• Title/Summary/Keyword: Equilibrium State

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Case Study on the Countermeasure Methods and Collapsed Sources of Segmental Retaining Wall Considering Site Conditions (시공환경을 고려한 블록식 보강토옹벽의 붕괴요인 분석 및 대책방안 사례연구)

  • Han, Jung-Geun;Cho, Sam-Deok;Jeong, Sang-Seom;Lee, Kwang-Wo;Kim, Ji-Sun
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.3
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    • pp.35-43
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    • 2005
  • The geosynthetic reinforced segmental retaining walls(SRW) are improved that the disadvantage of existed retaining wall and the workability in field. Recently, the segmental retaining wall is replacing the exited wall because it is quickly advanced to using by the block in-situ. The use, therefore, is increasing. But, the trends of the large scaled construction was developed that the problems likely to crack and collapse, those are caused of careless in design and construction of SRW not considering about various surrounding conditions. In this study, the cause analysis on destructed SRW was carried out that based on the datum of measured displacement of walls, rainfall features and ground sounding conditions. Also, the analysis of the global slope stability was carried out on collapsed section and non-collapsed section using critical equilibrium method. For the rational stability and analysis of slope including SRW structure, the site conditions including situations of topography, ground and histories of construction and collapse etc should be considered. The rational countermeasure methods for non-collapsed and collapsed areas may be sustained as much as possible current state.

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Simulation and Control of the Molten Carbonate System using Aspen $Dynamics^{TM}$ and ACM (Aspen $Dynamics^{TM}$와 ACM을 이용한 용융탄산염 연료전지 시스템의 모사 및 제어)

  • Jeon, Kyoung Yein;Kwak, Ha Yeon;Kyung, Ji Hyun;Yoo, Ahrim;Lee, Tae Won;Lee, Gi Pung;Moon, Kil Ho;Yang, Dae Ryook
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.423-431
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    • 2011
  • Recentincreasing awareness of the environmental damage caused by the $CO_2$ emission of fossil fuelsstimulated the interest in alternative and renewable sources of energy. Fuel cell is a representative example of hydrogen energy utilization. In this study, Molten Carbonate Fuel Cell system is simulated by using $Aspen^{TM}$. Stack model is consisted of equilibrium reaction equations using $ACM^{TM}$(Aspen Custom Modeler). Balance of process of fuel cell system is developed in Aspen $Plus^{TM}$ and simulated at steady-state. Analysis of performance of the system is carried out by using sensitivity analysis tool with main operating parameters such as current density, S/C ratio, and fuel utilization and recycle ratio.In Aspen $Dynamics^{TM}$, dynamics of MCFC system is simulated with PID control loops. From the simulation, we proposed operation range which generated maximum power and efficiency in MCFC power plant.

Dynamic Optimization of a Reactive Distillation Column Producing Methyl Acetate (메틸 아세테이트 생산을 위한 반응증류 공정의 동적 최적화)

  • Kim, Jiyong;Kim, Junghwan;Moon, Il
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.739-746
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    • 2008
  • The aim of this study is finding the optimal design parameters and the optimal operation variables of a reactive distillation column. Different from steady state optimization, dynamic optimization makes it possible considering operation ability as well as design problems at process design step. For performing dynamic optimization, dynamic simulation should be done first. If dynamic simulation is already finished, dynamic optimization can be performed with less effort than that of dynamic simulation.Reactive distillation systems involving reaction and separation in a single unit have the potential to reduce capital and operating costs, particularly when reaction have conversion constraint or when azeotropes exist making conventional separation difficult and expensive. This study here present work on the continuous distillation process, the homogeneous catalyzed esterification of methanol and acetic acid, the synthesis of methyl acetate. Based on an equilibrium stage model of a reactive distillation column a dynamic optimization problem was formulated and solved. And the results were verified by performing dynamic simulation and showing the variation of conversion and purity as the variation of the operation variables. As the results of dynamic optimization, this study found optimal feed ratio, reflux ratio and reboiler duty of this system. And as this study applied it to dynamic simulations the dynamic characteristics of a reactive distillation column are showed under optimal operating condition.

Adaptation of Neural Network based Intelligent Characters to Change of Game Environments (신경망 지능 캐릭터의 게임 환경 변화에 대한 적응 방법)

