• 제목/요약/키워드: Environmental enrichment

검색결과 479건 처리시간 0.019초

한반도 서해안 배경지역 미세입자의 화학적 특성 연구 (Study on the Chemical Characteristics of $PM_{10}$ at Background Area in Korean Peninsula)

  • 방소영;백광욱;정진도;남재철
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.455-468
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    • 2004
  • The purpose of this paper is to understand the time series and origin of a chemical component and to compare the difference during yellow sand episodes for analysis $PM_{10}$ chemical components in the region of west in Korean Peninsula, 1999-2001. An annual mean concentration of $PM_{10}$ is $29.1\;{\mu}g/m^3$. A monthly mean and standard deviation of $PM_{10}$ concentration are very high in spring but there is no remarkably seasonal variation. Also, water soluble ionic component of $PM_{10}$ be influenced by double more total anion than total cation, be included $NO_{3}^-\;and\;SO_{4}^{2-}$ for the source of acidity and $NH_{4}^+$ to neutralize. Tracer metals of $PM_{10}$ slowly increases caused by emitted for soil and ocean (Fe, Al, Ca, Mg, Na) and Zn, Pb, Cu, Mn for anthropogenic source. According to method of enrichment factor (E.F) and statistics, assuming that the origin of metal component in $PM_{10}$ most of element in the Earth's crust e.g. Mg, Ca, Fe originates soil and Cu, Zn, Cd, Pb derives from anthropogenic sources. The ionic component for $Na^{+}\;Cl^-,\;Mg^{2+}\;and\;Ca^{2+}$ and Mg, Al, Ca, Fe originated by soil component largely increase during yellow sand period and then tracer metal component as Pb, Cd, Zn decrease. According to factor analysis, the first group is ionic component ($Na^+,\;Mg^{2+},\;Ca^{2+}$) and metal component (Na, Fe, Mn and Ni) be influenced by soil. The second group, Mg, Cr also be influenced by soil particle.

3-Stage DRUM 샘플러를 이용한 광주 도심지역의 봄철과 여름철 PM2.5 원소적 조성 비교 (Elemental Composition of PM2.5 Particulate with a 3-Stage DRUM Sampler during Spring and Summer Seasons in Urban Area of Gwangju, Korea)

  • 류성윤;김영준
    • 한국대기환경학회지
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    • 제21권6호
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    • pp.699-708
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    • 2005
  • To characterize the elemental composition of fine particles in urban area, $PM_{2.5}$ was collected by a 3-stage DRUM impactor at Gwangju during spring and summer. Time and size resolved concentrations for 19 trace elements were obtained by synchrotron X-Ray fluorescence analysis. Trace elements in summer were distributed in smaller size range compared to those in spring. Almost trace element concentrations in fine particles were highly increased during the Asian dust. In spring, soil elements such as Si, K, Ca, Ti and Fe had low enrichment factors indicating the dominant influence of soil dust. However, all elements had high enrichment factors in summer implying that these elements could be emitted from the anthropogenic sources. Factor analysis was conducted with the elemental composition data in order to identify anthropogenic sources of aerosols in urban area during spring and summer. Fine particles in spring have several sources such as soil dust originating from China continental region, coal and oil combustion, biomass burning, sea salt, ferrous and nonferrous metal sources. On the other hand, fine particles in summer were influenced by road dust, gasoline vehicle as well as coal and oil combustion, sea salt, ferrous and nonferrous metal sources.

상류수계 영산강 하상퇴적물의 지화학적 특성과 오염 (Geochemical Characteristics and Contamination of Surface Sediments in Upper Yeongsan River System)

  • 오강호;김주용;고영구;윤석태;서구원;박배영;신상은;김해경
    • 한국물환경학회지
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    • 제21권5호
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    • pp.520-527
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    • 2005
  • In order to investigate the geochemical characteristics of surface sediments in streams of upper Yeongsan River drainage system, sediment samples from the main stream of Yeongsan river, Hwangryong river, Gwangju and Jiseok streams were collected and analyzed for grain size and metal and organic carbon contents. The metal contents in the sediments are mainly dependent on organic matter contents in the domestic sewage, grain size of the sediments and geology around the streams. Enrichment factor (EF) and index of geoaccumulation (Igeo) representing the degree of metal contamination in the sediments are relatively low in the main stream of Yeongsan river main stream, Hwangryong river and Jiseok stream. However, those of Gwangju stream show the EF maximum values of P=8.30, Cu=5.55, Zn=14.29 and Pb=7.45 and the Igeo maximum values of P=3.58, Cu=4.43, Zn=3.22 and Pb=1.59.

