• Title/Summary/Keyword: Evaporation Degradation

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Effect of Electrode Formation Process using E-beam Evaporation on Crystalline Silicon Solar Cell (E-Beam evaporation을 이용한 전극 형성 공정이 결정질 실리콘 태양전지에 미치는 영향 분석)

  • Choi, Dongjin;Park, Se Jin;Shin, Seung Hyun;Lee, Changhyun;Bae, Soohyun;Kang, Yoonmook;Lee, Hae-Seok;Kim, Donghwan
    • Current Photovoltaic Research
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    • v.7 no.1
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    • pp.15-20
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    • 2019
  • Most high-efficiency n-type silicon solar cells are based on the high quality surface passivation and ohmic contact between the emitter and the metal. Currently, various metalization methods such as screen printing using metal paste and physical vapor deposition are being used in forming electrodes of n-type silicon solar cell. In this paper, we analyzed the degradation factors induced by the front electrode formation process using e-beam evaporation of double passivation structure of p-type emitter and $Al_2O_3/SiN_x$ for high efficiency solar cell using n-type bulk silicon. In order to confirm the cause of the degradation, the passivation characteristics of each electrode region were determined through a quasi-steady-state photo-conductance (QSSPC).

Study on the dyestuff for acceration solar evaporation (함수의 천일증발촉진성 색소에 관한 시험)

  • 장판섭
    • YAKHAK HOEJI
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    • v.3 no.1
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    • pp.26-34
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    • 1957
  • The solar evaporation method is one of the most important and popular salt manufecturing method in Korea. The rate of evaporation of sea water depends on a complex climate factors. Of these factors, the most important is solar radiation and in particular the extent to which it is absorbed in the brine. By the addition of suitable dyestuff, a further increase in absorption is obtained and can result in all the radiation entering the brine being made available as heat. "Solivap Green", one of several dyestuffs which have been suggested for accelerating solar evaporation, was tested in this experiment. The results of the experiment. 1. Increase the evaporation rate of brine up to 20-25%. 2. Elevate the temperature of brine 2-$4^{\circ}C$. higher than that of brine adding no dyestuff. 3. Optimum dyestuff concentration is 25-30 mg/L and allowable maximum concentration can not exceeded 1000 mg/$m^2$ (50 mg/L). 4. Addition of dyestuff does not cause the degradation of salt produced. 5. A conversion table which indicates the concentrations for various depths of brine was prepared for engineering purpose. 6. Absorption spectrum of the dyestuff was studies, but toxicological and structural studies for the dyestuff have not been done in this experiment.

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Evaporation Characteristics of Oil and Abundance Ratio of Hydrocarbon Compounds at Different Temperatures (온도 변수에 대한 유류의 휘발특성 및 탄화수소 화합물의 존재비에 관한 연구)

  • Choi, Jung-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.7
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    • pp.1116-1123
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    • 2021
  • Oil spilled in seawater undergoes physical and chemical changes as well as biological degradation through various weathering processes, such as evaporation, diffusion, dispersion, emulsification, dissolution, oxidation, and sedimentation. Evaporation is one of the most immediate and prompt weathering processes, and it has the greatest influence on majority of pollutants. In this study, the evaporation characteristics of different oil samples were studied; the volatilization characteristics of gasoline, kerosene, and diesel were compared at average seawater (25 ℃) and near-equator (35 ℃) temperatures. The oil samples were pre-treated and then collected at regular intervals. Gas chromatography-mass spectrometry analysis was performed, and the changes in the amount of the hydrocarbons were calculated.

A Study on the degradation mechanism of PAN-LiCLO$_4$ Polymer Electrolyte EC windows (PAN-LIClO$_4$ 계 고분자전해질 EC창의 열화 기구에 관한 연구)

