• Title/Summary/Keyword: Energy distribution

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Surface Properties of Glutathione Layer Formed on Gold Surfaces Interacting with ZrO2 (이산화지르코늄과 상호작용하는 금 표면 위의 글루타싸이온층 표면 물성)

  • Park, Jin-Won
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.538-543
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    • 2014
  • It is investigated that that the physical properties of Glutathione layer formed on gold surfaces may make an effect on the distribution of either gold particle adsorbed to the $ZrO_2$ surface or vice versa with the adjustment of the electrostatic interactions. For the investigation, the atomic force microscope (AFM) was used to measure the surface forces between the surfaces as a function of the salt concentration and pH value. The forces were quantitatively analyzed with the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory to estimate the surface potential and charge density of the surfaces for each condition of salt concentration and pH value. The estimated-value dependence on the salt concentration was described with the law of mass action, and the pH dependence was explained with the ionizable groups on the surface. The salt concentration dependence of the surface properties, found from the measurement at pH 4 and 8, was consistent with the prediction from the law. It was found that the Glutathione layer had higher values for the surface charge densities and potentials than the zirconium dioxide surfaces at pH 4 and 8, which may be attributed to the ionized-functional-groups of the Glutathione layer.

A Study on Complementarity of Green Growth (녹색성장의 상보성에 관한 연구)

  • PARK, Seong-Kwae
    • Journal of Fisheries and Marine Sciences Education
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    • v.21 no.2
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    • pp.306-324
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    • 2009
  • The purpose of this study is to analyze green growth issues such as employment, education and training, social capital and nature's standing right from the complementary perspective between natural environment conservation and economic growth. Green growth can be defined as a growth which lowers an increasing rate of entropy and at the same time improves our living standard. Green growth paradigm requires a quite amount of understanding the laws of thermodynamics and the uncertainty principle as the highest orders which regulate our overall socio-economic behaviors. They suggest that socio-economic growth is a mere transformation process of natural energy from one form to another and they increases natural manmade entropy over time. The most important issue of green growth policy may be a problem concerning employment and/or unemployment since green growth may induce inevitable movement of resources from the existing industries to the green sector. In particular, green industries will demand more highly specialized manpower than the existing ones. Without a well-designed new training education system and social capital accumulation toward environmental concerns, green growth may accompany a substantial amount of structural involuntary frictional unemployment. This may increase not only wealth-distribution disparity but also political instability. In order to achieve harmonious green growth, we should recognize that there are important complementary relationships between green and growth. Our society should also be able to innovate the existing educational system to accumulate social capital, to create a new sharing system, and to admit nature's standing right. Although the 2003 lawsuit case of Korean Salamander in Cheonseong Mountain went against plaintiff, it would provide apparently our society with a way of green development ahead.

Relationship between Adaptation Luminance and Threshold Zone Luminance for Vehicular Traffic Tunnels (터널 순응휘도와 경계부 휘도의 관계 연구)

  • Cho, Won Bum;Jeong, Jun Hwa
    • International Journal of Highway Engineering
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    • v.16 no.3
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    • pp.85-99
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    • 2014
  • PURPOSES : This study has been performed with the objective to determine threshold zone luminance of adaptation luminance by target safety level in a vehicular traffic tunnel with design speed set at 100km/h. METHODS : The study made a miniature capable of portraying changes in luminance distribution within $2{\times}10^{\circ}$ conical field of view of the driver approaching to the tunnel for the test. Test conditions were set based on justifications for CIE 88-1990's threshold zone luminance used as a reference by domestic tunnel light standards (KS C 3703 : 2010). Luminance contrast of object background and object is 23%, object presentation duration is 0.5 seconds, and size of the object background is $7.3{\times}11.5m^2$ RESULTS : Threshold zone luminance was set within adaptation luminance of $100{\sim}3,000cd/m^2$. Adaptation luminance and threshold zone luminance based on 50%, 75% and 90% target safety level all showed a relatively high linear relationship. According to findings in the study, it is not appropriate to specify the relationship between adaptation luminance and threshold zone luminance as luminance ratio. Rather, direct utilization of the linear relationship gained from the study findings appears to be the better solution. CONCLUSIONS : Findings of this study may be used to determine operation of threshold zone luminance based on target safety level. However, a proper verification and validity of test results are required. Furthermore, a study to determine proper threshold zone luminance level considering target safety level reviewed in this study and various decision-making factors such as economic conditions in Korea and energy-related policies should be carried out in addition. Additional tests on adaptation luminance greater than $3,000cd/m^2$ will be performed, through which application scope of the test findings will be broadened.

