• Journal of Ocean Engineering and Technology
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• v.27 no.5
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• pp.99-104
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• 2013

Recently, various nanoparticles have been used for filler in polymer matrices. The particles of nano size are whether high or not cross-link density in polymer affects the thermal and mechanical properties of one. The properties change as a result of chemical reactions between the nanoparticles and the surface of the polymer. There are two models for nanocomposites: "repulsive interaction" and "attractive interaction" between the nanoparticles and matrix. In this study, the variation in the curing mechanism was examined when nano-size $TiO_2$ was dispersed into an epoxy (Bisphenol A, YD-128) with different curing agents. The results of this study showed that the exothermic temperature and Tg in the case of the nanoparticles used (Jeffamine) (D-180) at room temperature were reduced by an increase in the $TiO_2$ contents because of the "repulsive interaction" between the nanoparticles and the matrix. The tensile strengths were increased by increasing amounts of $TiO_2$ until 3 wt% because of a dispersion strengthening effect caused by the nanoparticles, because of the repulsive interaction. However, such tensile properties decreased at 5 wt% of $TiO_2$, because the $TiO_2$ was agglomerated in the epoxy. In contrast, in the case of the nanoparticles that used NMA and BDMA, the exothermic temperature and Tg tended to rise with increasing amounts of $TiO_2$ as a result of the "attractive interaction." This was because the same amounts of $TiO_2$ were well dispersed in the epoxy. The tensile strength decreased with an increase in the $TiO_2$ contents. In the general attractive interaction model, however, the cross-link density was higher, and tensile strength tended to increase. Therefore, for the nanoparticles that used NMA, it was difficult to conclude that the result was caused by the "attractive model."

• Steel and Composite Structures
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• v.35 no.5
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• pp.627-634
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• 2020

The past years were marked by an increase in the use of wood waste in civil and mechanical constructions. Date palm waste remains also one of the most solicited renewable and recyclable natural resources in the composition of composite materials. In Algeria, a great amount of this type of plant wastes accumulates every year. In order to make use of this waste, a new wood-epoxy composite material based on date palm petiole particleboard is developed. It makes use of date palm petiole particleboard as reinforcement and epoxy resin as matrix. The size of the particles reinforcement are between 1~3 mm and proportion of reinforcement used is 37%. In this work, experimental and numerical studies are conducted in order to characterize the wood fibre-epoxy plates. Firstly, experimental modal analysis test was carried out to determine Young's modulus of the elaborated material. Then, in order to validate the results, compression test was conducted. Furthermore, additional information about the shear modulus of this material is obtained by performing an experimental modal analysis to extract the first torsional mode. Moreover, a finite element model is developed using ANSYS software to simulate the vibration behaviour of the plates. The results show a good agreement with the experimental modal analysis, which confirms the values of Young's modulus and shear modulus.

• Composites Research
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• v.24 no.4
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• pp.11-16
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• 2011

Retention of interfacial shear strength (IFSS) of polymer composites at cryogenic temperature application is very important. In this work, single carbon tiber reinforced epoxy compositc was used to evaluate IFSS and apparent modulus under room and cryogenic temperatures. The property change of carbon and selected epoxy for particularly cryogenic temperature application were tested in tension and compression. Tensile strength and elongation of carbon fiber decreased at cryogenic temperature, whereas tensile modulus was almost same. On the other hand, epoxy matrix showed the increased tensile strength but decreased elongation. It can be due to maximum thermal contraction existing free volume in cryogenic temperature. IFSS increased up to $-10^{\circ}C$ and then decreased steadily. However, IFSS at cryogenic temperature was still similar to that at room temperature. This result is very useful to cryogenic application since selected epoxy toughness and interfacial adhesion can keep at such low temperature.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.2
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• pp.426-434
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• 2010

This study is experimentally performed to evaluate the strength reduction behavior and its statistical properties of plain woven glass/epoxy composites. The results indicate that the major impact damage of plain woven glass/epoxy composites is the fiber breakage and matrix crack, whereas the dominant impact damage of unidirectional carbon/epoxy laminates is the delamination, which depends on the stacking sequence. The residual strength prediction models, previously proposed on unidirectional laminates, are applied to evaluate the residual strength of plain woven glass/epoxy composites with impact damage. Among these models, the results by Caprino and Avva's model have a good agreement with the experimental results. To investigate the variability of residual strength of the impacted composite materials, a statistical model was proposed and its results were in conformance with the experimental results regardless of their thickness.

• Composites Research
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• v.29 no.4
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• pp.223-229
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• 2016

SiC nanoparticles were used to increase flexural properties of polymer matrix. This study was to manufacture huge concentration SiC nanoparticle/epoxy composites and to evaluate the dispersion. During mixing SiC nanoparticle and epoxy, 20 wt% SiC nanoparticle in total composites was used with both stirrer and sonication equipment together. Mixing speed and dispersion were improved with the method by using both stirrer and sonication equipment at the same time via mechanical test and FE-SEM. Based on the results, modeling of SiC nanoparticle dispersion could be established. Ultimately, unidirectional carbon fiber reinforced composites was manufactured using 20 wt% SiC nanoparticle/epoxy. Mechanical property of CFRP using dual stirrer and sonication mixing method was better than composites by single sonication mixing method.

