• Title/Summary/Keyword: Energy stability

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Deaggregation and Ultradispersion of Detonation Nanodiamonds in Polar Solvent Using Physicochemical Treatments (물리화학적 처리를 통한 극성 용매 내 나노다이아몬드의 탈응집 및 분산성 향상 연구)

  • Kim, Changkyu;Lee, Gyoung-Ja;Rhee, Changkyu
    • Journal of Powder Materials
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    • v.20 no.6
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    • pp.479-486
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    • 2013
  • In the present work, physicochemical treatments were introduced for de-aggregation and stable dispersion of detonation nanodiamonds (DND) in polar solvents. The DNDs in water exhibited a particle size of 138 nm and high dispersion stability without particular treatment. However, the DNDs in ethanol were severely aggregated to several micrometers in size and showed poor dispersion stability with time. To break down aggregates of DNDs and enhance the dispersion stability of them in ethanol, mechanical force and chemical surfactant were introduced as functions of zirconia ball size, kind of surfactant and amount of surfactant added. From the analyses of average particle size and Turbiscan results, it was suggested that the size of DNDs in ethanol can be reduced by only mechanical force; however, the DNDs were re-aggregated due to high surface activity. The long-term dispersion stability can be achieved by applying mechanical force to break down the aggregates of DNDs and by preventing re-aggregation of them using proper surfactant.

Hydrocarbon-Organic Composite Membranes for Improved Oxidative Stability for PEMFC Applications (연료전지용 탄화수소 전해질 막의 산화안정성 향상을 위한 유기물 복합막의 제조 및 특성 분석)

  • Park, Satbyul;Lee, Hyejin;Bae, Byungchan
    • Journal of the Korean Electrochemical Society
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    • v.19 no.2
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    • pp.45-49
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    • 2016
  • In order to mitigate oxidative degradation of polymer membrane during fuel cell operation, an organic radical quencher was introduced. Rutin was selected as a radical quencher and mixed with sulfonated poly(arylene ether sulfone) to prepare composite membrane. Physicochemical properties of the composite membranes such as water uptake and proton conductivity were characterized. Hydrogen peroxide exposure experiment, which can mimic accelerated oxidative stability test during fuel cell operation, was adopted to evaluate the oxidative stability of the membranes. The composite membranes containing Rutin showed similar proton conductivity and enhanced oxidative stability compared to pristine ones.

Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • v.15 no.3
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

Efficient routing in multicast mesh by using forwarding nodes and weighted cost function

  • Vyas, Kapila;Khuteta, Ajay;Chaturvedi, Amit
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.12
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    • pp.5928-5947
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    • 2019
  • Multicast Mesh based Mobile Ad-hoc NETworks (MANETs) provide efficient data transmission in energy restraint areas without a fixed infrastructure. In this paper, the authors present an improved version of protocol SLIMMER developed by them earlier, and name it SLIMMER-SN. Most mesh-based protocols suffer from redundancy; however, the proposed protocol controls redundancy through the concept of forwarding nodes. The proposed protocol uses remaining energy of a node to decide its energy efficiency. For measuring stability, a new metric called Stability of Node (SN) has been introduced which depends on transmission range, node density and node velocity. For data transfer, a weighted cost function selects the most energy efficient nodes / most stable nodes or a weighted combination of both. This makes the node selection criteria more dynamic. The protocol works in two steps: (1) calculating SN and (2) using SN value in the weighted cost function for selection of nodes. The study compared the proposed protocol, with other mesh-based protocols PUMA and SLIMMER, based on packet delivery ratio (PDR), throughput, end-to-end delay and average energy consumption under different simulation conditions. Results clearly demonstrate that SLIMMER-SN outperformed both PUMA and SLIMMER.

A New Stabilizing Method for Transiently Unstable Systems by Using Transient Energy Function (에너지함수를 이용한 과도불안정 시스템의 안정화 방법)

  • Kim, Jung-Woo;Chun, Yeong-Han
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.4
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    • pp.567-575
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    • 2008
  • Transient security assessment(TSA) is becoming an essential requirement not only for security monitoring but also for stabilizing control of power systems under new electricity environments. It has already been pointed out that fast transient stability study is an important part for monitoring and controlling system security. In this paper, we discuss an energy function method for stabilizing control of transiently unstable systems by introducing generator tripping system to enhance the transient stability of power systems. The stabilization with less tripped power can be obtained by tripping the generators faster than out-of-synchronism relay. Fast transient stability assessment based on the state estimation and direct transient energy function method is an important part of the stabilizing scheme. It is possible to stabilize the transiently unstable system by tripping less generators before the action of out-of-synchronism relay, especially when a group of generator are going to be out-of-synchronism. Moreover, the amount of generator output needed for tripping can be decided by Transient Energy Function(TEF) method. The main contribution of this paper is on the stabilizing scheme which can be running in the Wide Area Control System.

