• 제목/요약/키워드: Energy transfer ratio

검색결과 405건 처리시간 0.022초

Study of Anisotropic Photoluminescence and Energy Transfer in Oriented Dye-incorporating Zeolite-L Monolayer

  • Lee, Jin-Seok
    • Bulletin of the Korean Chemical Society
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    • 제31권8호
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    • pp.2190-2194
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    • 2010
  • Development of the methods to organize zeolite microcrystals into closely packed and uniformly aligned monolayers on various substrates have been pursued viewing microparticles as a novel class of building blocks. We now report that the vertically aligned zeolite monolayer can be applied as novel supramolecularly organized systems for anisotropic photoluminescence in high dichroic ratio, to study energy transfer dynamics between the internal and external fluorophores, and to develop zeolite-based advanced materials. Study of polarized fluorescence spectroscopy and angle-dependent intensity change with dye molecules in different surroundings further provides insight into molecular interactions that can be used for the future design of optoelectronic device in nanometer size. In addition, this report shows that isolating of organic dye through surface treatment is crucial for preventing the egress of the incorporated dye molecules from the channels of zeolite to the solution and to enhance the anisotropic luminescence.

Single-molecule Detection of Fluorescence Resonance Energy Transfer Using Confocal Microscopy

  • Kim, Sung-Hyun;Choi, Don-Seong;Kim, Do-Seok
    • Journal of the Optical Society of Korea
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    • 제12권2호
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    • pp.107-111
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    • 2008
  • We demonstrated single-molecule fluorescence resonance energy transfer (FRET) from single donor-acceptor dye pair attached to a DNA with a setup based on a confocal microscope. Singlestrand DNAs were immobilized on a glass surface with suitable inter-dye distance. Energy transfer efficiency between the donor and the acceptor dyes attached to the DNA was measured with different lengths of DNA. Photobleaching of single dye molecule was observed and used as a sign of single-molecule detection. We could achieve high enough signal-to-noise ratio to detect the fluorescence from a single-molecule, which allows real-time observation of the distance change between single dye pairs in nanometer scale.

용량이행영 소형 XeCl레이저 제작 및 출력특성 (Fabrication and Output Characteristics of Compact Capacitor Transfer XeCl Laser)

  • 김동환
    • 한국광학회지
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    • 제4권1호
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    • pp.57-65
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    • 1993
  • 용량 이행형 방전여기에 의한 소형 XeCl레이저를 제작하고, 가스 혼합비에 따른 출력특성을 조사하였다. 내자형 capacitor에 의한 자동 예비전리 방식과 2.7 cm 간격의 Chang형상으로 가공된 전극구조의 레이저를 구성하여 2.7cm${\times}$1.5cm 크기의 출력 빔을 얻었고, Xe과 HC1의 농도 변화 및 완충 기체의 종류에 따른 최대 출력 에너지 및 최대 효율 조건을 조사하였다. 최대 레이저 펄스 에너지는 Ne 완충기체를 사용시 230mJ이며, 단위 방전 체적당 1.1 J/l의 에너지를 얻었으며, 최대 에너지 효율은 1.6%이었다. 1:3의 낮은 비율의 피-킹 캐패시턴스의 구성에 의해 레이저 펄스폭은 장펄스 효과를 나타내 foot-to-foot 200 ns로 측정되었다.

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증속기어 모듈을 이용한 발판형 에너지 하베스터의 설계 및 제작 (Design and Fabrication of Scaffold Type Energy Harvester Using Multiplying Gear Module)

  • 민철홍;김태선
    • 한국전기전자재료학회논문지
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    • 제27권12호
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    • pp.857-862
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    • 2014
  • In this paper, we designed and fabricated electromagnetic induction based scaffold type energy harvester. For energy harvesting, mechanical energy of vertical motion is transferred to rotational energy using rack gear and multiplying gear was used to maximize energy transfer. To optimize design parameters, physical structure of energy harvester was modeled using finite element method. The effect of multiplying gear ratio and frequency levels of applied mechanical energy on energy generation efficiency are analyzed by computer simulation and experimental test. Experimental results showed that maximum 25.36 W of electric power can be achieved at the frequency of 2 Hz and 1:77 of gear ratio with only 5 mm of vertical changes on scaffold structure.

Experimental investigation on heat transfer of nitrogen flowing in a circular tube

  • Chenglong Wang;Yuliang Fang;Wenxi Tian;Guanghui Su;Suizheng Qiu
    • Nuclear Engineering and Technology
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    • 제56권2호
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    • pp.463-471
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    • 2024
  • Average and local convective heat transfer coefficients of nitrogen are measured experimentally in an electrically heated circular tube for a range of Reynolds number from 1.08 × 104 to 3.60 × 104, and wall-to-bulk temperature ratio from 1.01 to 1.77. The exit Mach number is up to 0.17, and the heat flux is up to 46 kW·m-2. The molybdenum test section has a 62 diameters heated section with an inside diameter of 5 mm and a 30 diameters entrance section to ensure the fully-developed flow. Uncertainty of Nusselt number is less than 1.6 % in this study. The results indicate that the average heat transfer correlations evaluated by both the bulk and the modified film Reynolds numbers agree well with the experimental data. The local heat transfer results based on bulk properties are compared with previous empirical correlations. New prediction correlations are recommended which are significantly affected by the property variation and heated length. The comparison between the proposed correlations and experimental points shows that 88 % of experimental data fall into an error of 10 %, and almost all data are within an error of 20 %.