The Influence of W Addition on Cube Textured Ni Substrates for YBCO Coated Conductor (양축 정렬된 Ni 기판의 특성에 미치는 W 첨가의 효과)

  • Kim Kyu Tae;Lim Jun Hyung;Kim Jung Ho;Jang Seok Hern;Kim Ho-Jin;Joo Jinho;Kim Chan-Joong;Song Kyu Jung;Shin Hyung Sub
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.64-68
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    • 2004
  • We fabricated cube-textured Ni and Ni-W alloy substrates for coated conductors and characterized the effects of W addition on microstructure, mechanical strength, and magnetic properties of the substrate. Pure Ni and Ni-(2, 3, 5at.%)W alloys were prepared by plasma arc melting, heavily cold rolled and then annealed at various temperatures of $600-1300^{\circ}C$. The texture was evaluated by pole-figure and orientation distribution function (ODF) analysis. Mechanical properties were investigated by micro Vickers hardness and tension test. Ferromagnetism of the substrate was measured by physical property measurement system (PPMS). It was observed that Ni-W substrates had sharp cube texture, and the full-width at half-maximums (FWHMs) of in-plane texture was $^{\circ}$-5.57$4.42^{\circ}$, which is better than that of pure Ni substrate. In addition cube texture of Ni-W substrates was retained at higher temperature up to $1300^{\circ}C$. Microstructural observation showed that the Ni-W substrates had fine grain size and higher mechanical properties than the pure Ni substrate. These improvements are probably due to strengthening mechanisms such as solid solution hardening and/or grain size strengthening. PPMS analysis showed that addition of W effectively reduced saturation magnetization in applied magnetic field and Curie temperature.

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New Approach to Air Quality Management (대기오염관리의 새로운 접근방법)

  • 윤명조
    • Journal of environmental and Sanitary engineering
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    • v.8 no.2
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    • pp.25-48
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    • 1993
  • International concern over the environmental pollution is ever increasing, and diversified countermeasures must be devised in Korea also. Global trend, damages, problems and countermeasures with respect to issues mentioned in the Rio Declaration, such as prevention of ozone layer destruction, reduction of migratory atmospheric pollution between neighboring countries, and prevention of global greenhouse effect, were discussed in this report. Conclusion of the report is summarized as follows : A. Measurement, Planning and Monitoring (1) Development and implementation of a global network for measurement and monitoring from the global aspects such factors as related to acid rain(Pioneer substances, pH, sulfate, nitrate), effect of global temperature(Air temperature, $CO_2$, $CH_4$, CFC, $N_2O$) and destruction of ozone layer($CFC_S$). (2) Establishment of network system via satellite monitoring movement of regional air mass, damage on the ozone layer and ground temperature distribution. B. Elucidation of Present State (1) Improvement and development of devices for carbon circulation capable of accurately forecasting input and output of carbon. (2) Developmental research on chemical reactions of greenhouse gas in the air. (3) Improvement and development of global circulation model(GCM) C. Impact Assessment Impact assessment on ecosystem, human body, agriculture, floodgate, land use, coastal ecology, industries, etc. D. Preventive Measures and Technology Development (1) Development and consumption of new energy (2) Development of new technology for removal of pioneer substances (3) Development of substitute matter for $CFC_S$ (4) Improvement of agriculture and forestry means to prevent the destruction of ozone layer and the greenhouse effect of the globe (5) Improvement of housing to prevent the destruction of ozone layer and the greenhouse effect of the globe (6) Development of new technology for probing underground water (7) Preservation of forest (8) Biomass 5. Policy Development (1) Development of strategy model (2) Development of long term forecast model (3) Development of penalty charge effect and expense evaluation methods (4) Feasibility study on regulations By establishing the above mentioned measures for environmentally sound and sustainable development to establish the right to live for humankind and to preserve the one and only earth.

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A Study on Effective Energy Use of the Open Type Ground Heat Exchanger Using Underground Temperature Gradient (지중온도 경사를 이용한 효율적 지중에너지 이용 방안에 관한 연구)

  • Ryu, Hyungkyou;Chung, Minho;Lee, Byungseok;Rhew, Hyojun;Choi, Hyunjun;Choi, Hangseok
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.9
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    • pp.401-408
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    • 2014
  • This paper proposes an optimum operation method for open type ground heat exchangers. A series of TRTs and artificial heating/cooling operations were carried out while monitoring temperature in the hole of SCW. The ground temperature naturally increases with depth, but a switch between the cooling/heating mode results in a change in the distribution of ground temperature. The effect of the mode change was evaluated by performing LMTD and COMSOL multiphysics analysis for a reduced model with the depth of 150 m. As a result, in the cooling mode, the upstream operation is more efficient than the downstream operation and reduces EWT by $2.26^{\circ}C$. On the other hand, in the heating mode, the downstream operation is advantageous over the upstream operation and increases EWT by $3.19^{\circ}C$. The merit of the optimum operation will be enhanced for the typical dimension of SCW with a depth of 400~500 m. In the future, an open type ground heat exchanger system adopting the optimum operation with variation in the ground temperature will be used in practice.

