• Transactions of the Korean hydrogen and new energy society
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• v.34 no.1
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• pp.1-7
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• 2023

A fuel handling process combined with a pressure swing adsorption system (PSA) was simulated to produce pure hydrogen with a purity greater than 99.97%. The simulation consists of two parts. The fuel processing part consisting of reformer and water-gas shift reaction was simulated with Aspen plus^®, and the hydrogen purification part consisting of PSA was simulated with Aspen Adsorption^®. In this study, the effect of reformer temperature and pressure on the total hydrogen production yield was investigated. Simulations were performed over a temperature range of 700 to 1,000℃ and a pressure range of 1 to 10 bar. The total hydrogen production yield increased with increasing temperature and decreasing pressure. The maximum hydrogen yield was less than 50% in the simulation and will be lower in the real process.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2000.10a
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• pp.265-272
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• 2000

Unbond brace hysteretic dampers are generally used to prevent or decrease structural damage in buildings subjected to strong earthquake by its energy dissipating hysteretic behavior. According to a previous research, the optimum ratio of device yield strength to story yield strength of the combined system has been identified as the most important parameter for characterizing the performance of this device. In this research, the validity and the applicability of the previous research has been investigated and a new approach has been proposed through earthquake response analysis of a steel structure installed with unbond brace type hysteretic damper.

• Bulletin of the Korean Chemical Society
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• v.15 no.11
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• pp.971-975
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• 1994

Cross sections and recoil properties have been measured for the fragments produced in the interaction of silver with 40 MeV/nucleon $^{14}N$ ions using off-line ${\gamma}$-ray spectroscopy. The data were used to obtain the isobaric-yield distribution, the mass yield distribution, and the fractional momentum transfer. The values of forward-to-backward ratios were measured to be very large, indicating that substantial momentum transfer occurs at this energy regime. The results are compared with other studies of the interaction of silver with intermediate-energy heavy ions.

• Journal of Soil and Groundwater Environment
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• v.19 no.5
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• pp.45-52
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• 2014

Torrefaction and hydrothermal carbonization (HTC) are productive methods to reclaim energy from lignocellulosic biomass. The hydrophobic, homogenized, energy dense and carbon rich solid fuel can be obtain from torrefaction and hydrothermal carbonization. Dead leaves were carbonized in a stainless steel reactor of volume 200 ml with torrefaction ($250-270^{\circ}C$) for 120 minutes and hydrothermal carbonization ($200-250^{\circ}C$) for 30 minutes, with mass yield solid fuel ranging from 57-70% and energy content from 16.81MJ/kg to 22.01 MJ/kg compare to the biomass. The char produced from torrefaction process possess high energy content than hydrothermal carbonization. The highest energy yield of 89.96% was obtained by torrefaction at $250^{\circ}C$. The energy densification ratio fluctuated in between 1.15 to 1.30. On the basis of pore size distribution of the chars, the definition of the International Union of Pure and Applied Chemistry (IUPAC) was used as a classification standard. The pore diameter was ranging within 11.09-19 nm which play important role in water holding capacity in soil. Larger pores can hold water and provide passage for small pores. Therefore, it can be concluded that high pore size char can be obtained my HTC process and high energy content char of 22.01 MJ/Kg with 34.04% increase in energy can be obtain by torrefaction process.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.232-238
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• 2021

The development of a low cost catalyst with high performance and small amount of carbon deposition on catalyst from toluene steam reforming were investigated by using coal ash as a support material. Ni-loaded coal ash catalyst showed similar catalytic activity for toluene steam reforming compared with the Ni/Al2O3. At 800 ℃, the toluene conversion was 77% for Ni/TAL, 68% for Ni/KPU and 78% for Ni/Al2O3. Ni/TAL showed similar toluene conversion to Ni/Al2O3. However, Ni/KPU produced higher hydrogen yield at relatively lower toluene conversion. Ni/KPU catalyst showed a remarkable ability of suppressing the carbon deposition. The difference in coke deposition and hydrogen yield is due to the composition of KPU ash (Ca and Fe) which increase coke resistance and water gas shift reaction. This study suggests that coal ash catalysts have great potential for the application in the steam reforming of biomass tar.

