• Journal of Magnetics
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• v.18 no.4
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• pp.386-390
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• 2013

This paper studies the effects of A-site substitution by barium on the magnetic and magnetocaloric properties of $Pr_{0.5}Sr_{0.5-x}Ba_{x}MnO_{3}$ (x = 0, 0.04, 0.08 and 0.1). The tetragonal crystal structures of the samples are confirmed by room temperature X-ray diffraction. The dependence of the Curie temperature ($T_C$) and the magnetic entropy change (${\Delta}S_M$) on the Ba doping content has been investigated. The samples of all doping contents undergo the second order phase transition. As the concentration of Ba increased, the maximum entropy change ($|{\Delta}S_M|_{max}$) increased gradually, from 1.15 J $kg^{-1}$ $K^{-1}$ (x = 0) to 1.36 J $kg^{-1}$ $K^{-1}$ (x = 0.1), in a magnetic field change of 1.5 T. The measured value of $T_C$ is 265 K, 275 K, 260 K and 250 K for x = 0, 0.04, 0.08 and 0.1, respectively. If combining these samples for magnetic refrigeration, the temperature range of ~220 K and 290 K, where |${\Delta}S_M$|max is stable at ~1.27 J $kg^{-1}$ $K^{-1}$ and RCP = 88.9 $J{\cdot}kg^{-1}$ for ${\Delta}H$ = 1.5 T. $Pr_{0.5}Sr_{0.5-x}Ba_{x}MnO_{3}$ compounds, are expected to be suitable for magnetic-refrigeration application due to these magnetic properties.

• Bulletin of the Korean Chemical Society
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• v.28 no.5
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• pp.758-762
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• 2007

A new alkyldithiocarbonate (xanthate), as sodium salts, C2H5OCS2Na, was synthesized by the reaction between CS2 with ethyl alcohol in the presence of NaOH. The new xanthate was characterized by 1H NMR, IR and elemental analysis. Then, the new synthesized compound was examined for functional study of cresolase activity of Mushroom Tyrosinase (MT) from a commercial source of Agricus bisporus in 10 mM phosphate buffer pH 6.8, at three temperatures of 10, 20 and 33℃ using UV spectrophotemetry. 4-[(4-methylphenyl)- azo]-phenol (MePAPh) was used as a synthetic substrate for the enzyme for cresolase reaction. The results show that ethyl xanthate can activate or inhibit the cresolase activity of mushroom tyrosinase depending to the concentration of ethyl xanthate. It was concluded that the enzyme has two distinct sites for ethyl xanthate. The first one is a high-affinity activation site and the other is a low-affinity inhibition site. Activation of the enzyme in the low concentration of ethyl xanthate arises from increasing the affinity of binding for the substrate as well as increasing the enzyme catalytic constant. The affinity of ligand binding in the activation site is decreased by increasing of the temperature, which is the opposite result for the inhibition site. Hence, the nature of the interaction of ethyl xanthate is different in two distinct sites. The binding process for cresolase inhibition is only entropy driven, meanwhile the binding process for cresolase activation is not only entropy driven but also enthalpy driven means that hydrophobic interaction is more important in the inhibition site.

• Korean Journal of Food Science and Technology
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• v.9 no.2
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• pp.165-169
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• 1977

An apparatus for continuous sterilization of fluids in which heating-up and cooling time are negligible enabled determination of the kinetics of thermal inactivation of peroxidase for the range of temperatures $110{\sim}140^{\circ}C$. The enthalpy of activation was 146.4 kJ/mol; free energy of activation, 113kJ/mol; and the entropy of activation, 82.9J/mol.K. Comparisons of the experimental results with the thermal destruction time curves of microorganisms showed the possibility that the time required to inactivate peroxidase might be taken into account in evaluating thermal processes for commerciel HTST methods.

• Architectural research
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• v.12 no.1
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• pp.9-14
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• 2010

The present study explored the applicability of Visibility Graph Analysis (VGA) techniques to workplace design research. Six types of VGA measures in Depthmap encompassing visual connectivity, three types of visual integration, mean depth, and visual entropy were employed for the analysis of individual privacy for task concentration and group relationship behavior in the open-plan office environment. Data comprised 136 workers in 6 open-plan offices filled with low-paneled (1.2-1.5m) cubicle workspaces. For the statistical analysis, Spearman's rho correlations and t-tests were applied for the spatial and behavioral measures. The results showed that workspace VGA measures have a potential to be useful information to account for workers' concentration privacy and, limitedly, also informal relationships with team members. Visual entropy values especially offer reliable information to predict various aspects of office workers' privacy behavior while visual integration can be used to account for the workers' sense of trust in group relations. The study also discussed the limitation of VGA applications to the workplace context.

