• 제목/요약/키워드: Equilibrium Model

검색결과 2,121건 처리시간 0.028초

저공해 compact 유해폐기물 dump 소각기 개발 (The Development of Hazardous Waste Compact Dump incinerator for Low Emissions)

  • 전영남;채종성;정오진
    • 한국대기환경학회지
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    • 제16권6호
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    • pp.653-663
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    • 2000
  • A lot of hazardous wastes are discharged as by-products of working process by industrial development. Hazardous wastes is physical characteristics of difficult destruction at hight temperature. Numerical simulation and combustion experiment performed of dump incinerator for hazardous waste incineration. For the numerical simulation, the SIMPLEST algorithm was used to ensure rapid converge A K-$\varepsilon$ model was incorporate for the enclosure of turbulence flow. Combustion model was used by ESCRS (extended simple chemically reacting system) model available of CHEMKIN thermodynamic data for the source term of species conservation equation or energy equation. Radiation model is used by six flux model. A parametric screening studies was carried out through numerical simulation and experiment. Residence time and concentration in the incinerator was strongly dependent on the parameters of mixture velocity, mixture equilibrium ratio, surrogate velocity and surrogate equilibrium ratio.

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실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측 (Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction)

  • 강성필
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.477-480
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    • 2007
  • Hydrate phase equilibrium for the binary CO2+water and CH4+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal urn pore size were nealy identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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전력시장 해석을 위한 3연 참여 게임의 해법 연구 (A Solution Method of a Three-Player Game for Application to an Electric Power Market)

  • 이광호
    • 대한전기학회논문지:전력기술부문A
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    • 제52권6호
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    • pp.347-353
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    • 2003
  • In models of imperfect competition of deregulated electricity markets, the key task is to find the Nash equilibrium(NE). The approaches for finding the NE have had two major bottlenecks: computation of mixed strategy equilibrium and treatment of multi-player games. This paper proposes a payoff matrix approach that resolves these bottlenecks. The proposed method can efficiently find a mixed strategy equilibrium in a multi-player game. The formulation of the m condition for a three-player game is introduced and a basic computation scheme of solving nonlinear equalities and checking inequalities is proposed. In order to relieve the inevitable burden of searching the subspace of payoffs, several techniques are adopted in this paper. Two example application problems arising from electricity markets and involving a Cournot and a Bertrand model, respectively, are investigated for verifying the proposed method.

다공성 물질 안에서의 자연대류 현상에 대한 열역학적 국소평형상태 가정의 고찰 (An Investigation on Local Thermodynamic Equilibrium Assumption of Natural Convection in a Porous Medium)

  • 김인선;남진현;김찬중
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 추계학술대회논문집B
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    • pp.112-117
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    • 2000
  • A numerical study on natural convection in a vertical square cavity filled with a porous medium is carried out with Brinkman-Forchheimer-extended Darcy flow model, and the validity of local thermodynamic equilibrium assumption is studied. The local thermodynamic equilibrium refers to the state in which a single temperature can be used to describe a heat transfer process in a multiphase system. With this assumption, the analysis is greatly simplified because only one equation is needed to describe the heat transfer process. But prior to using this assumption, it is necessary to know in what conditions the assumption can be used. The numerical results of this study reveal that large temperature difference between fluid phase and solid phase exists near wall region, paticularily when the convection becomes dominant over conduction. And the influence of flow parameters such as fluid Rayleigh number, fluid Prandtl number, dimensionless particle diameter and conductivity ratio are investigated.

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실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측 (Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction)

  • 강성필
    • 신재생에너지
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    • 제3권2호
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    • pp.47-52
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    • 2007
  • Hydrate phase equilibrium for the binary $CO_{2}$+water and $CH_{4}$+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal nm pore size were nearly identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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pH 의존성 Methacrylic acid 공중합체의 팽윤특성 (pH-dependent Swelling Properties of Methacrylic Acid Copolymer Hydrogels)

  • 김경충;이승진
    • 약학회지
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    • 제33권6호
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    • pp.372-376
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    • 1989
  • Equilibrium swelling and pH-sensitivity of a polyelectrolyte copolymer hydrogel were controlled by employing copolymers with different hydrophilic-hydrophobic balances. Model pH-sensitive hydrogels, e.g., poly(methacrylic acid), poly(methacrylic acid-co-acrylamide), poly(methacrylic acid-co-2-hydroxyethylmethacrylate), poly(methacrylic acid-co-styrene) were synthesized at various monomer compositions. As hydrophobicity of the copolymer hydrogels increased, the equilibrium swelling decreased while the pH-sensitivity increased. In the case of poly(methacrylic acid-co-acrylamide), polymer-polymer interaction significantly affected the equilibrium swelling and provided a wide range control of pH-sensitivity.

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충격 압축에 의한 제논 가스의 이온화 특성 연구 (A Study of the Ionization Characteristics of Xenon Gas by Shock Compression)

  • 이대성;신재렬;최정열;최윤수;김형원
    • 한국군사과학기술학회지
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    • 제13권3호
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    • pp.493-502
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    • 2010
  • In this paper, the ionization characteristics of noble gases are studied numerically behind strong shock waves. As a first step, the equilibrium ionization mechanism of noble gases is modeled in wide ranges of temperature and pressure. As a next step the equilibrium ionization model is coupled with fluid dynamic equations to analyze the local thermodynamic equilibrium(LTE) ionization process at high temperature and pressure conditions behind the strong imploding shock waves. The ionization characteristics of xenon gas is studied in a wide range of test conditions with thermal radiation effects. Hence, the results give optimal conditions of maximum ionization and radiation behind the imploding shock waves.

