• Title/Summary/Keyword: Energy Materials

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A Comparison Study of Output Performance of Organic-Inorganic Piezoelectric Nanocomposite Made of Piezoelectric/Non-piezoelectric Polymers and BaTiO3 Nanoparticles (압전 및 비압전 폴리머와 BaTiO3 나노입자로 제조된 유-무기 압전 나노복합체의 발전성능 비교연구)

  • Hyeon, Dong Yeol;Park, Kwi-Il
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.119-125
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    • 2019
  • Piezoelectric energy harvesting technology is attracting attention, as it can be used to convert more accessible mechanical energy resources to periodic electricity. Recent developments in the field of piezoelectric energy harvesters (PEHs) are associated with nanocomposites made from inorganic piezoelectric nanomaterials and organic elastomers. Here, we used the $BaTiO_3$ nanoparticles and piezoelectric poly(vinylidene fluoride) (PVDF) polymeric matrix to fabricate the nanocomposites-based PEH to improve the output performance of PEHs. The piezoelectric nanocomposite is produced by dispersing the inorganic piezo-ceramic nanoparticles inside an organic piezo-polymer and subsequently spin-coat it onto a metal plate. The fabricated organic-inorganic piezoelectric nanocomposite-based PEH harvested the output voltage of ~1.5 V and current signals of ~90 nA under repeated mechanical pushings: these values are compared to those of energy devices made from non-piezoelectric polydimethylsiloxane (PDMS) elastomers and supported by a multiphysics simulation software.

Effect of C, Mn and Al Additions on Tensile and Charpy Impact Properties of Austenitic High-manganese Steels for Cryogenic Applications (극저온용 오스테나이트계 고망간강의 인장 및 충격 특성에 미치는 C, Mn, Al 첨가의 영향)

  • Lee, Seung-Wan;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.189-195
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    • 2019
  • The effect of C, Mn, and Al additions on the tensile and Charpy impact properties of austenitic high-manganese steels for cryogenic applications is investigated in terms of the deformation mechanism dependent on stacking fault energy and austenite stability. The addition of the alloying elements usually increases the stacking fault energy, which is calculated using a modified thermodynamic model. Although the yield strength of austenitic high-manganese steels is increased by the addition of the alloying elements, the tensile strength is significantly affected by the deformation mechanism associated with stacking fault energy because of grain size refinement caused by deformation twinning and mobile dislocations generated during deformation-induced martensite transformation. None of the austenitic high-manganese steels exhibit clear ductile-brittle transition behavior, but their absorbed energy gradually decreases with lowering test temperature, regardless of the alloying elements. However, the combined addition of Mn and Al to the austenitic high-manganese steels suppresses the decrease in absorbed energy with a decreasing temperature by enhancing austenite stability.

Recent Advances on Multi-Dimensional Nanocarbons for Superapacitors: A Review

  • Bae, Joonho
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.251-259
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    • 2018
  • In general, the charge storage characteristics and overall performance of electrochemical energy devices (such as lithiumion batteries and supercapacitors) significantly depends on the structural and geometrical factors of the electrodes' active materials. The most widely used active materials of electrochemical energy storage devices are based on carbons of various forms. Each carbon type has drawbacks and advantages when used as the electrode material. Studies have been recently carried out to combine different types of carbons, in particular nanostructured carbons, in order to overcome the structure-originated limitations and thus enhance the overall electrochemical performances. In this feature article, we report the recent progress on the development of this novel class of materials (multidimensional nanocarbons), and their applications for supercapacitors. Multidimensional nanocarbons include graphenes/carbon nanotubes (CNTs), CNTs/carbon films, CNTs/fullerenes, and ternary carbon nanostructures. Various applications using these multidimensional nanocarbons have been proposed and demonstrated in the literature. Owing to the recent extensive studies on electrochemical energy storage devices and considering that carbons are their most fundamental electrode materials, the number of reports on nanocarbons employed as electrodes of the electrochemical energy storage devices is rapidly increasing. Recently, numerous multidimensional nanocarbons have been designed, prepared, and utilized as electrodes of electrochemical capacitors or supercapacitors, which are considered next-generation energy devices owing to their unique merits compared to the conventional structures. In this review, we summarize the basic motivations, preparation methods, and resultant supercapacitor performances of each class of multidimensional nanocarbons published in the literature, focusing on recent reports.