한라산 1,100 m 지역의 대기 중 PM2.5에 함유된 이온 및 원소 성분의 조성특성 (Ionic and Elemental Compositions of PM2.5 at the 1,100 m-Highland of Mt. Hallasan in Jeju Island)

  • 이기호;허철구
    • 한국환경과학회지
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    • 제25권6호
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    • pp.865-875
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    • 2016
  • In this study, mass concentrations and chemical compositions of $PM_{2.5}$, including water-soluble ions and elements were determined at the 1,100 m-highland of Mt. Hallasan in Jeju Island across four seasons from August 2013 to August 2014. The average mass concentration of $PM_{2.5}$ was $12.5{\pm}8.41{\mu}g/m^3$ with 45.8% of the contribution from eight water-soluble ionic species. Three ionic species ($SO{_4}^{2-}$, $NH{_4}^+$, and $NO{_3}^-$) comprised 96.2% of the total concentration of ions contained in $PM_{2.5}$ and were the dominant ions, accounting for 43.5% of the $PM_{2.5}$ mass at Mt. Hallasan. On the basis of the mass concentration level, seasonal variation, enrichment factor, and relationship among elements, we can presume that Mg, K, Ca, Mn, Fe, Co, Sr, Ba, Nd, and Dy originated mainly from crust or soil and that V, Cr, Ni, Cu, Zn, As, Cd, and Pb were significantly enriched in $PM_{2.5}$ owing to the effects of the anthropogenic emissions. These results and the local distribution of emission sources and topographic characteristics near this sampling site suggest that the compositions of $PM_{2.5}$ collected at the 1100 m-highland of Mt. Hallasan were largely influenced by inflow from outside of Jeju Island.

제주시 미세먼지(PM2.5)에 함유된 원소의 조성특성 및 오염원 (Elemental Composition and Source Identification of PM2.5 in Jeju City)

  • 이기호;허철구
    • 한국환경과학회지
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    • 제27권7호
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    • pp.543-554
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    • 2018
  • From November 2013 to December 2016, ambient fine particulate matter ($PM_{2.5}$) was sampled in the downtown area of Jeju City, South Korea, which has seen rapid urbanization. The atmospheric concentrations of elements were measured in the $PM_{2.5}$ samples. This study focused on Cd, Cr, Cu, Mn, Ni, Pb, As, Sb, Sn, V, and Zn. The concentrations of Al, Na, K, Fe, Ca, Mg, Sr, and La were also obtained for reference. The objectives of this study were to examine the contributions of these elements to $PM_{2.5}$ concentrations in downtown Jeju City, and to investigate the inter-element relationships and the elemental sources by using enrichment factors and principal components analysis (PCA). A composition analysis showed that the 19 elements constituted 6.65 % of the $PM_{2.5}$ mass, and Na, K, Al, Fe, Ca, Mg, and Zn constituted 98 % of the total ion mass. Seasonal trend analysis for the sampling period indicated that the concentrations of the elements increased from November to April. However, no substantial seasonal variations were found in the concentrations of the elements. The composition ratios of some elements (Cu/Zn, Cu/Cd, Cu/Pb, V/Ni, and V/La) were found to be out of range when compared to the literature from other urban areas. The ratios between the elements and the PCA results showed that local contaminant sources in Jeju City rarely influence the composition of $PM_{2.5}$. This suggests that the major sources of $PM_{2.5}$ in Jeju City may include long-range transport of fine particulate matter produced in other areas.

어패류에서 분리한 장염비브리오균의 분포 및 항균제 감수성 (Antibiotic Susceptibility and Distribution of Vibrio parahaemolyticus Isolated from the Seafood)

  • 이향;오영희;최성민;박석기
    • 한국환경보건학회지
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    • 제33권1호
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    • pp.16-20
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    • 2007
  • Vibrio parahaemolyticus was investigated for analysis of distribution and antibiotic susceptibility at the markets, Seoul in 2004. The average isolation rate was 26.8%(306/1,143) and the highest rate with 64.9% was obtained in August. The isolation rates from December to April was 0.0%. It is more effective to inoculate into the enrichment medium, alkaline pepton water by swabbing a sample with a cotton ball rather than pouring mixed sample. The isolation rates were from 24.4% to 37.1% in domestic samples and from 9.8% to 26.8% in imported ones. All of the isolates were resistent to ampicillin and ticarcillin and most of them were sensitive to chloramphenicol, tetracycline, nalidixic acid, amoxicillin, ceftriaxone, streptomycin, kanamycin, trimethoprim/sulfamethoxazol, ampicillin/sulbactam, ciprofloxacin.

장흥지역 1차수계 하상퇴적물의 지질집단별 지구화학적 특성과 하천수에 대한 연구 (Geochemical characteristics on the petrological groups of stream sediments and water in primary channels of the Jangheung area, Korea)