  • Cho Byeong-heon;Jung Sung-hoon;Sung Yeong-rak;Oh Ha-ryoung
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.42 no.3 s.303
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    • pp.17-28
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    • 2005
  • Recently intelligent characters in computer games have been an important element more and more because they continually stimulate gamers' interests. As a typical method for implementing such intelligent characters, neural networks have been used for training action patterns of opponent's characters and game rules. However, some of the game rules can be abruptly changed and action properties of garners in on-line game environments are quite different according to gamers. In this paper, we address how a neural network adapts to those environmental changes. Our adaptation solution includes two components: an individual adaptation mechanism and a group adaptation mechanism. With the individual adaptation algorithm, an intelligent character steadily checks its game score, assesses the environmental change with taking into consideration of the lastly earned scores, and initiates a new learning process when a change is detected. In multi-user games, including massively multiple on-line games, intelligent characters confront diverse opponents that have various action patterns and strategies depending on the gamers controlling the opponents. The group adaptation algorithm controls the birth of intelligent characters to conserve an equilibrium state of a game world by using a genetic algorithm. To show the performance of the proposed schemes, we implement a simple fighting action game and experiment on it with changing game rules and opponent characters' action patterns. The experimental results show that the proposed algorithms are able to make intelligent characters adapt themselves to the change.

Design Approach for Boundary Element of Flexure-Governed RC Slender Shear Walls Based on Displacement Ductility Ratio (휨 항복형 철근콘크리트 전단벽의 경계요소설계를 위한 변위연성비 모델제시)

  • Mun, Ju-Hyun;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.26 no.6
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    • pp.687-694
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    • 2014
  • This study established a displacement ductility ratio model for ductile design for the boundary element of shear walls. To determine the curvature distribution along the member length and displacement at the free end of the member, the distributions of strains and internal forces along the shear wall section depth were idealized based on the Bernoulli's principle, strain compatibility condition, and equilibrium condition of forces. The confinement effect at the boundary element, provided by transverse reinforcement, was calculated using the stress-strain relationship of confined concrete proposed by Razvi and Saatcioglu. The curvatures corresponding to the initial yielding moment and 80% of the ultimate state after the peak strength were then conversed into displacement values based on the concept of equivalent hinge length. The derived displacement ductility ratio model was simplified by the regression approach using the comprehensive analytical data obtained from the parametric study. The proposed model is in good agreement with test results, indicating that the mean and standard deviation of the ratios between predictions and experiments are 1.05 and 0.19, respectively. Overall, the proposed model is expected to be available for determining the transverse reinforcement ratio at the boundary element for a targeted displacement ductility ratio.

Application of Rare Earth Compounds for the Treatment of Phosphate and Fluoride in Wastewater (인산염 및 불소폐수 처리제로서의 희토류 화합물 적용에 관한 연구)

  • Kim, Jin-Wha;Shin, Sung-Hye;Song, Hye-Won;Kim, Dong-Su;Woo, Sang-Mo;Kwon, Young-Shik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1127-1137
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    • 2000
  • Applications of lanthanum ion and crude rare earth chloride to the phosphate wastewater and fluorine wastewater, respectively, as treatment agents were studied. For the investigation of phosphate removal characteristics according to the amount of lanthanum ion, initial phosphate content was decreased by about 50% when molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] was 0.25 and nearly all of phosphate was removed when the molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] to be doubled. The removal of phosphate by $La^{3+}$ appeared to reach equilibrium state rapidly, and it was exothermic reaction since the removed amount of phosphate was diminished somewhat when the reaction temperature was increased. The zeta potential of combined particulate compound of lanthanum ion and phosphate was located for its isoelectric point at pH 5.5 and the turbidity of treated wastewater was found to vary according to the pH in a similar manner as the absolute value of zeta potential of the combined particulate compound did. For the treatment of fluorine wastewater by crude rare earth chloride, the remaining fluorine content after treatment decreased as the dosage of crude rare earth chloride increased. Whereas, the turbidity of treated wastewater and the amount of sludge generated were shown to increase as more crude rare earth chloride was added. The remaining fluorine content and the turbidity of treated wastewater were decreased and the amount of sludge generated was observed to increase according the increase of coagulant dosage under the condition of constant input of crude rare earth chloride.

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Characteristics of Submarine's Turbulent Wake using Analytical Solution of B(ξ) for the given λ (임의 λ에 대한 근사해 B(ξ)를 이용한 잠수함 난류항적 특성 연구)

  • Lee, Yong-Chol
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.8
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    • pp.1604-1610
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    • 2017
  • Using analytical solution of $B({\xi})$, I could find out the characteristics of Submarine's turbulent wake for the given various ${\lambda}$, which were unknown facts before. As the results, $B({\xi}){\approx}{\frac{B({\xi})_{max}}{2}}$ and ${{\int}_{0}^{{\approx}0.6}}B({\xi})d{\xi}{\approx}0.85{{\int}_{0}^{1}}B({\xi})d{\xi}$ in the vicinity ${\xi}{\approx}0.6$, there was some dependencies on the given ${\lambda}$ though. The values of ${\lambda}$, in the range of $4{\leq}{\lambda}{\leq}8$, are more suitable to describe submarine's turbulent wake realistically, due to the bases on the quasi equilibrium state of turbulent wake. ${\lambda}$ mainly affects on the radius and detection range of the submarine's turbulent wake on the surface, however, the speed of submarine mainly affect on the duration of the wake rather than shape. If $7{\leq}{\lambda}{\leq}8$, it can be expected that the turbulent wake can be seen on the surface in the West sea, however, snorkeling(or snorkeled) submarine's wake can be found easily in the East sea.

