• 한국보육지원학회지
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• 제15권6호
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• pp.41-57
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• 2019

Objective: The purpose of this study was to investigate the moderate effect of the physical environmental-level between infant teachers' positive play beliefs and teacher-infant interaction. Methods: The subjects of this study were 483 teachers in charge of one-year-old and two-year-old infants in child care centers located in metropolitan areas. The data were collected by asking the teachers to respond to a questionnaire and the data collected were analyzed through correlation and hierarchical multi- regression analysis. Results: First, the positive play beliefs of the infant teacher, the physical environment level, and the teacher-infant interaction showed significant proportional correlations. Second, the physical environment level moderated the influence of the teacher's positive play beliefs on teacher-infant interaction. In particular, results showed that functional interior space configuration, outdoor playground composition and facilities among the sub-variables of the physical environment level had a moderating effect. Conclusion/Implications: The results of this study show that teachers with positive play beliefs have positive teacher-infant interaction when there is sufficient space available for infants and teachers. This indicates that the human and physical environments of child care centers can promote teacher-child interaction.

• 한국물환경학회지
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• 제28권1호
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• pp.148-156
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• 2012

In this research, the application of carbon nanotubes (CNTs) modified PVDF (polyvinylidene fluoride) membrane was tested as a simply and beginning attempt to overcome membrane fouling because CNTs importantly affect the transport of natural organic matter (NOM). Suwannee River fulvic acid (SRFA) as the representative of NOM was selected and its sorption results with single-walled CNT (SWCNT), multi-walled CNT (MWCNT), and oxidized MWCNT (O-MWCNT) were obtained through the batch experiment. SRFA sorption isotherms had a strong nonlinearity and its sorption capacity followed the order O-MWCNT < MWCNT < SWCNT. The adsorbed mass of SRFA on each CNT decreased as a function of pH due to their charge repulsion. For the CNT-PVDF membrane filtration experiments, the suspended CNT solution (10 mg/40 mL) was incorporated into $0.45{\mu}m$-PVDF membrane and 5 mg/L of SRFA solution was monitored using UV detector connected with high pressure pump after passing through CNT-PVDF membrane. The SRFA removal efficiency by MWCNT-PVDF membrane was the strongest among other modified membranes. This suggests that the CNT modified microfiltration (MF) membrane might effectively and selectively apply to treat the contaminated water including organic compounds in the presence of NOM.

• Membrane and Water Treatment
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• 제6권2호
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• pp.141-160
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• 2015

This study aims to investigate the impacts of chemical cleaning on the performance of a reverse osmosis membrane. Chemicals used for simulating membrane cleaning include a surfactant (sodium dodecyl sulfate, SDS), a chelating agent (ethylenediaminetetraacetic acid, EDTA), and two proprietary cleaning formulations namely MC3 and MC11. The impact of sequential exposure to multiple membrane cleaning solutions was also examined. Water permeability and the rejection of boron and sodium were investigated under various water fluxes, temperatures and feedwater pH. Changes in the membrane performance were systematically explained based on the changes in the charge density, hydrophobicity and chemical structure of the membrane surface. The experimental results show that membrane cleaning can significantly alter the hydrophobicity and water permeability of the membrane; however, its impacts on the rejections of boron and sodium are marginal. Although the presence of surfactant or chelating agent may cause decreases in the rejection, solution pH is the key factor responsible for the loss of membrane separation and changes in the surface properties. The impact of solution pH on the water permeability can be reversed by applying a subsequent cleaning with the opposite pH condition. Nevertheless, the impacts of solution pH on boron and sodium rejections are irreversible in most cases.

• Computers and Concrete
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• 제17권2호
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• pp.201-214
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• 2016

The outer tank of a liquefied natural gas (LNG) storage tank is a longitudinally and meridianally pre-stressed concrete (PSC) wall structure. Because of the current trend of constructing larger LNG storage tanks, the pre-stressing forces required to increase wall strength must be significantly increased. Because of the increase in tank sizes and pre-stressing forces, an extreme loading scenario such as a bomb blast or an airplane crash needs to be investigated. Therefore, in this study, the blast resistance performance of LNG storage tanks was analyzed by conducting a blast simulation to investigate the safety of larger LNG storage tanks. Test data validation for a blast simulation of reinforced concrete panels was performed using a specific FEM code, LS-DYNA, prior to a full-scale blast simulation of the outer tank of a 270,000-kL LNG storage tank. Another objective of this study was to evaluate the safety and serviceability of an LNG storage tank with respect to varying amounts of explosive charge. The results of this study can be used as basic data for the design and safety evaluation of PSC LNG storage tanks.

• Environmental Engineering Research
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• 제19권1호
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• pp.107-113
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• 2014

Small sized manganese dioxide particles are immobilized onto the surface of sand by the wet impregnation process. The surface morphology of the solid, i.e., immobilized manganese dioxide natural sand (IMNS) is performed by taking scanning electron microscope images and characterized by the X-ray diffraction data. The specific surface area of the solid is obtained, which shows a significant increase in the specific surface area obtained by the immobilization of manganese dioxide. The $pH_{PZC}$ (point of zero charge) is found to be 6.28. Further, the IMNS is assessed in the removal of As(III) and As(V) pollutants from aqueous solutions under the batch and column operations. Batch reactor experiments are conducted for various physicochemical parametric studies, viz. the effect of sorptive pH (pH 2.0-10.0), concentration (1.0-25.0 mg/L), and background electrolyte concentrations (0.0001-0.1 mol/L $NaNO_3$). Further, column experiments are conducted to obtain the efficiency of IMNS under dynamic conditions. The breakthrough data obtained by the column experiments are employed in non-linear fitting to the Thomas equation, so as to estimate the loading capacity of the column for As(III) and As(V).

