• Title/Summary/Keyword: Environmentally friendly Materials

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Development of Eco-Friendly Ag Embedded Peroxo Titanium Complex Solution Based Thin Film and Electrical Behaviors of Res is tive Random Access Memory

  • Won Jin Kim;Jinho Lee;Ryun Na Kim;Donghee Lee;Woo-Byoung Kim
    • Korean Journal of Materials Research
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    • v.34 no.3
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    • pp.152-162
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    • 2024
  • In this study, we introduce a novel TiN/Ag embedded TiO2/FTO resistive random-access memory (RRAM) device. This distinctive device was fabricated using an environmentally sustainable, solution-based thin film manufacturing process. Utilizing the peroxo titanium complex (PTC) method, we successfully incorporated Ag precursors into the device architecture, markedly enhancing its performance. This innovative approach effectively mitigates the random filament formation typically observed in RRAM devices, and leverages the seed effect to guide filament growth. As a result, the device demonstrates switching behavior at substantially reduced voltage and current levels, heralding a new era of low-power RRAM operation. The changes occurring within the insulator depending on Ag contents were confirmed by X-ray photoelectron spectroscopy (XPS) analysis. Additionally, we confirmed the correlation between Ag and oxygen vacancies (Vo). The current-voltage (I-V) curves obtained suggest that as the Ag content increases there is a change in the operating mechanism, from the space charge limited conduction (SCLC) model to ionic conduction mechanism. We propose a new filament model based on changes in filament configuration and the change in conduction mechanisms. Further, we propose a novel filament model that encapsulates this shift in conduction behavior. This model illustrates how introducing Ag alters the filament configuration within the device, leading to a more efficient and controlled resistive switching process.

Effect of the Concentration of Citrate on the Growth of Aqueous Chemical Bath Deposited ZnO and Application of the Film to Cu(In,Ga)Se2 Solar Cells (Citrate 농도에 따른 수용액 화학조 증착 ZnO 성장 및 ZnO 박막의 Cu(In,Ga)Se2 태양전지 응용)

  • Cho, Kyung Soo;Jang, Hyunjun;Oh, Jae-Young;Kim, Jae Woo;Lee, Jun Su;Choi, Yesol;Hong, Ki-Ha;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.30 no.4
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    • pp.204-210
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    • 2020
  • ZnO thin films are of considerable interest because they can be customized by various coating technologies to have high electrical conductivity and high visible light transmittance. Therefore, ZnO thin films can be applied to various optoelectronic device applications such as transparent conducting thin films, solar cells and displays. In this study, ZnO rod and thin films are fabricated using aqueous chemical bath deposition (CBD), which is a low-cost method at low temperatures, and environmentally friendly. To investigate the structural, electrical and optical properties of ZnO for the presence of citrate ion, which can significantly affect crystal form of ZnO, various amounts of the citrate ion are added to the aqueous CBD ZnO reaction bath. As a result, ZnO crystals show a nanorod form without citrate, but a continuous thin film when citrate is above a certain concentration. In addition, as the citrate concentration increases, the electrical conductivity of the ZnO thin films increases, and is almost unchanged above a certain citrate concentration. Cu(In,Ga)Se2 (CIGS) solar cell substrates are used to evaluate whether aqueous CBD ZnO thin films can be applicable to real devices. The performance of aqueous CBD ZnO thin films shows performance similar to that of a sputter-deposited ZnO:Al thin film as top transparent electrodes of CIGS solar cells.