Redox Stability and Electrochemical Performances of La0.6Sr0.4Fe1-xScxO3-δ for Solid Oxide Cells Interconnector (고체산화물전지 접속자용 La0.6Sr0.4Fe1-xScxO3-δ의 상 안정성 및 전기화학 성능)

  • KWAK, MINJUN;CHOI, HYUN-JONG;KIM, TAE WOO;SEO, DOO-WON;WOO, SANG-KUK;KIM, SUN-DONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.3
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    • pp.274-279
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    • 2018
  • Sc-substituted $La_{0.6}Sr_{0.4}FeO_{3-{\delta}}$(LSFSc) has synthesized for ceramic interconnector of tubular solid oxide cells (SOCs). For improving the redox stability and electric conductivity of LSFSc, the compositions of Sc, pH value of mixed precursors, calcination temperature and times were optimizing. The electrochemical performances of $La_{0.6}Sr_{0.4}Fe_{1-x}Sc_xO_{3-{\delta}}$ powders were measured as depending on Sc composition. The electric conductivity and redox stability of $La_{0.6}Sr_{0.4}Fe_{1-x}Sc_xO_{3-{\delta}}$ was determined by Sc concentration. $La_{0.6}Sr_{0.4}Fe_{0.9}Sc_{0.1}O_{3-{\delta}}$ powders can be one of the stable composition for ceramic interconnector of tubular-SOCs.

Analyses on Thermal Stability and Structural Integrity of the Improved Disposal Systems for Spent Nuclear Fuels in Korea

  • Lee, Jongyoul;Kim, Hyeona;Kim, Inyoung;Choi, Heuijoo;Cho, Dongkeun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.spc
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    • pp.21-36
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    • 2020
  • With respect to spent nuclear fuels, disposal containers and bentonite buffer blocks in deep geological disposal systems are the primary engineered barrier elements that are required to isolate radioactive toxicity for a long period of time and delay the leakage of radio nuclides such that they do not affect human and natural environments. Therefore, the thermal stability of the bentonite buffer and structural integrity of the disposal container are essential factors for maintaining the safety of a deep geological disposal system. The most important requirement in the design of such a system involves ensuring that the temperature of the buffer does not exceed 100℃ because of the decay heat emitted from high-level wastes loaded in the disposal container. In addition, the disposal containers should maintain structural integrity under loads, such as hydraulic pressure, at an underground depth of 500 m and swelling pressure of the bentonite buffer. In this study, we analyzed the thermal stability and structural integrity in a deep geological disposal environment of the improved deep geological disposal systems for domestic light-water and heavy-water reactor types of spent nuclear fuels, which were considered to be subject to direct disposal. The results of the thermal stability and structural integrity assessments indicated that the improved disposal systems for each type of spent nuclear fuel satisfied the temperature limit requirement (< 100℃) of the disposal system, and the disposal containers were observed to maintain their integrity with a safety ratio of 2.0 or higher in the environment of deep disposal.

Correlation of the Green Microstructure of ZrO2 with the Colloid/Interface Variables (Zirconia성형체의 미세구조와 콜로이드/계면변수와의 상관관계에 대한 분석)

  • 장현명;한규호;이기강;정한남
    • Journal of the Korean Ceramic Society
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    • v.27 no.1
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    • pp.91-101
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    • 1990
  • The green microstructure and sintering behavior of ZrO2 were analyzed in terms of kinetic stability (measured by the stability ratio ; W) and interfacial characteristics of colloidal suspension. Green density and the most frequent pore radius(MFPR) of green body were directly correlated with the stability ratio. These observations were explained using a concept of the critical stability ratio(Wc) and the potential energy of two interacting particles in colloidal suspension. Analysis of the data also indicates that the potential energy barrier between two interacting colloid particles should be higher than its critical value for a fabrication of ZrO2 green body with dense and uniform microstructure. Besides, we have successfully applied a concept of the donoracceptor interaction to increase the kinetic stability of ZrO2 slip and density of green body.

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A Study on the identical basis of static voltage stability analysis methods in power systems (전력 계통 정적 전압 안정도 해석법의 동일 근거에 관한 연구)

  • Moon, Young-Hyun;Kim, Baik;Lee, Eung-Hyuk
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.4
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    • pp.457-466
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    • 1996
  • The Voltage stability problem has recently been dealt with in the literature from various points of view. The diverse theories have been established in voltage stability analysis because of the complicates of power systems and diverse phenomena of voltage collapse. Through rigorous mathematical operations, this paper shows that all the major methods used in static voltage stability, i.e - Jacobian method, voltage sensitivity method, real and reactive power loss sensitivity method and energy function method - have an identical background in theory. The results from the test in sample systems have shown the validity of this verification. (author). refs., figs., tabs.

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Improved Thermal Stability of Ag Nanowire Heaters with ZnO Layer (ZnO를 이용한 은 나노와이어 히터의 열 안정성 향상)

  • Choi, Wonjung;Jo, Sungjin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.8
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    • pp.530-534
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    • 2017
  • Transparent film heaters employing silver nanowires (Ag NWs) have attracted increasing attention because of their widespread applications. However, the low thermal resistance of Ag NWs limits the maximum operating temperature of the Ag NW film heater. In this study, Ag NW film heaters with high mechanical and thermal stability were successfully developed. The thermal power-out characteristics of the Ag NW heaters were investigated as a function of the Ag NW density. The results revealed that the prepared flexible Ag NW heater possessed high thermal stability over $190^{\circ}C$ owing to ZnO encapsulation. This indicates that the Ag NW film with excellent thermal stability have remarkably high potential for use as electrodes in film heaters operating at high temperatures.