• 대한환경공학회지
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• 제33권9호
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• pp.686-691
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• 2011

본 연구는 MEA가 함침된 MCM-41에 대하여 이산화탄소 흡착실험과 특성 분석을 하였다. 흡착제의 XRD, FT-IR, $N_2$흡탈착 실험을 통하여 물리적 특성을 분석하였으며, 흡착실험은 15%의 이산화탄소를 사용하여 GC-TCD를 통하여 분석하였다. MEA 함침량이 10~40 wt%까지 함침량이 증가할수록 이산화탄소 흡착능은 증가하였다. 그러나 MEA 함침량이 50 wt%에서 흡착능이 감소하였다. 많은 아민이 제공되면 흡착제 표면에서 제공된 아민이 변형되는 경향이 있다. 그러므로 이산화탄소 흡착능이 감소될 수 있다. 본 연구의 결과로 이산화탄소 흡착을 위한 MCM-41에 MEA의 함침 함량의 조절이 중요하다는 것으로 사료되어진다.

• 한국환경과학회지
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• 제20권2호
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• pp.185-197
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• 2011

Sorption of chlorinated pesticides such as 2,4-dichlorophenoxyacetic acid (2,4-D) and atrazine onto natural clays (montmorillonite and zeolite) modified with cationic surfactant, hexadecyltrimethyl-ammonium (HDTMA) and a natural soil was investigated using batch adsorbers. The clays were transformed from hydrophilic to hydrophobic by the cation exchange between clay surface and HDTMA up to 100% of the cation exchange capacity (CEC). Physicochemical characteristics of the sorbents such as pH, PZC (point of zero charge), organic carbon content ($f_{oc}$), fourier transform infrared spectroscopy (FT-IR), differential thermogravimetric analysis (DTGA) and X-ray diffraction (XRD) were analyzed. Sorption isotherm models such as Freundlich and Langmuir were fitted to the experimental data, resulting Langmuir model ($R^2$ > 0.986) was fitted better than Freundlich model ($R^2$ > 0.973). Sorption capacity ($Q^0$) for 2,4-D and atrazine was in the order of HDTMA-montmorillonite > HDTMA-zeolite > natural soil corresponding to the increase in organic carbon content ($f_{oc}$). The sorption of the pesticides was also affected by pH. The sorption of 2,4-D decreased with the increase in pH, whereas that of atrazine was not changed. This indicated that the sorption capacity ($Q^0$) of 2,4-D and atrazine was not affected by the solution pH because they exist as anionic (deprotonated) forms at pH above pKa. The results indicate that organoclay has a promising potential to reduce chlorinated pesticides in the effluent from golf courses.

• 한국환경과학회지
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• 제28권6호
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• pp.561-570
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• 2019

A zeolitic material (Z-Y2) was synthesized from Coal Fly Ash (CFA) using a fusion/hydrothermal method under low-alkali condition (NaOH/CFA = 0.6). The adsorption performance of the prepared zeolite was evaluated by monitoring its removal efficiencies for Sr and Cs ions, which are well-known as significant radionuclides in liquid radioactive waste. The XRD (X-ray diffraction) patterns of the synthesized Z-Y2 indicated that a Na-A type zeolite was formed from raw coal fly ash. The SEM (scanning electron microscope) images also showed that a cubic crystal structure of size $1{\sim}3{\mu}m$ was formed on its surface. In the adsorption kinetic analysis, the adsorption of Sr and Cs ions on Z-Y2 fitted the pseudo-second-order kinetic model well, instead of the pseudo-first-order kinetic model. The second-order kinetic rate constant ($k_2$) was determined to be $0.0614g/mmol{\cdot}min$ for Sr and $1.8172g/mmol{\cdot}min$ for Cs. The adsorption equilibria of Sr and Cs ions on Z-Y2 were fitted successfully by Langmuir model. The maximum adsorption capacity ($q_m$) of Sr and Cs was calculated as 1.6846 mmol/g and 1.2055 mmol/g, respectively. The maximum desorption capacity ($q_{dm}$) of the Na ions estimated via the Langmuir desorption model was 2.4196 mmol/g for Sr and 2.1870 mmol/g for Cs. The molar ratio of the desorption/adsorption capacity ($q_{dm}/q_m$) was determined to be 1.44 for Na/Sr and 1.81 for Na/Cs, indicating that the amounts of desorbed Na ions and adsorbed Sr and Cs ions did not yield an equimolar ratio when using Z-Y2.