  • 박영석;김종균;한민수;김용준;장우석;신성천
    • 자원환경지질
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    • 제35권6호
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    • pp.509-521
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    • 2002
  • 본 연구는 지화학적 재해를 평가하는 좋은 지시자인 하상퇴적물에 대하여 지질집단별 지구화학적 특성과 하천수의 특성을 장흥지역 1차 수계를 중심으로 밝히고자 한다. 암석의 생성시기와 지질학적 환경에 따라 풍화에 영향을 받은 정도에 차이가 많은 점을 고려하여 연구지역의 지질을 화강암류지역, 화강암질편마암류(일부 변성퇴적암류포함)지역, 응회암류지역으로 나누어 주성분원소, 미량원소, 희토류원소, 독성원소 등의 분포특성에 대하여 기술하였다. 하천수에 대한 온도, pH. 전기전도도 등의 물리화학적 특성은 1999년과 2001년에 현장에서 측정하였고, 하상퇴적물 시료는 1999년 4월과 5월에 걸쳐 채취하였으며, XRF ICP-AES, NAA를 이용하여 화학분석을 실시하였다. 주성분원소의 함량은 지질집단에 관계없이 비슷한 함량비를 나타냈으며, 희토류원소는 화강암질편마암류(일부 변성퇴적암류 포함)지역에서 다른 두 지역에 비해 낮게 나타났고, 독성원소 중 Zn과 Cu가 비교적 높은 함량을 나타내었다. 부화계수와 부화지수를 도출한 결과 주성분 원소에서는 $Fe_2O_3$, MgO, $TiO_2$, MnO가, 희토류원소에서는 응회암류지역의 시료들 중 Eu. Yb가, 독성원소에서는 Co, Cr, Zn에서 약간의 부화경향을 나타냈다.

천수만 퇴적물에서 미량금속의 지화학적 특성 (Trace metals in Chun-su Bay sediments)

  • 송윤호;최만식;안윤우
    • 한국해양학회지:바다
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    • 제16권4호
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    • pp.169-179
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    • 2011
  • 본 연구에서는 미량 금속의 농축 가능성이 제기되는 천수만 퇴적물에 대하여 미량 금속의 조절 요인과 농축 정도를 파악하고자 하였다. 천수만 전역에 걸쳐 27개의 표층 퇴적물을 채취하였으며, 입도, 비표면적, 유기탄소 및 탄산칼슘 함량과 주성분 및 미량 금속(Al, Fe, Na, K, Mg, Ca, Ti, Mn, P, S, Ba, Sr, Li, Co, Cr, Ni, Cu, Zn, As, Cd, Cs, Sc, V, Sn) 농도를 분석하였다. 퇴적물의 총 금속 농도는 크게 3 가지 요인(석영, 희석, 탄산칼슘, 굵은 모래 혹은 정장석)에 의해 조절되었는데 V, Co, Cr, Ni, Cu, Zn, As, Cd는 석영 희석 효과(quartz dilution effect)에 의해 Mn 및 As는 석영 희석 효과와 정장석(굵은 모래) 함량의 복합적 요인에 의해 조절되었다. 농축 인자(enrichment factor) 및 약산(1 M HCl) 용출 실험 결과 천수만 퇴적물에서 미량 금속은 농축되지 않았음을 알 수 있었으며 금속의 농도는 퇴적물의 지화학적 특성들로 잘 설명되었다. 특징적으로 As는 조립질 퇴적물에서도 세립질 퇴적물과 유사한 농도를 보여주었는데, 이것은 조립질 퇴적물 내 Mn 산화물(용출 부분) 및 정장석(잔류 부분)과 밀접한 관련이 있는 것으로 해석되었다. 따라서 퇴적물 중 As의 농축 정도를 평가할 경우, 모래질을 포함하는 시료는 모래질 부분을 따로 분리하거나 $16{\mu}m$보다 작은 세립질 퇴적물의 함량이 10% 이상인 시료만을 대상으로 하는 것이 합리적인 것으로 판단된다.

광주광역시 토양의 지화학적 거동 특성과 오염 (Geochemical Behavior and Pollution of Soils in Gwangju City)

  • 신상은;김주용;오강호
    • 환경영향평가
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    • 제14권6호
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    • pp.415-425
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    • 2005
  • To examine the geochemical behavior and pollution of soils in Gwangju City, an analysis was carried out for pH, on the contents of metals, and organic carbon. Soil samples were taken from environs areas, industrial areas and downtown areas. The major factor controlling the behavior of metallic elements in the soil was chemical weathering of clay mineral in the environs areas, industrialization, and urbanization. Heavy metals including Cu, Pb and Zn were highly enriched for the samples from central part of downtown area. This indicated that the urbanization and the industrialization affected soil pollution. The results show that soil pollution in a metropolitan city which is caused by harmful heavy metals is severest in the center of the city. In consequence, it is inevitable that practical measures should be taken to prevent soil pollution expansion.

영산강 유역에서의 고빈도 병원성 감염 여부 (High Incidence of Campylobacter Contamination in the Yeong-San)

  • Unno, Tatsuya;Cha, Sung-Min;Kim, Jun-Ha;Hur, Hor-Gil
    • 한국방재학회:학술대회논문집
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    • 한국방재학회 2008년도 정기총회 및 학술발표대회
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    • pp.831-833
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    • 2008
  • 병원성 장내세균인 Campylobacter 를 영산강의 강물 샘플에서 발견하였으며, 이는 50ml의 물 샘플을 $0.45{\mu}m$ pore size의 filter paper에서 여과한 뒤 이를 배양한 배양액을 대상으로 수행된 PCR 반응에서 양성을 보임으로서 판명되었음. 우리는 이 연구를 통해 하천을 통한 공중보건상의 감염 잠재성을 보고자 함.

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