루프 써모사이폰에서 작동유체 충액률과 열유속이 열전달계수의 상관식에 미치는 영향 (Effects of Working Fluid Filling Ratio and Heat flux on Correlations of Heat Transfer Coefficient in Loop Thermosyphon)

  • 장기창;이기우;이영수;유성연
    • 설비공학논문집
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    • 제13권6호
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    • pp.462-473
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    • 2001
  • Due to the coupling between momentum and energy transport theoretical analysis of the loop performance is very complicate, therefore it is necessary that these problems be solved by experimental investigation before applying th loop thermosyphon to heat exchanger design. The evaporator and condenser of the loop thermosyphon were made of carbon-steel, and distilled water was used as working fluid in the experiments. From the experimental data correlations of heat transfer coefficient for evaporator and condenser sections were obtained. For heat fluxes in th range of 13~78kW/$m^2$, the correlation equations of heat transfer coefficients in evaporator and condenser predict the experimental behavior to within $\p$\pm$5% and\;\pm20$% respectively.

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DNA Mediated Energy Transfer from 4',6-Diamidino-2-phenylindole to tetra- and bis-cationic Porphyrins at Low Binding Densities

  • Gong, Lindan;Ryu, Jae-Ki;Kim, Bok-Jo;Jang, Yoon-Jung
    • Bulletin of the Korean Chemical Society
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    • 제33권2호
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    • pp.529-534
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    • 2012
  • The fluorescence of 4',6-diamidino-2-phenylindole (DAPI) bound to DNA at a [DAPI]/[DNA base] ratio of 0.005 was quenched by meso-tetrakis(N-methylpyridinium-4-yl)porphyrin (TMPyP) or cis-bis(N-methylpyridinium-4-yl)porphyrin (BMPyP) when both DAPI and either porphyrin spontaneously bound to the same DNA strand. The quenching was investigated using the "one-dimensional inner sphere" and the "F$\ddot{o}$rster resonance energy transfer" (FRET) models. Total quenching occurred when DAPI and TMPyP were up to 19.3 base pairs or $66\AA$ apart. BMPyP could quench the fluorescence up to 13.9 base pairs or $47\AA$. TMPyP, which intercalated between the DNA base-pairs, appeared to be a better acceptor than BMPyP, which stacked along the DNA stem. The higher quenching and higher resonance energy transfer efficiency of TMPyP was due to the larger overlap integral between its absorption spectrum and the emission spectrum of DNA-bound DAPI.

음향장 내의 상변화 열전달 촉진에 관한 연구 (A Study on the Enhancement of Phase Change Heat Transfer in Acoustic Fields)

  • 양호동;나기대;오율권
    • 에너지공학
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    • 제13권2호
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    • pp.152-160
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    • 2004
  • The present study investigates on the experimental and numerical results of heat transfer in the acoustic fields induced by ultrasonic waves. The strong upwards flow which moves from the bottom surface in a cavity to the free surface called as "acoustic streaming" was visualized by a particle image velocimetry (PIV). In addition, the augmentation ratio of heat transfer was experimentally investigated in the presence of acoustic streaming and was compared with the profiles of acoustic pressure calculated by the numerical analysis. A coupled finite element-boundary element method (FE-BEM) was applied for a numerical analysis. The results of experimental and numerical studies clearly show that acoustic pressure variations caused by ultrasonic waves in a medium are closely related to the augmentation of heat transfer.

흡수식 냉동기 고온재생기 내의 가스복사체 열전달 특성에 관한 연구 (A study on the heat transfer characteristics of gas-radiative medium into a high temperature generator of an absorption refrigerator)

  • 정대인;김용모;배석태
    • 태양에너지
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    • 제18권1호
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    • pp.81-89
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    • 1998
  • In this paper an experimental was done to design combustion chambers which is required radiation strength of high temperature generator of absorption rigerator. Partiqularly, in combustion chamber radiative mediums were set and basic experiments were done according to its size by radiation strength and effects of heat transfer promotion. The results are as follows : 1) When radiative mediums were set in small combustion furnace burning nonframely radiative heat transfer was effected. 2) In case that area ratio($A/A_o$) of radiative medium is 0.82 or over, temperature fluctuation effects of furnace inside were not nearly. 3) In experimental boundary heat transfer effects were 1.8 times by setting up radiative medium. Specially, $q/{\Delta}T$ values of furnace inside were uniformed nearly by setting up radiative mediums.

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상변화물질의 대류유동 및 열전달 현상에 관한 연구 (Study of Convective Flow and Heat Transfer Phenomena in the Phase Change Material)

  • 손상석;이채문;이재헌;임장순
    • 태양에너지
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    • 제6권2호
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    • pp.43-53
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    • 1986
  • The objective of this study is to report on the characterics of convective flow and heat transfer during metling process in order to provide design information for thermal energy storage systems which use phase change material. In present study, flow and heat transfer characteristics of the Phase Change Material in the Open Top Model (O.T.M) and in the Closed Top Model (C.T.M) were studied numerically by the control volume formulation using the algebraic non-orthogonal coordinate transformation. For the calculation procedure, the physical properties of fluid are assumed to be constant except density which is linely dependent on temperature in the bouyancy term of momentum equations. At start of melting process, the thickness of melting layer is assumed from the Stefan Problem assumption. The heat transfer results of Open Top Model and Closed Top Model are compared with the parameters of Grashof number and aspect ratio. It was found that heat transfer phenomena in melted region was greatly affected by buoyancy-driven natural convection and the melting distance of Open Top Model at the upper region is greater than that of Closed Top Model.

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