• Journal of the Microelectronics and Packaging Society
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• v.8 no.4
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• pp.59-65
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• 2001

Epoxy/$BaTiO_3$composite capacitor films with excellent stability at room temperature, uniform thickness, and electrical properties over a large area ware successfully fabricated. The composite capacitor films with good film formation capability and easy process ability were made from epoxy resin developed for ACF as a matrix and two kinds of $BaTiO_3$powders as fillers to increase the dielectric constant of the composite film. The crystal structure of the powders and its effects on dielectric constant of the films were investigated by X-ray diffraction (XRD). And the optimum amount of dispersant, phosphate ester, was determined by viscosity measurement of suspension. DSC and dielectric property tests were conducted to decide the right curing temperature and the optimum amount of the curing agent. As a result, the capacitors of 7 $\mu \textrm{m}$ thick film with 10 nF/$\textrm{cm}^2$ and low leakage current were successfully demonstrated.

• Composites Research
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• v.23 no.3
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• pp.58-63
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• 2010

Tensile and flexural properties and electrical conductivity of MWCNT/epoxy composites with different aspect ratios of MWCNTs were compared. The MWCNT/epoxy mixtures were prepared by mechanical dispersion methods using a homomixer and a three-roll mill, and then composite samples were fabricated by compression molding process. The fractured surfaces of the samples were observed by SEM in order to evaluate the degree of dispersion of MWCNTs. The addition of MWCNTs into epoxy resin improved its tensile strength by 7.0% while its flexural strength increased slightly as compared with the one without MWCNTs. In the case of MWCNTs having highest aspect ratio, the mechanical properties of the composites were decreased. When the contents of CM-95 MWCNTs were varied, maximum of tensile and flexural strengths occurred at 1wt% and 0.5wt%, respectively. From the higher contents than these, tensile and flexural strengths of the composites decreased. Electrical conductivities of in-plane and thought-the-thickness directions of MWCNT/epoxy composites were measured using a two-point probe method. They increased with the increase of the aspect ratios and concentrations of MWCNTs in the epoxy matrix.

• Journal of Powder Materials
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• v.22 no.4
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• pp.234-239
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• 2015

Electronic products are a major part of evolving industry and human life style; however most of them are known to emit electromagnetic waves that have severe health hazards. Therefore, different materials and fabrication techniques are understudy to control or limit transfer of such waves to human body. In this study, nanocomposite powder is dispersed into epoxy resin and shielding effects such as absorption, reflection, penetration and multiple reflections are investigated. In addition, nano size powder (Ni, $Fe_2O_3$, Fe-85Ni, C-Ni) is fabricated by pulsed wire evaporation method and dispersed manually into epoxy. Characterization techniques such as X-ray diffraction, Scanning electron microscopy and Transmission electron microscopy are used to investigate the phase analysis, size and shape as well as dispersion trend of a nano powder on epoxy matrix. Shielding effect is measured by standard test method to investigate the electromagnetic shielding effectiveness of planar materials, ASTM D4935. At lower frequency, sample consisting nano-powder of Fe-85%Wt Ni shows better electromagnetic shielding effect compared to only epoxy, only Ni, $Fe_2O_3$ and C-Ni samples.

• Journal of Adhesion and Interface
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• v.14 no.2
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• pp.75-81
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• 2013

Epoxy matrix based composites were fabricated by adding SiC nano fillers. The interfacial properties of composites were varied with different shapes of SiC nano fillers. To investigate the shape effects on the interfacial properties, beta and whisker type SiC nano fillers were used for this evaluation. The dispersion states of nano SiC-epoxy nanocomposites were evaluated by capacitance measurements. FE-SEM was used to observe the fracture surface of different structures of SiC-epoxy nanocomposites and to investigate for reinforcement effect. Interfacial properties between carbon fiber and SiC-epoxy nanocomposites were also evaluated by ILSS (interlaminar shear strength) and IFSS (interfacial shear strength) tests. The interfacial adhesion of beta type nanocomposites was better than whisker type.

• Elastomers and Composites
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• v.56 no.3
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• pp.179-186
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• 2021

Carbon-based nanofillers, including nanodiamond (ND) and carbon nanotubes (CNTs), have been employed in epoxy matrixes for improving the toughness, using the tow prepreg method, of epoxy compounds for high pressure tanks. The reinforcing performance was compared with those of commercially available toughening fillers, including carboxyl-terminated butadiene acrylonitrile (CTBN) and block copolymers, such as poly(methyl methacrylate)-b-poly(butyl acrylate)-b-poly(methyl methacrylate) (BA-b-MMA). CTNB improved the mechanical performance at a relatively high filler loading of ~5 phr. Nanosized BA-b-MMA showed improved performance at a lower filler loading of ~2 phr. However, the mechanical properties deteriorated at a higher loading of ~5 phr because of the formation of larger aggregates. ND showed no significant improvement in mechanical properties because of aggregate formation. In contrast, surface-treated ND with epoxidized hydroxyl-terminated polybutadiene considerably improved the mechanical properties, notably the impact strength, because of more uniform dispersion of particles in the epoxy matrix. CNTs noticeably improved the flexural strength and impact strength at a filler loading of 0.5 phr. However, the improvements were lost with further addition of fillers because of CNT aggregation.