• 한국지반공학회논문집
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• 제25권6호
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• pp.47-57
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• 2009

본 연구에서는 다층지반에서 수평하중을 받는 말뚝을 대상으로 콘관입치를 이용하여 극한수평지지력을 산정하였으며, 다층지반조건을 고려할 수 있는 토압분포 형태를 제안하고자 한다. 이를 위해 각 층의 상대밀도를 달리한 12개의 다층지반을 조성하여 각 지반에 대해 콘관입시험 및 수평말뚝재하시험을 수행하였으며, 각각의 다층지반조건에 대한 극한수평지지력을 비교, 분석하였다. 극한수평지지력 산정은 Broms(1964), Petrasovits & Award(1972), Prasad & Ch뼈(1999)가 제안한 방법을 기준으로 하였으며, Prasad & Chari(1999)의 방법에 대해서는 다층지반 조건을 고려하기 위한 수정된 토압분포형상을 적용하였다. 본 연구 결과, 다층지반 조건을 고려한 제안 방법이, 기존의 단일지반에 적용했던 토압분포 형상을 이용하는 방법보다 향상된 정밀도를 보여 주였다. 극한수평지지력 분포형상에 있어서도 Broms(1964), Petrasovits & Award(1972)의 방법으로 산정한 극한수평지지력과 유사한 분포를 보였다.

• 한국지반공학회논문집
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• 제25권1호
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• pp.55-64
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• 2009

수평하중에 대한 지지력의 발휘는 말뚝의 주요 용도 중 하나이며, 최근 초고층 건물, 송전탑, 풍력발전기 등 수평하중이 지배적인 구조물의 증가로 이에 대한 연구가 활발히 진행되고 있다. Broms(1964) 이후 많은 연구자들이 수평방향 지지력 산정을 위한 방법들을 제안하여 왔으나, 각 방법별로 서로 다른 토압분포와 수평토압계수를 가정하여 설계자로 하여금 혼란을 가져을 여지를 갖고 있다. 수평지지력 산정에 주요 요소가 되는 수평토압계수는 수평하증에 의한 말뚝의 회전 거동에 영향을 받는다. Prasad와 Chari(1999)는 말뚝의 회전점을 가정하여 극한지지력을 산정하는 식을 제안하였다. 본 연구에서는 균일지반과 다층지반의 모두에서 말뚝의 회전점을 측정하였으적, 기존의 연구 결과와 비교하였다. 실험 결과 회전점 측정값과Prasad와 Chari(1999)의 예측값이 잘 일치하였으며 다층지반은 회전점의 위치를 변하게 하는 요소로 작용하는 것으로 나타났다.

• 한국지반환경공학회 논문집
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• 제18권10호
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• pp.5-14
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• 2017

In recent years, world has witnessed many man-made activities related to both above and underground blasts. Details on behaviour of shallow foundations subjected to blast loads and induced liquefaction is scarce in literature. In this paper, typical shallow strip foundation in saturated cohesionless soils subjected to both above and underground blasting have been simulated by using finite difference based numerical model FLAC3D. Peak particle velocity (PPV) has been obtained to propose critical values for which bearing capacity failure for shallow foundations with soil liquefaction can occur. Typical results for pore pressure ratio (PPR) for various scaled distances are compared to PPR values obtained by using empirical equation available in literature which shows good agreement. Critical design values obtained in the present study for PPV and PPR to estimate the scaled distance, bearing capacity failure and liquefaction susceptibility can be used effectively for design of shallow strip foundation in cohesionless soil subjected to both above and under ground blast loads.