Present and Future of Thermoplastic Elastomers As Environmentally Friendly Organic Materials (친환경 유기 소재로서 열가소성 탄성체의 오늘과 내일)

  • Choi, Eun-Ji;Yoon, Ji-Hwan;Jo, Jung-Kyu;Shim, Sang-Eun;Yun, Ju-Ho;Kim, Il
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.170-187
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    • 2010
  • Much interest on the thermoplastic elastomers (TPEs) has recently been attracted in commercial fields as well as scientific and applied researches. The TPEs have their own characteristic area especially in relation with block copolymers as well as many other polymeric materials, since they show interesting features displayed by the conventional vulcanized rubber, and at the same time, by the thermoplastics. In addition, they are characterized by a set of interesting properties inherent to block and graft copolymers, variety of blends and vulcanized materials. The importance of TPE as organic materials can be evaluated by the number of published reports (papers, patents, technical reports, etc). The input of the concept 'thermoplastic elastomer' to SciFinderScholar yields 18,508 results between 1939 and July 10, 2010, and the number increased exponentially after the mid of 1990. For the suitable introduction of the TPE, historic, scientific, technical and commercial considerations should be taken into account. This review article starts with a brief discussion on historical considerations, followed by a introduction of the main preparations and analytical techniques utilized in chemical, structural, and morphological studies. The properties, processing tools, the position among organic materials, and applications of TPEs are also briefly reviewed. Finally, the most probable trends of their future development are discussed in a short final remarks.

Economic Analysis of Rice Transplanting Method using Pot Raised Seedling for Environment-friendly Agriculture (친환경 쌀 생산을 위한 포트육묘 이앙의 경제성 분석)

  • Shin, Yong-Kyu;Choi, In-Young;Kwon, Young-Rip;Moon, Young-Hun;Choi, Dong-Chil;Lee, Wang-Hyu
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.4
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    • pp.456-462
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    • 2012
  • In the new changing scenario, the goal of agriculture is shifting from traditional to sustainable and environment-friendly agriculture. Therefore, in this experiment, we analyzed economic efficiency of two methods of rice cultivation i.e. new cultural method and conventional method, at farmers' fields. In the new cultural method, cost of materials and machines (rice-transplanting and sowing machine) was found 245% higher than the conventional method. Depreciation of cost and working hours were also higher in the new cultural method by 1.9 and 1.1 time, respectively. However, cost of seeds and seedbed soil were 44.0% and 49.2% lower and total material cost was 4.4% lower than the conventional method. In the new cultural method, overall working cost of nursery raising and transplanting per 10a was 229.8% higher than the conventional method. However, in spite of high input cost, yield of rice in new cultural method was higher by 6.7% than the conventional method. Our results showed that new cultural method was better than the conventional method except the input cost. If government provide 80% subsidy for machine cost then its input cost will be reduced by 45.4% than the conventional method.

Utilization of Charcoal as an Environmentally Friendly Building Materials (II) - A Study on the Energy Saving and Sound Insulation Characteristics of Building Materials Prepared with Charcoal - (목탄을 이용한 친환경 건축자재 이용기술(II) - 목탄 함유 건축자재의 에너지 절감 및 차음 특성에 관한 연구)

  • Ahn, Byoung-Jun;Paik, Ki-Hyon
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.1
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    • pp.41-52
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    • 2011
  • This study was carried out to investigate the effect of energy saving and sound insulation of building materials mixed with charcoal. To investigate the functionality of building based on the difference of construction materials, three different experimental buildings were constructed. They were buildings built with the conventional construction materials (A), the charcoal construction materials (B), and the charcoal-sericite construction materials (C). The study showed that energy consumption could be reduced approximately 9.5% and 14.5% by replacing A with B and C, respectively. Especially, it is revealed that the lower outdoor temperature was, the higher energy saving effect was. Also, after shutoff the boiler switch the decrease rate of room temperature of the one using B was lower than those of others using A and C so that the room temperature at the building using B was higher by $3.5{\sim}4.2^{\circ}C$ in the 1 meter air above the ground and by $4.4{\sim}5.4^{\circ}C$ on the floor surface after 12 hours passed. In the building noise test the heavy-and light-weight impact sound of the plate, represented by criterion of noise between floors in multi-story building, tended to decrease in the test sample containing charcoal.