  • 김용혁;김형선;조원일;조병원;윤경석;박인철
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.223-230
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    • 1997
  • Tungsten oxide and nickel oxide thin films were deposited onto ITO(Indium Tin Oxide) transparent glass by the E-beam evaporation and were used as a cathode and an anode for the EC(Electrochromic) smart window, respectively. Stoichiometric structures of the deposited films were investigated by the implementation of XPS(X-ray Photoelectron Spectroscopy) analysis and the results were $WO_{2.42}$ and $NiO_{0.44}$. This oxygen deficincy might affect affect the transparency of the thin films. The electrolyte for the EC smart windows was PAN-$LiCIO_4$ conducting polymer. EC(Ethylene Carbonate)and PC(Propylene Carbonate) were added as plasticizer to enhance ion conductivity. When the weight ratio of the EC : PC was 3 : 1, transmission difference and cycle life performance were tested. Polymer EC windows showed 40% $\Delta$T at 1.5V operating volage for 3,200 cycles. Structural degradation was observed by the SIMS(Secondary Ion Mass Spectroscopy) analysis and it was confirmed that structural degradation of polymer caused by the solvent evaporation was the main cause to degrade EC smart windows.

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Oxidative Degradation of a Drug during the Course of Diffusion Across the Skin

  • Choi, Hoo-Kyun
    • Archives of Pharmacal Research
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    • v.20 no.6
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    • pp.637-642
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    • 1997
  • Degradation of a compound with a hydroxyl group during the course of its diffusion across the skin was investigated. Based on the experimental findings of ashortened retention time of a degradant peak from post-diffusion samples and from the ability to evaporate radioactivity from such samples, it seems that during diffusion the parent compound degrades into a more hydrophilic product which is then oxidized. A tritium label at the carbon with a hydroxyl group was released as a tritiated water. When the post-diffusion samples were left open to the air allowing evaporation of water, there was a corresponding decrease in radioactivity of such samples. There was a linear relationship between the time left open and the fraction of radioactivity lost. When such samples were fractionated by HPLC, and then had their radioactivities measured by scintillation counting, two peaks wre identified. The first peak, which may be attributable to tritiated water, was eluted at the same retention time as the solvent front. The second peak eluted at the retention time of the parent compound. When the evaporation/loss of radioactivity experiment was repeated using a $^{14}C$-labeled compound there was no significant loss of radioactivity, indicating that the earlier loss with $^{3}H$-labeled compound was related to the formation and loas sof tritiated water.

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Effect of enzyme treatment on the DSC and TGA behavior of silkworm powder

  • Jo, You-Young;Bae, Sung Min;Kim, HyunBok;Lee, Kwang Gill;Kweon, HaeYong
    • International Journal of Industrial Entomology and Biomaterials
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    • v.37 no.1
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    • pp.29-32
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    • 2018
  • Silkworm powder's thermal property is an important factor for its storage and marketing. This study examined the effect of edible enzyme on the thermal property of silkworm powder using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC). Results of the TGA showed that regardless of the enzyme treatment, the weight loss patterns of silkworm powders exhibited 3 step thermal property deterioration at approximately $80^{\circ}C$, $280^{\circ}C$, and $480^{\circ}C$ due to water evaporation and thermal degradation. This is similar with the DSC which also resulted in all samples two endothermic peaks attributed also to water evaporation and thermal degradation. These results indicated that the use of enzyme such as protease and cellulase might not affect significantly the thermal properties of silkworm powder.

Synthesis and High Photocatalytic Activity of Zn-doped TiO2 Nanoparticles by Sol-gel and Ammonia-Evaporation Method

  • Nguyen, Thanh Binh;Hwang, Moon-Jin;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.243-247
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    • 2012
  • Photocatalysis has been applied to decompose the waste and toxic materials produced in daily life and in the global environment. Pure $TiO_2$ (Zn-$TiO_2$-0) and Zn-doped $TiO_2$ (Zn-$TiO_2$-x, x = 3-10 mol %) samples were synthesized using a novel sol-gel and ammonia-evaporation method. The Zn-doped $TiO_2$ samples showed high photocatalytic activity for the degradation of methylene blue (MB). The physicochemical properties of the samples were investigated using XRD, SEM, ICP, DLS and BET methods. In addition, the most important measurement of photocatalytic ability was investigated by a UV-vis spectrophotometer. The effects of the mol % of zinc ion doping in $TiO_2$ on photocatalytic activity were studied. Among the mol % Zn ions investigated, the Zn-$TiO_2$-9 sample showed the highest photoreactivity. This sample removed 91.4% of the MB after 4 h, while the pure $TiO_2$ only removed 46.4% of the MB.