• Proceedings of the Korean Nuclear Society Conference
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• 2004.10a
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• pp.767-767
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• 2004

• Magazine of the Korean Society of Agricultural Engineers
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• v.39 no.1
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• pp.93-101
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• 1997

This paper presents yield surfaces and hardening laws for describing the state of an unsaturated soil under isotropic compression and suction changes. The yield surface is formulated within the framework of hardening plasticity using two independent sets of stress variables : the excess of total stress over air pressure and the suction. And the application of the yield surfaces and hardening laws are confirmed from the result of the experiment. To this end a series of suction-controlled isotropic tests are conducted on clayey soils. Matric suction is controlled by the axis translation technique using high air entry ceramic disk. The specimens are compacted using a half of Proctor compaction energy with 5 % lower of water content than the optimum moisture contents. From test results, existence of the yield surfaces and an application of hardening laws to samples are confirmed by comparison between test and predicted results. And it is confirmed that LC yield locus is extened with the total plastic deformations induced by suction or stress changes, however, SI yield locus is only extended with the plastic deformations by induced suction changes.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.326-332
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• 2011

The authors examined the effects of operating parameters on the $H_2$ production by dark fermentation of the wastewater generated from food waste recycling facilities, in short "food waste wastewater (FWW)". Central composite design based response surface methodology was applied to analyze the effect of initial pH (5.5-8.5) and substrate concentration (2-20 g Carbo. COD/L) on $H_2$ production. The experiment was conducted under mesophilic ($35^{\circ}C$) condition and a heat-treated ($90^{\circ}C$ for 20min)anaerobic digester sludge was used as a seeding source. Although there was a little difference in carbohydrate removal, $H_2$ yield was largely affected by the experimental conditions, from 0.38 to 1.77 mol $H_2$/mol $hexose_{added}$. By applying regression analysis, $H_2$ yield was well fitted based on the coded value to a second order polynomial equation (p = 0.0243): Y = $1.78-0.17X_1+0.30X_2+0.37X_1X_2-0.29X_1{^2}-0.35X_2{^2}$, where $X_1$, $X_2$, and Y are pH, substrate concentration (g Carbo. COD/L), and hydrogen yield (mol $H_2$/mol $hexose_{added}$), respectively. The 2-D response surface clearly showed a high inter-dependency between initial pH and substrate concentration, and the role of these two factors was to control the pH during fermentation. According to the statistical optimization, the optimum condition of initial pH and substrate concentration were 7.0 and 13.4 g Carbo. COD/L, respectively, under which predicted $H_2$ yield was 1.84 mol $H_2$/mol $hexose_{added}$. Microbial analysis using 16S rRNA PCR-DGGE showed that $Clostridium$ sp. such as $Clostridium$ $perfringens$, $Clostridium$ $sticklandii$, and $Clostridium$ $bifermentans$ were main $H_2$-producers.

• Journal of the Korean Society of Food Science and Nutrition
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• v.40 no.5
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• pp.712-716
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• 2011

We investigated changes in the extraction yield and whitening activity of polysaccharides from Undaria pinnatifida sporophyll due to gamma irradiation. U. pinnatifida sporophyll was gamma-irradiated at doses of 10, 30, 50, 70, and 100 kGy, then extracted with hot water and precipitated with ethanol to extract polysaccharides. Crude polysaccharide yields increased with an increase in irradiation dosage, but tyrosinase inhibition activity did not change. Melanin synthesis did not significantly differ between B16BL6 cells treated with irradiated and non-irradiated samples. In conclusion, gamma irradiation increased the crude polysaccharide extraction yield but did not change the whitening activity of U. pinnatifida sporophyll. This implies that gamma irradiation can be used to increase yields in the cosmetic industry, thus increasing profits.

• Journal of Radiation Industry
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• v.4 no.1
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• pp.1-6
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• 2010

The purpose of this study is to synthesize the radio fluorine labelled isoquinoline salt derivative as new radiopharmaceutical for imaging tumors using positron emission tomography (PET). The planarity of isoquinoline allows to inhibit topoisomerase or intercalate between adjacent DNA base pairs, which result in producing double strand breaks in the DNA and a cell death. Therefore, the isoquinoline has seemed to have a potential anticancer activity. In order to obtain 2-(5-[$^{18}F$]fluoropentylisoquinolinium salt with good radiochemical yield, tosylated precursors have been synthesized. The labelling reaction was carried out for 30 minute in HMPA at $120^{\circ}C$. The radiochemical yield was about 50~60%.