수입 수산물과 국내산 수산물의 가격간 유통단계별 인과성 분석 : 명태, 갈치, 조기 냉동품을 대상으로 (A Causality Analysis of the Prices between Imported Fisheries and Domestic Fisheries in Distribution Channel)

  • 차영기;김기수
    • 수산경영론집
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    • 제40권2호
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    • pp.105-126
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    • 2009
  • This study applies the cointegration theory to analyse the causality of the prices between imported fisheries and domestic fisheries in distribution channel. We've focused on the prices of import, wholesale and retail about the frozen Alaska pollack, hairtail and croaker which take up high portion and are popular among most of the consumers. In process of analysis, the unit root test was adopted to find the stability of time series data prior to the cointegration test. If the time series data was found as stable one in unit root test, we should analyse the VAR model. If unstable, the cointegratioin test was adopeted to find the long-run equilibrium relationship between the data. When the long-run equilibrium relationship was found among the price of the import, wholesale and retail price, the VECM model was adoped. If not, the differenced VAR model was adopted. The main findings of this study could be summarized as follows ; First, according to the result of the analysis on VAR model, time series data of frozen Alaska pollack was found as stable and has causality relationship and close effect was existing among the import, wholesale and retail price. Second, the data of frozen hairtail was found as an unstable one in unit root test and the result of cointegration test showed the long-run equilibrium relationship at lag 1. From the results of VECM model, we could find that the coefficient of error correction is effective, and the sign is negative(-). It means that the existence of adjustment tendency to long-run equilibrium after a short-run deviation. But the short-run causality of the prices were not found except the price of wholesale. Third, according to the results of differenced VAR model, data from frozen croaker did not have the stability and long-run equilibrium. Moreover, it was found that the import price has a weak causality on the retail price. Because of having difficulties in collecting data, the result of this paper could not explain the relationship among the prices of import, wholesale and retail perfectly. However, it more or less contributed to a long-lasted debate on the direction of causality of price-setting in academic research and provided a useful guide for the policy makers in charge of the price-setting of fisheries products as well.

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빠른 입계 확산 수치 모델의 우주화학에의 적용 (Applications of the Fast Grain Boundary Model to Cosmochemistry)

  • 박창근
    • 광물과 암석
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    • 제36권3호
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    • pp.199-212
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    • 2023
  • 확산은 지구물질은 물론 운석과 같은 우주물질의 원소 및 동위원소 연구에서 매우 유용하게 활용될 수 있다. 고온의 태양계 성운에서 일어난 확산과 상대적으로 저온의 소행성에서 일어난 열수 변질 과정에서의 확산 양상은 다르기 때문에 광물에 기록된 원소 및 동위원소 확산에 대한 모델 수립은 초기 태양계 진화를 이해하는데 있어 특히 중요하다. 광물 입자 경계를 따라 일어나는 빠른 입계 확산은 닫힌계에서 구성 광물간 원소 또는 동위원소의 교환을 수치 모델화하는데 유용하며, 본 연구에서는 유한차분법을 이용하였다. 수립된 빠른 입계 확산 수치 모델은 1) CH 콘드라이트의 아메바 형태 감람석 집합체(amoeboid olivine aggregate; AOA)내 사장석의 마그네슘-26(26Mg) 동위원소 조성 변화와 2) CO 콘드라이트의 콘드률, AOA, 기질 구성 광물간 Fe-Mg 상호 확산에 적용되었다. 빠른 입계 확산을 통해 광물 결정의 표면에서는 평형상태에 도달할 수 있다는 가정에 기반해서 평형상태 동위원소 질량 분배(equilibrium isotopic fractionation)와 평형상태 원소 분배(equilibrium partitioning)도 수치 모델에 포함하였다. 모델을 통해 닫힌계를 구성하는 구성 광물간 원소 또는 동위원소의 교환과 확산으로 실제 운석에서 관찰된 원소 및 동위원소 조성 분포를 설명할 수 있음을 보였다. 또한 암석을 구성하는 광물이 여러 종류일 경우에 폐쇄 온도는 확산이 가장 느린 광물종에 의해서만 결정되는 것이 아니라 전체 광물들의 함량비에도 크게 영향을 받는다는 것을 확인할 수 있었다.

A Variability Analysis on the Flatfish Production and Revenue using Expectation Hypotheses and GARCH Model

  • Yoon, Hyung-Mo;Yoon, Ji-Young
    • 수산경영론집
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    • 제48권2호
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    • pp.1-17
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    • 2017
  • This work studies the variability of flatfish sales revenue. The theoretical analysis draws functions for equilibrium price and quantity using expectation hypotheses. The functions include unpredictable phenomenon with dummy variable and GARCH. The equilibrium function, using adaptive expectation hypothesis, contains the independent variables of supply and demand, while the equilibrium function, embodying rational expectation hypothesis, includes only the independent variables of supply side, because the demand side disappears by the information extraction process theoretically, if economic subjects build the expectation rational. The empirical analysis shows: the variability of flatfish production has a spillover effect on the variability of revenue with the adaptive expectation hypothesis. In the case when the model has a rational expectation hypothesis, the variability of flatfish production has a spillover effect on the revenue (the mean equation of GARCH model). This study indicates that there is the variability in flatfish production and sales revenue, and the spillover effect between them. The result can help to build of the rational system for the fishery income stability.