Studies on Moisture Evaporation and Economical Analysis for Composting of Piggery Slurry (양돈 슬러리 퇴비화 방법의 수분증발율 및 경제성 분석에 관한 연구)

  • Park, C.H.;Yoon, T.H.;Ryoo, J.W.;Kim, J.H.;Choi, T.B.;Choi, D.Y.;Kwag, J.H.;Jeong, K.W.;Kim, H.H.
    • Journal of Animal Environmental Science
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    • v.8 no.2
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    • pp.119-124
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    • 2002
  • To evaluate composting process of piggery slurry, we made $1m^3$ bench scale composting reactor, and investigated the input and output of mass, moisture evaporation, volatile solid degradation, and running cost. For 15 days experimentation the results was as followed, The quantity of sawdust used was 0.47ton(18,000won) per 1ton slurry. The amount of moisture evaporated was 16.8kg/kg VS degradated. Total evaporation and VS degradation were 24.8%, 5.7% respectably. To analysis the running cost of that, we included only two factors, sawdust cost and compost income. The compost price to sell was 63won/kg(50% of market price) it made 8,694won income to 756 won loss, but 25won/kg, it was $13,650{\sim}23,100won$ loss per 1 ton slurry in the current pig farmer's condition. This cost was $8.5{\sim}14.4%$ of pig production cost and damage strongly to pig farmers to treat it.

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Degradation of thin carbon-backed lithium fluoride targets bombarded by 68 MeV 17O beams

  • Y.H. Kim;B. Davids;M. Williams;K.H. Hudson;S. Upadhyayula;M. Alcorta;P. Machule;N.E. Esker;C.J. Griffin;J. Williams;D. Yates;A. Lennarz;C. Angus;G. Hackman;D.G. Kim;J. Son;J. Park;K. Pak;Y.K. Kim
    • Nuclear Engineering and Technology
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    • v.55 no.3
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    • pp.919-926
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    • 2023
  • To analyze the cause of the destruction of thin, carbon-backed lithium fluoride targets during a measurement of the fusion of 7Li and 17O, we estimate theoretically the lifetimes of carbon and LiF films due to sputtering, thermal evaporation, and lattice damage and compare them with the lifetime observed in the experiment. Sputtering yields and thermal evaporation rates in carbon and LiF films are too low to play significant roles in the destruction of the targets. We estimate the lifetime of the target due to lattice damage of the carbon backing and the LiF film using a previously reported model. In the experiment, elastically scattered target and beam ions were detected by surface silicon barrier (SSB) detectors so that the product of the beam flux and the target density could be monitored during the experiment. The areas of the targets exposed to different beam intensities and fluences were degraded and then perforated, forming holes with a diameter around the beam spot size. Overall, the target thickness tends to decrease linearly as a function of the beam fluence. However, the thickness also exhibits an increasing interval after SSB counts per beam ion decreases linearly, extending the target lifetime. The lifetime of thin LiF film as determined by lattice damage is calculated for the first time using a lattice damage model, and the calculated lifetime agrees well with the observed target lifetime during the experiment. In experiments using a thin LiF target to induce nuclear reactions, this study suggests methods to predict the lifetime of the LiF film and arrange the experimental plan for maximum efficiency.

Analysis of Degradation Characteristics for Oil-Paper Insulation using Tan Delta Measurement (Tan Delta 측정을 이용한 유침 절연지의 열화특성 분석)

  • Kim, Jeong-Tae;Kim, Woo-Bin
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1518-1523
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    • 2016
  • In this study, in order to understand the degradation characteristics of oil-paper insulation for power transformers and OF cables, tan delta was measured using cable model specimens with long-term accelerated thermal and electrical aging. In addition, to find out the degradation level due to the accelerated aging, tensile strengths of aged papers were measured. As a result, tan ${\delta}$ showed the characteristics of slight decrease at the first stage and then increase with the aging time, which could be analyzed due to the evaporation of remaining moisture and the change of aging rate with time. Also, the trend of tensile strengths with aging temperature and time was appeared to be exponentially decreased and by use of these data equivalent calculated lifetimes and accelerated aging factors were derived for each aging temperatures. After then, tan ${\delta}$ was analyzed with the equivalent operating years. For all different aging temperatures, the aged data were very well fit to the equivalent operating years and it is shown that tan ${\delta}$ was increased with the decrease of tensile strength.