Determining PGAA collimator plug design using Monte Carlo simulation

  • Jalil, A.;Chetaine, A.;Amsil, H.;Embarch, K.;Benchrif, A.;Laraki, K.;Marah, H.
    • Nuclear Engineering and Technology
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    • v.53 no.3
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    • pp.942-948
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    • 2021
  • The aim of this work is to help inform the decision for choosing a convenient material for the PGAA (Prompt Gamma Activation Analysis) collimator plug to be installed at the tangential channel of the Moroccan Triga Mark II Research Reactor. Two families of materials are usually used for collimator construction: a mixture of high-density polyethylene (HDPE) with boron, which is commonly used to moderate and absorb neutrons, and heavy materials, either for gamma absorption or for fast neutron absorption. An investigation of two different collimator designs was performed using N-Particle Monte Carlo MCNP6.2 code with the ENDF/B-VII.1 and MCLIP84 libraries. For each design, carbon steel and lead materials were used separately as collimator heavy materials. The performed study focused on both the impact on neutron beam quality and the neutron-gamma background at the exit of the collimator beam tube. An analysis and assessment of the principal findings is presented in this paper, as well as recommendations.

Study on Solution-Processed Flexible Electrochromic Devices with Improved Coloration Efficiency and Stability

  • Gihwan Song;Haekyoung Kim
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.1
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    • pp.1-9
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    • 2023
  • According to the recent global warming, it is necessary to use energy efficiently together with eco-friendly energy. The development of alternative technologies is requisite for managing the current energy and climate crises. In this regard, "smart windows," which can control solar radiation, can be used to mitigate energy demands. Electrochromic devices (ECDs) effectively control the amount of solar energy reaching commercial and other living areas and maintain climate conditions via color modulation in response to small external stimuli, such as temperature and light irradiation. However, the performance and the stability of ECDs depend on the state of the electrolyte and sealing of the device. To resolve the aforementioned issues, an ECD was manufactured by using a poly (methyl methacrylate) (PMMA)-based gel polymer electrolyte (GPE), and a laminating method was used to adequately seal the ECD. The concentrations of PMMA, acetonitrile (ACN), and ferrocene (Fc) were controlled to optimize the composition of the GPE to achieve an enhanced electrochromic performance. The fabricated GPE-based ECD afforded high optical contrast (~81.92%), with high electrochromic stability up to 10,000 cycles. Moreover, the lamination method employing the GPE could be used to fabricate large-area ECDs.

Enhancing the ability of strain energy release rate criterion for fracture assessment of orthotropic materials under mixed-mode I/II loading considering the effect of crack tip damage zone

  • Khaji, Zahra;Fakoor, Mahdi
    • Steel and Composite Structures
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    • v.44 no.6
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    • pp.817-828
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    • 2022
  • In this study, considering dissipated energy in fracture process zone (FPZ), a novel criterion based on maximum strain energy release rate (SER) for orthotropic materials is presented. General case of in-plane loading for cracks along the fibers is assumed. According to the experimental observations, crack propagation is supposed along the fibers and the reinforcement isotropic solid (RIS) concept is employed as a superior model for orthotropic materials. SER in crack initiation and propagation phases is investigated. Elastic properties of FPZ are extracted as a function of undamaged matrix media and micro-crack density. This criterion meaningfully links between dissipated energy due to toughening mechanisms of FPZ and the macroscopic fracture by defining stress intensity factors of the damaged zone. These coefficients are used in equations of maximum SER criterion. The effect of crack initiation angle and the damaged zone is considered simultaneously in this criterion and mode II stress intensity factor is extracted in terms of stress intensity factors of damage zone and crack initiation angle. This criterion can evaluate the effects of FPZ on the fracture behavior of orthotropic material. Good agreement between extracted fracture limit curves (FLC's) and available experimental data proves the ability of the new proposed criterion.