Study on the Sector for Enterprise Support of the Industry of Transportation, Machinery, Materials and Parts in Chungbuk through Statistical Analysis (충북 수송기계소재부품산업 통계분석을 통한 기업지원영역 연구)

  • Lee, Hyoungwook;Park, Sung-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.246-253
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    • 2018
  • The main industries in Chungcheongbuk-do are the smart IT parts; bio-health; and transportation machinery, materials and parts. The transportation, machinery, materials and parts (TMMP) industry is a key source technology for environmentally friendly and intelligent vehicles related to future vehicles in the machinery sector. Business support projects to improve this industry are currently underway. In this study, the number of enterprises, number of employees, amount of shipment, and added value of the enterprises in Chungbuk area were analyzed for the downstream and rear industries of the transportation, machinery, materials, and parts industry to set targets and directions for the technical support projects during the enterprise support. In particular, for the SMEs with less than 50 employees, the changes in the value added per enterprise were analyzed according to the period from the year of foundation. In the case of the rear industry, the value added by companies within three years after foundation has decreased gradually each year, so technical support is needed at the beginning of the startup. Companies between the ages of five and nine years are showing a fluctuating trend each year. Therefore, it is necessary to support business diversification or find new items.

Disease Control Efficacy of the Extract of Magnolia officinalis against Perilla and Zoysiagrass Rusts (후박 추출물의 들깨 녹병과 잔디 녹병에 대한 방제 효과)

  • Yoon, Mi-Young;Choi, Yong Ho;Kang, Mun Seong;Lee, Jae Hong;Han, Seong Sook;Myoung, In Sik;Han, Byoung Soo;Choi, Gyung Ja;Jang, Kyoung Soo;Kim, Jin-Cheol
    • Research in Plant Disease
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    • v.19 no.1
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    • pp.45-48
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    • 2013
  • Rusts are plant diseases caused by pathogenic fungi of the order Pucciniales. Rusts can affect a variety of plants. Development of new effective and environmentally benign agents against rusts is of great interest. In this study, we investigated the disease control efficacy of the emulsion concentrate (EC10) and wettable powder (WP20) type formulations of the extract of Magnolia officinalis (Magjia90; containing honokiol and magnolol at 90%) against rust diseases of perilla and zoysiagrass in fields. The treatment of EC10 and WP20 of Magjia90 showed control values of 47.9% to 69.6% and Magjia90-WP20 reduced more effectively the development of rust symptoms on perilla plants than Magjia90-EC10. Magjia90-WP20 also highly suppressed zoysiagrass rust with control values of 65.7% to 80.5%. On the other hand, no harmful effect of Magjia90-EC10 and Magjia90-WP20 was observed on the perilla and zoysiagrass plants tested. The results strongly indicate that the extract of M. officinalis (Magjia90) can be used as a natural fungicide for the control of rust diseases.

A Study on the Healing Architecture of Health Promotion Villages (건강마을의 건축적 치유요소 연구)

  • Lee, Min-Ah
    • Journal of Families and Better Life
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    • v.29 no.5
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    • pp.1-17
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    • 2011
  • This study aimed to analyze health promotion villages from the perspective of therapeutic architecture, and to provide basic information for planning relevant health facilities. On the basis of a review of previous literature, the characteristics of therapeutic architecture were classified into eight categories: safety, comfort, sociality, autonomy, openness, diversity, privacy, and natural environment. Field study and observation were performed in four health promotion villages that conduct programs for lifestyle improvement, physical fitness, and treatment; these villages were also considered to have a healthy residential environment. The researcher and three assistants visited the facilities and checked utilization of space through interviews with the staff and guided tours. Basic information about the subject facilities, such as the purpose of establishment, was gathered from websites before visits. Two of the villages examined in this study had a traditional Korean wooden structure, while the other two were reinforced concrete and masonry block structures. All the facilities emphasized the use of environmentally friendly material and harmony with nature. Each site was divided into the following areas: office, residence, health/treatment, public/rest, and outdoor. The safety standards of the healing architecture were not completely satisfactory at all facilities. In particular, it was found that they lacked adequate universal design equipment. However, the healing characteristics of autonomy and diversity were strong. With regard to autonomy, the facilities allowed visitors to select indoor-outdoor moving lines and the use of front- and backyards constructed on slopes. In addition, they were equipped with many entries, staircases, void, terraces, and crossroads. The architecture was aesthetically designed using feng shui symbolism, and visitors found the scenes depicted in various spaces in the villages to be stimulating. Besides, the facilities were constructed using natural materials, had a natural indoor environment, and provided a sense of spaciousness and flexibility.