• Proceedings of the Korea Contents Association Conference
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• 2006.05a
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• pp.351-355
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• 2006

The purpose of this study is to develop an efficient and useful equation of discharge measurement which can calculate easily discharge using only the surface velocity in both channels and rivers. The research results show: (1) Natural river have a propensity to establish and maintain an equilibrium state the corresponds to a value of the entropy parameter M; (2) Velocity distribution estimated by the method using surface velocity was compared with that of actual survey. It shows fairly close agreements between the estimated and the observed; (3) Developed equations for calculating the discharge using the surface velocity at the spot of the maximum velocity in a river section were established and show that the method of using fairly acceptable. An entropy based method for determining the discharge using only surface velocity in the rivers has been developed. The method presented is also efficient and applicable in estimating the discharge in high flows during the flood season that are very difficult or impossible to measure before, due to technical or theoretical reasons.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.5
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• pp.437-446
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• 2016

Feature selection has become an essential technique to reduce the dimensionality of data sets. Many features are frequently irrelevant or redundant for the classification tasks. The purpose of feature selection is to select relevant features and remove irrelevant and redundant features. Applications of the feature selection range from text processing, face recognition, bioinformatics, speaker verification, and medical diagnosis to financial domains. In this study, we focus on filter methods based on information entropy : IG (Information Gain), FCBF (Fast Correlation Based Filter), and mRMR (minimum Redundancy Maximum Relevance). FCBF has the advantage of reducing computational burden by eliminating the redundant features that satisfy the condition of approximate Markov blanket. However, FCBF considers only the relevance between the feature and the class in order to select the best features, thus failing to take into consideration the interaction between features. In this paper, we propose an improved FCBF to overcome this shortcoming. We also perform a comparative study to evaluate the performance of the proposed method.

• Proceedings of the Korean Magnestics Society Conference
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• 2012.11a
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• pp.166-167
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• 2012

• Journal of the Korean Ceramic Society
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• v.28 no.2
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• pp.109-118
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• 1991

Steady-state sublimation vapour pressures of anhydrous bismuth triiodide have been measured by the torsion-effusion method from 488.8 to 570.5 K and equilibrium sublimation pressures were obtained from the steady-state data. The standard sublimation enthalpy changes derived by both second(modified sigma function) and third(average enthalpy method) law methods were 159.316${\pm}$0.055, 137.67${\pm}$1.43 kJ$.$mol-1 respectively. The standard sublmation entropy change derived by modified sigma function was 232.88${\pm}$0.10 J$.$K-1$.$mol-1. The reliable standard sublimation enthalpy change based on a correlation of {{{{ { TRIANGLE }`_{cr } ^{g } }} H{{{{ { 0} atop {m } }}(298.15K) and {{{{ { TRIANGLE }`_{cr } ^{g } }} S{{{{ { 0} atop {m } }}(298.15K), a recommended p(T) equation has been obtained for BiI3(cr) ; lg(p/Pa)=-(C$.$K/T)+5.071lg(T/K)-2.838${\times}$10-3(T/K)-7.758${\times}$103(K/T)2+1.4519 where C={{{{{ { TRIANGLE }`_{cr } ^{g } }} H{{{{ { 0} atop {m } }}(298.15K)/0.019146 kJ$.$mol-1}-456.27.

• Journal of the Korean Chemical Society
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• v.40 no.6
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• pp.409-414
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• 1996

The limit of applicability of Navier-Stokes equation to stationary plane shock-waves is examined by using the principle of minimum entropy production of linear irreversible thermodynamics. In order to obtain analytic results, the equation is linearized near the equilibrium of downstream. Results show that the solution of Navier-Stokes equation which fits the boundary condition of far downstream flow is consistent with the thermodynamic requirement within the first order when the solution is expanded around the M=1, where M is the Mach number of upstream speed.

• Bulletin of the Korean Chemical Society
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• v.6 no.5
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• pp.266-269
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• 1985

The dissociation constants(K) of m-chloroanilinium ion in water-ethanol mixture, where the volume percentage of water is 89.5%, were evaluated by UV-spectroscopic method at $20{\sim}50^{\circ}C$, up to 1500 bars with changing ionic strength from 0.04 to 0.10 mol $kg^{-1}$ by use of acetate buffer. K values enhance with increasing ionic strength and temperature, but decrease with elevating pressure. From K values, we obtained the partial molar volume change and some other thermodynamic parameters. From the values of enthalpy, entropy and isoequilibrium temperature (649 K), we concluded that the dissociation of m-chloroanilinium ion mentioned above is controlled by enthalpy.