The Study of Optimized Combustion Tuning for Fossil Power Plant (발전보일러의 최적연소조정에 대한 실험적 연구)

  • Jung, Jae-Jin;Song, Jung-Il
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.102-108
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    • 2009
  • Fossil power plants firing lower grade coals or equipped with modified system for NOx controls are challenged with maintaining good combustion conditions while maximizing generation and minimizing emissions. In many cases significant derate, availability losses and increase in unburned carbon levels can be attributed to poor combustion conditions as a result of poorly controlled local fuel and air distribution within the boiler furnace. In order to develop a on-line combustion tuning system, field test was conducted at operating power boiler. During the field test the exhaust gases' $O_2$, NOx and CO was monitored by using a spatially distributed monitoring grid located in the boiler's high temperature vestibule and upper convective back-pass region. At these locations, the flue gas flow is still significantly stratified, and air in-leakage is minimal which enables tracing of poor combustion zones to specific burners and over-fire air ports. using these monitored information we can improving combustion at every point within the furnace, therefore the boiler can operate at reduced excess $O_2$ and gas temperature deviation, reduced furnace exit gas temperature levels while also reducing localized hot spots, corrosive gas conditions, slag or clinker formation and UBC. Benefits include improving efficiency, reducing NOx emissions, increasing output and maximizing availability. Discussion concerning the reduction of greenhouse gases is prevalent in the world. When taking a practical approach to addressing this problem, the best way and short-term solution to reduce greenhouse gases on coal-fired power plants is to improve efficiency. From this point of view the real time optimized combustion tuning approach is the most effective and implemented with minimal cost.

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Gamma Radiation Shielding Effect of Various Heavy Concretes Using Domestic Mineral Aggregates

  • Lim, Yong-Kyu
    • Nuclear Engineering and Technology
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    • v.2 no.3
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    • pp.149-161
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    • 1970
  • This paper describes a detailed investigational performance on the gamma radiation shield effect of heavy concretes that were manufactured by the use of mineral ores produced domestically and which may be possibly applied for the biological shield design. Ten different kinds of mineral ores were collected for use as the aggregates, physical test and chemical analysis for them were carried out to select the aggregate with a better property. Through the experimental investigation on the shielding effect of various concretes with different combination of concrete components such as water-cement and fine-coarse aggregate ratios, it was possible to derive some criteria for the best condition being capable of obtaining the concretes with high density and good uniformity. Data on the shielding-effectiveness of the different concretes were obtained by performing collimated beam experiment using 60Co gamma-ray. Analyzing the shielding-efficiency, shielding-concrete specific gravity and biological shield cost, the optimum condition of yielding the best economic shielding design, with low cost and good spatial distribution to some extent was determined.

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Laboratory Tests of Chromium-51 Complexes for teak Detection in Pipes Carrying A Liquid Flow

  • Kim, You-Sun;Lee, Byung-Hyun
    • Nuclear Engineering and Technology
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    • v.6 no.4
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    • pp.231-237
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    • 1974
  • For detection and localization of leaks in closed vessels or pipes carrying liquid flow, $^{51}$ Cr-EDTA and $^{51}$ Cr-DTPA were synthesized and, the column and batch equilibrium experiments were carried out. In the column experiment, the recovery of $^{51}$ Cr-EDTA is 100% in quartz sand and 80.9% in steel sawdust, and that of $^{51}$ Cr-DTPA is 77.4% in quartz sand and 6.4% in steel sawdust. The recovery curve. $^{51}$ Cr-DTPA system in steel sawdust does not show a certain plateau, exceptionally. In general, $^{51}$ Cr-EDTA is adsorbed less than $^{51}$ Cr-DTPA. In the batch equilibrium experiment, the distribution coefficients (Kd) and effect of pH were investigated by using quartz sand, montmorillonite, steel sawdust, and mixed cement raw material as media. In general, the Kd values for $^{51}$ Cr-EDTA are lower than that of $^{51}$ Cr-DTPA. The Kd values for $^{51}$ Cr-EDTA are almost zero at pH 6.0, 7.0, and 8.0.

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Study of the Librational Motion of $H_2$O Molecules in Hydrates by Neutron Inelastic Scattering

  • Kim, Huhn-Jun;Yoon, Byung-Gook
    • Nuclear Engineering and Technology
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    • v.11 no.1
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    • pp.1-20
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    • 1979
  • Neutron inelastic scattering studies on polycrystalline hydrates, NaBr-2$H_2O$ and BaCl$_2$-2$H_2O$ have been performed to observe librational modes. Assuming all observed peaks are from the $H_2O$ librational origin, the weighted frequency distribution functions are obtained by eliminating the contributions from the higher order processes. All of theoretical frequencies obtained using FG matrix method are dus to highly mixed modes, and therefore the modes identified as significant $H_2O$ librationat modes from their large potential energy distributions are assigned to the observed peaks. The H-bond interactions are estimated using a modified Lippincott Schroeder potential function, and the applicability of the potential function to the H-bond with highly bent or bifurcated configuration is examined on the basis of the shape of $H_2O$ librational potential energies. Some discussions are given on the usefulness of introducing O-H…Y bending terms in addition to the H…Y stretching in similar frequency calculation in order to obtain more information on the nature of H-bond. Also the purity and symmetry properties of the $H_2O$ librational modes are discussed using group theoretical analyses.

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