• 한국환경과학회지
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• 제11권9호
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• pp.945-954
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• 2002

The objective okgf this study is understanding and evaluation of temporal and spatial variation of pollutant loads by input sources for water quality management in Kamak Bay. Flow rate of rivers and ditches ranges from about $2,592-63,072m^3/d$ in October to $864-55,296m^3/d$ in January. In particular, the R2 predominated flow rate among input sources. Total COD, BOD, DIN and DIP loadings in January were about 896kg/d, 718kg/d, 2,152kg/d, and 154kg/d, respectively, which exceeded those of October. Lower POC/TOC levels are estimated in R2, and also in October. Temporal variation of pollutant loads were closely related to the human activity. Total discharging loadings of BOD, TN and TP by unit loading estimation were 4,993.0kg/d, 2,558.7kg/d, and 289.2kg/d, respectively, and were mainly affected by the population. Runoff ratio of BOD was about 0.14 in January Mean $NH_4^＋_-N$ and $PO_4\;^{3-}-P$ loadings from sediment were 16.23mg/$m^2$/d and 7.26mg/$m^2$/d, respectively. For the improvement of water quality in this area, not only pollutant loads of rivers and ditches but also benthic flux from sediment should be reduced within the limits of the environmental capacity.

• 한국환경과학회지
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• 제21권6호
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• pp.705-711
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• 2012

Adsorption experiment of carbon dioxide was performed on MCM41 silica with a 30 wt.% EDA(ethylenediamine) loading at different $CO_2$ inlet concentration and various adsorption temperature. The surface characteristics of $CO_2$ capturing agent were carried out using BET analysis, X-ray diffraction and FT-IR. The results of BET showed 781 $m^2/g$ for MCM41 and 464 $m^2/g$ for EDA/MCM41. X-ray diffraction results reveled typical hexagonal pore system. The higher sorption capacity of EDA/MCM41 was about 80 $mg_{CO2}/g_{sorbent}$ with 50% $CO_2$ inlet concentration and 303 K adsorption temperature. The isosteric heat of adsorption in 303-353 K ranged from -25.47 to -28.24 KJ/mole for EDA/MCM41, which indicates $CO_2$-EDA/MCM41 interaction with exothermic adsorption process. Finally, the performance of EDA/MCM41 in 10 consecutive sorption-desorption runs was a stable with only a minor drop in its sorption capacity.

• 한국환경과학회지
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• 제21권6호
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• pp.687-694
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• 2012

Zeolite 4A was synthesized by fusion method from coal fly ash discharged at the thermal power plants. The synthesized zeolite(FAZ) was characterized through particle size analyzer, XRD, XRF and SEM. $N_2$ adsorption-desorption measurement was used to examine surface and pore structures. The adsorption experiments were carried out under dynamic conditions of trace $SO_2$ in $N_2$ to investigate $SO_2$ adsorption capacity of FAZ. The experiments were conducted to characterize the breakthrough characteristics of $SO_2$ in a fixed bed under different operating conditions including temperature(50-$125^{\circ}C$), concentration of $SO_2$(3000-10000 ppm) and FAZ with 4 kinds of commercial zeolite. The adsorption capacity of FAZ was 53.84 $mgSO_2/g$ adsorbent, larger than that of the same type commercial zeolite(WK4A).

• 한국환경과학회지
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• 제29권8호
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• pp.827-835
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• 2020

Zeolite material having XRD peaks of Na-A zeolite in the 2θ range of 7.18 to 34.18 can be synthesized from the waste catalyst using a fusion/hydrothermal method. The adsorption rate of Mn ions by a commercial Na-A zeolite and the synthesized zeolitic material increased as the adsorption temperature increased in the range of 10 ~ 40℃. The adsorption of Mn ion were very rapid in the first 30 min and then reached to the equilibrium state after approximately 60 min. The adsorption kinetics of Mn ions by the commercial Na-A zeolite and the zeolitic material were found to be well fitted to the pseudo-2^nd order kinetic model. Equilibrium data by the commercial Na-A zeolite and the zeolitic material fit the Langmuir, Koble-Corrigan, and Redlich-Peterson isotherm models well rather than Freundlich isotherm model. The removal capacity of the Mn ions by the commercial Na-A zeolite and the zeolitic material obtained from the Langmuir model was 135.2 mg/g and 128.9 mg/g at 30℃, respectively. The adsorption capacity of Mn ions by the synthesized zeolitic material was almost similar to that of commercial Na-A zeolite. The synthesized zeolitic material could be applied as an economically feasible commercial adsorbent.