On magnetostrictive materials and their use in adaptive structures

  • Dapino, Marcelo J.
    • Structural Engineering and Mechanics
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    • v.17 no.3_4
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    • pp.303-329
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    • 2004
  • Magnetostrictive materials are routinely employed as actuator and sensor elements in a wide variety of noise and vibration control problems. In infrastructural applications, other technologies such as hydraulic actuation, piezoelectric materials and more recently, magnetorheological fluids, are being favored for actuation and sensing purposes. These technologies have reached a degree of technical maturity and in some cases, cost effectiveness, which justify their broad use in infrastructural applications. Advanced civil structures present new challenges in the areas of condition monitoring and repair, reliability, and high-authority actuation which motivate the need to explore new methods and materials recently developed in the areas of materials science and transducer design. This paper provides an overview of a class of materials that because of the large force, displacement, and energy conversion effciency that it can provide is being considered in a growing number of quasistatic and dynamic applications. Since magnetostriction involves a bidirectional energy exchange between magnetic and elastic states, magnetostrictive materials provide mechanisms both for actuation and sensing. This paper provides an overview of materials, methods and applications with the goal to inspire novel solutions based on magnetostrictive materials for the design and control of advanced infrastructural systems.

Deposition of β-SiC by a LPCVD Method and the Effect of the Crystallographic Orientation on Mechanical Properties (저압 화학기상증착법을 이용한 β-SiC의 증착 및 결정 성장 방위에 따른 기계적 특성 변화)

  • Kim, Daejong;Lee, Jongmin;Kim, Weon-Ju;Yoon, Soon Gil;Park, Ji Yeon
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.43-49
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    • 2013
  • ${\beta}$-SiC was deposited onto a graphite substrate by a LPCVD method and the effect of the crystallographic orientation on mechanical properties of the deposited SiC was investigated. The deposition was performed at $1300^{\circ}C$ in a cylindrical hot-wall LPCVD system by varying the deposition pressure and total flow rate. The texture and crystallographic orientation of the SiC were evaluated by XRD. The deposition rate increased linearly with the gas flow rate from 800 sccm to 1600 sccm. It also increased with the pressure but became saturated above a total pressure of 3.3 kPa. In the range of 3.3 - 10 kPa, the preferred orientation changed from the (220) and (311) planes to the (111) plane. The hardness and elastic modulus showed maximum values when the SiC had the (111) preferred orientation, though it gradually decreased upon a change to the (220) and (311) preferred orientations.

Improved methods for the preparation of $(Y_{1-x}Eu_x)_2O_3$:MX and $(Y_{1-x-y}Gd_xEu_y)_2O_3$:MX as red phosphor materials

  • Lee, You-Hui;Han, Sang-Do;Kim, Jung-Duk;Chang, Mi-Yeon;Singh, Ishwar.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.715-718
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    • 2004
  • Substantially improved methods for the preparation of europium-doped yttrium oxide red phosphor with the inclusion of alkali metal halides having a general formula $(Y_{1-x}Eu_x)_2O_3$:MX where 0.025${\leq}$x${\leq}$0.2 and MX is alkali halide in the mole ratio 0.025 to 0.6, more preferably between 0.05 to 0.2 mole, are reported. Another series of the red phosphor materials with general formula $(Y_{1-x-y}Gd_xEu_y)_2O_3$:MX where 0.05${\leq}$x${\leq}$0.40 and 0.025${\leq}$y${\leq}$0.20 and MX is alkali halide in the mole ratio 0.025 to 0.5, more preferably between 0.1 to 0.2 mole, has also been presented. The inclusion of alkali halide greatly increase the luminance of the materials. The materials are very soft with fine particle size less than 100nm. The phosphorescent materials have good luminance in VUV region.

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Microstructure and Hardness Changes of the CVD-ZrC Film with Different Deposition Temperature (증착온도 변화에 따른 화학증착 ZrC의 미세구조와 경도 변화)

  • Park, Jong-Hoon;Jung, Choong-Hwan;Kim, Weon-Ju;Kim, Do-Jin;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.567-571
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    • 2008
  • The properties of a grown film by the chemical vapor deposition process depend on the deposition temperature because the deposition mechanism of the CVD film is controlled by the deposition temperature. The preferred orientation of the zrC film changed from (111) to (220) or (200) with an increase of the deposition temperature. The grain size of the ZrC film changes from $0.8{\mu}m$ to $2.5{\mu}m$ in the range of 1350 to $1500^{\circ}C$. The hardness of the deposited ZrC film depended on the preferred orientation and the grain size. The hardness of the ZrC film deposited at $1400^{\circ}C$ was 31 GPa.