• Environmental Engineering Research
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• 제14권4호
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• pp.220-225
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• 2009

The water quality in eutrophic lakes is affected by serious problems, such as abnormal increasing of Cyanobacteria. The purpose of this study was to investigate the possibility of a modified flotation system using a hybrid technique formed by chemical compounds and an electrostatic bridge. Therefore, experiments using the hybrid technique were performed to measure the zeta potential value on the phytoplankton surface and the removal efficiencies of phytoplankton, ammonia nitrogen, nitrate nitrogen and phosphoric acid. The results were as follows: Firstly, the zeta potential of M.aeruginosa was observed to approach charge neutralization due to adhesion of magnesium hydroxide precipitate on the phytoplankton surface in the pH range 10.5 to 11. Secondly, the concentration of chlorophyll-a decreased from about 150 to 20${\mu}g$g/L, with a maximum removal efficiency of 84% due to coagulation with pH values higher than 10. Thirdly, the N$H_4$-N concentration was observed to decrease from 0.62 to 0.54mg-N/L (13%), and the P$O_4$-P concentration, which is a limiting factor to the formation of algae blooms, decreased from 0.27 to 0.02mg-P/L (92%). These findings suggest that the modified flotation system can be applied for the purification of the raw water of numerous lakes containing high phytoplankton populations and elevated pH.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3671-3676
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• 2013

A series of carbon nanotube, $C_{60}$, and graphene modified $TiO_2$ nanocomposites were prepared by hydrothermal method. X-ray diffraction, $N_2$ adsorption, UV-Vis spectroscopy, photoluminescence, and Electrochemical impedance spectra were used to characterize the prepared composite materials The results reveal that incorporating $TiO_2$ with carbon materials can extend the adsorption edge of all the $TiO_2$-carbon nanocomposites to the visible light region. The photocatalytic activities were tested in the degradation of 2,4,6-trichlorophenol (TCP) under visible light. No obvious difference in essence was observed in structural and optical properties among three series of carbon modified $TiO_2$ nanocomposites. Three series of carbon materials modified $TiO_2$ composites follow the analogous tentative reaction mechanism for TCP degradation. GR modified $TiO_2$ nanocomposite exhibits the strongest interaction and the most effective interfacial charge transfer among three carbon materials, thus shows the highest electron-hole separation rate, leading to the highest photocatalytic activity and stability.

• 상하수도학회지
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• 제28권5호
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• pp.517-527
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• 2014

As sewer flooding frequents due to localized and concentrated stormwater and increased non-permeable surface area after urbanization, building cities with sound water recycle and accordingly efficient management of rainwater is demanded. To do this, the existing sewage (including rainwater) fee imposition system should be philosophically evaluated. This study presents problematic issues of the existing domestic sewage fee imposition system considering the principle of sharing costs on the service of sewage and rainwater collection and treatment. Four methods to improve the existing sewage fee imposition system are suggested: 1) imposing stormwater fee according to Polluter Pays Principle, 2) clarification of the share of public sector, 3) reducing or exempting the sewerage fee for inhabitants reducing urban runoff by constructing their own rainwater management facilities, 4) imposing charge for discharging rainwater to sewers due to new development action. Short, mid, or long term planning for rainwater management is recommended considering the situation of each municipality.

• 한국환경과학회지
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• 제18권10호
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• pp.1181-1187
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• 2009

Results for application of RDF(Refuse Derived Fuel) to selected wastes in metropolitan and small and medium cities are as follows. The physical characteristics of waste are paper, plastic, food waste, and so on. The proximate analysis in P city showed 20.2% of moisture, 71% of combustible material, and 8.8% of ash on annual average. That in G city showed 31.6% of moisture, 59.5% of combustible material, and 8.9% of ash. Ultimate analysis in P city showed 52.04% of carbon, 7.02% of hydrogen, 28.80% of oxygen, 0.66% of nitrogen, and 0.09% of sulfur. Heating value was 3,363 kcal/kg. Ultimate analysis in G city showed 50.85% of carbon, 6.56% of hydrogen, 29.86% of oxygen, 0.79% of nitrogen, and 0.12% of sulfur. Heating value in the G city was somewhat lower than that in the P city with 2,632 kcal/kg. Thus, application of RDF in metropolitan city was more effective than that in small and medium cities. Heating value in mixture for the P city was lower than that in waste of the volume rate waste charge system alone by 143 kcal/kg. In proximate analysis, moisture, and combustible material were likely to be more adequate to RDF.

• 환경위생공학
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• 제17권3호
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• pp.115-120
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• 2002

This study was performed on a questionnaire survey of 500 people about their awareness for indoor air pollution, and measured efficiency of air cleaner which can remove the CO and air-borne particulate of ETS(Environmental Tobacco Smoke) in air clean chamber. The room-size cleaner for measuring indoor air contaminants has been applied to evaluation of two different air cleaner such as the mechanic air cleaner with hepafilter(HPA) and the electrostatic air cleaner with metal plate. The measuring experiment was carried out in a chamber by sampling the air. The results obtained were as follows; As respondents are having their 90% of daytime indoors a day, and 38% of them can feel indoor air pollutions degrees directly by their sense of smell, For the installation of indoor pollution control equipment, 34% of all respondents installed air cleaner because of the problem of economical charge and almost respondents was not satisfied the trust of ability purified indoor air pollutants. In the experimental results, it was found that more than 95% of CD and air-borne particulate of ETS were removed within 20 minutes. The reaction kinetics of removal pollutants was verified as the pseudo-first order, Finally, it appeared that the room-sire air cleaner can be applied to new technology for removing indoor air contaminants.