Study on Retardation Effect of a Heavy Metal in Sandy Soils

  • Kim, Dong-Ju;Sung, Baek-Doo
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.06a
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    • pp.43-49
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    • 1998
  • Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomena. The adsorption of metal ions has been recognized more strong in clay mineral and organic matter contents rather than sands and gravels. In this study, we investigated the retardation effect in two sandy soils by conducting batch and column tests. The column tests were conducted to obtain the relationship between concentration and time known as breakthrough curve (BTC). We applied pulse type injection of ZnCl$_2$solution on the inlet boundary and monitored the effluent concentration at the exit boundary under steady state condition using EC-meter and ICP-AES. Batch test consisted of an equilibrium procedure for fine fractions collected from two sandy soils for various initial ZnCl$_2$concentrations, and analysis of Zn ions in equilibrated solution using ICP-AES. The results of column test showed that i) the peak concentration of Zn analyzed by ICP was far less than that detected by EC-meter for both soils and ii) travel times for peak concentration were more less identical for two different monitoring techniques. The first result can be explained by ion exchange between Zn and other cations initially present in the soil particles since ICP analysis showed a significant amount of Ca, Mg ions in the effluent. From the second result, we found that retardation effect was not present in these soils due to strong cation exchange capacity of Zn ion over other cations since we did not apply a solution containing more adsorptive cations such as Al. The result of batch test also showed high distribution coefficients (K$_{d}$) for two soils supporting the dominant ion exchange phenomena. Based on the retardation factor obtained from the Kd, we predicted the BTC using CDE model and compared with the BTC of Zn concentration obtained from ICP The predicted BTC, however, disagreed with the monitored in terms of travel time and magnitude of the peak concentrations. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in liquid phase.e.

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Miscibility of Melt-mixed PLLA/PMMA Blends for Optical Film Application (광학 필름 적용을 위한 용융혼합된 PLLA/PMMA 블렌드의 상용성 연구)

  • Park, Eun Ju;Kim, In Seok;Park, Sang Seok;Lee, Ho Sang;Lee, Moo Sung
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.744-752
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    • 2013
  • The miscibility between poly(L-lactide) (PLLA) and poly(methyl methacrylate) (PMMA) was investigated using thermal analyses for the purpose of developing birefringence-free material at oriented state. The effect of methyl acrylate (MA) units as comonomer of PMMA on the miscibility was also studied. All the blends prepared in this study show composition-dependent single $T_g$'s between those of blend components and high transparency over the visible region, indicating the miscibility at molecular level and no discernible effect of MA units on it. No phase separation was observed at elevated temperature of $280^{\circ}C$, higher than the degradation of PLLA and PMMA. The interaction energy density in PLLA/PMMA blends with 17 mol% of MA was measured to be $-0.74J/cm^3$ from the equilibrium melting temperature depression based on the Hoffman-Weeks method. The blends show zero-${\Delta}$n behavior at a specific mixing ratio and the drawing ratio of 3 due to compensation of intrinsic orientation birefringence. Birefringence dispersion of PLLA/PMMA5 blends was also measured to examine the possibility for quarter-wave plates or polarizer protective films.

Development of Selectable Vector Plasmid in Bacteriophage P2-P4 System and Its Stability (박테리오파지 P2-P4 시스템을 위한 벡터 플라스미드 개발과 안정성)

  • Kim, Kyoung-Jin
    • Korean Journal of Microbiology
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    • v.34 no.4
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    • pp.236-242
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    • 1998
  • While bacteriophage P2-P4 system is very useful experimental tool for the study of viral capsid assembly, there is no useful plasmid vector for the DNA manipulation in bacteriophage P2-P4 system. In this study, a new vector plasmid, P4 ash8 (sid71) kmr, was constructed by swapping the non-essential region of P4 DNA for kanamycin resistance(kmr) gene cassette of plasmid pUC4-K. P4 ash8 sid71 was starting material for the construction, since it tends to be maintained as a plasmid in the absence of the helper phage. The total size of this chimera was designed to be packaged into P4 or P2 size heads with induction by P2 infection. The conversion of plasmid P4 ash8 (sid71) kmr to bacteriophage was proved by burst size determination experiment and CsCl buoyant equilibrium density gradient experiment. Integrase destructed P4 derivative, P4 ash8 sid71 kmr intS, was able to be constructed easily by in vitro DNA manipulation of P4 ash8 sid71 kmr. The plasmid stability experiment with P4 ash8 sid71 kmr if/tS showed that the integrase of P4 affects the stable maintenance of plasmid P4 state.

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