Phytochemicals and antioxidant activity in the kenaf plant (Hibiscus cannabinus L.)

  • Ryu, Jaihyunk;Kwon, Soon-Jae;Ahn, Joon-Woo;Jo, Yeong Deuk;Kim, Sang Hoon;Jeong, Sang Wook;Lee, Min Kyu;Kim, Jin-Baek;Kang, Si-Yong
    • Journal of Plant Biotechnology
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    • v.44 no.2
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    • pp.191-202
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    • 2017
  • Chemical compounds from four different tissues of the kenaf plant (Hibiscus cannabinus), a valuable medicinal crop originating from Africa, were examined to determine its potential for use as a new drug material. Leaves, bark, flowers, and seeds were harvested to identify phytochemical compounds and measure antioxidant activities. Gas chromatography mass spectrometry analyses identified 22 different phytocompounds in hexane extracts of the different parts of the kenaf plant. The most abundant volatile compounds were E-phytol (32.4%), linolenic acid (47.3%), trisiloxane-1,1,1,5,5,5-hexamethyl-3,3-bis[(trimethylsilyl)oxy] (16.4%), and linoleic acid (46.4%) in leaves, bark, flowers, and seeds, respectively. Ultra-high performance liquid chromatography identified the major compounds in the different parts of the kenaf plant as kaemperitrin, caffeic acid, myricetin glycoside, and p-hydroxybenzoic acid in leaves, bark, flowers, and seeds, respectively. Water extracts of flowers, leaves, and seeds exhibited the greatest DPPH radical scavenging activity and SOD activity. Our analyses suggest that water is the optimal solvent, as it extracted the greatest quantity of functional compounds with the highest levels of antioxidant activity. These results provide valuable information for the development of environmentally friendly natural products for the pharmaceutical industry.

Geotechnical shear behavior of Xanthan Gum biopolymer treated sand from direct shear testing

  • Lee, Sojeong;Chang, Ilhan;Chung, Moon-Kyung;Kim, Yunyoung;Kee, Jong
    • Geomechanics and Engineering
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    • v.12 no.5
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    • pp.831-847
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    • 2017
  • Conventional geotechnical engineering soil binders such as ordinary cement or lime have environmental issues in terms of sustainable development. Thus, environmentally friendly materials have attracted considerable interest in modern geotechnical engineering. Microbial biopolymers are being actively developed in order to improve geotechnical engineering properties such as aggregate stability, strength, and hydraulic conductivity of various soil types. This study evaluates the geotechnical engineering shear behavior of sand treated with xanthan gum biopolymer through laboratory direct shear testing. Xanthan gum-sand mixtures with various xanthan gum content (percent to the mass of sand) and gel phases (initial, dried, and re-submerged) were considered. Xanthan gum content of 1.0% sufficiently improves the inter-particle cohesion of cohesionless sands 3.8 times and more (up to 14 times for dried state) than in the untreated (natural) condition, regardless of the xanthan gum gel condition. In general, the strength of xanthan gum-treated sand shows dependency with the rheology and phase of xanthan gum gels in inter-granular pores, which decreases in order as dried (biofilm state), initial (uniform hydrogel), and re-submerged (swollen hydrogel after drying) states. As xanthan gum hydrogels are pseudo-plastic, both inter-particle friction angle and cohesion of xanthan gum-treated sand decrease with water adsorbed swelling at large strain levels. However, for 2% xanthan gum-treated sands, the re-submerged state shows a higher strength than the initial state due to the gradual and non-uniform swelling behavior of highly concentrated biofilms.