consistent even with the change of the distribution of the internal forces on the boundary. If the elasticity is concerned, the result from this proposed approach becomes identical to that from the classical methods.