• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.183-187
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• 2009

The structure of nano-crystalline $MnFe_2O_4$ was determined and refined with electron powder diffraction data employing the Rietveld refinement technique. A nano-crystalline sample (with average crystal size of about 10.9 nm) was characterized by selected area electron diffraction in an energy-filtering transmission electron microscope operated at 120 kV. All reflection intensities were extracted from a digitized image plate using the program ELD and then used in the course of structure refinements employing the program FULLPROF for the Rietveld analysis. The final structure was refined in space group Fd-3m (# 227) with lattice parameters a=8.3413(7) $\AA$. The reliability factors of the refinement are $R_F$=7.98% and $R_B$=3.55%. Comparison of crystallographic data between electron powder diffraction data and reference data resulted in better agreement with ICSD-56121 rather than with ICSD-28517 which assumes an initial structure model.

• 제어로봇시스템학회:학술대회논문집
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• 1995.10a
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• pp.392-395
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• 1995

This paper presents a time efficient method for determining a sequence of locations of a mobile manipulator that facilitates tracking of continuous path in cluttered environment. Given the task trajectory in the form of octree data structure, the algorithm performs characterization of task space and subsequent multistage optimization process to determine task feasible locations of the robot. Firstly, the collision free portion of the trajectory is determined and classified according to uniqueness domains of the inverse kinematics solutions. Then by implementing the extent of task feasible subspace into an optimization criteria, a multistage optimization problem is formulated to determines the task feasible locations of the mobile manipulator. The effectiveness of the proposed method is shown through a simulation study performed for a 3-d.o.f. manipulator with generic kinematic structure.

• Carbon letters
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• v.12 no.2
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• pp.70-80
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• 2011

Two pitches with different average molecular structures were electrospun and compared in terms of the properties of their fibers after oxidative stabilization, carbonization, and activation. The precursor with a higher molecular weight and greater content of aliphatic groups (Pitch A) resulted in better solubility and spinnability compared to that with a lower molecular weight and lower aliphatic group content (Pitch B). The electrical conductivity of the carbon fiber web from Pitch A of 67 S/cm was higher than that from Pitch B of 52 S/cm. The carbon fiber web based on Pitch A was activated more readily with lower activation energy, resulting in a higher specific surface area compared to the carbon fiber based on Pitch B (Pitch A, 2053 $m^2/g$; Pitch B, 1374 $m^2/g$).

• Advances in concrete construction
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• v.12 no.5
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• pp.377-389
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• 2021

Reinforced concrete vertical silos are universal structures that store large amounts of granular materials. Due to the asymmetric structure, heavy load, uneven storage material distribution, and the difference between the storage volume and the storage material bulk density, the corresponding earthquake is very complicated. Some scholars have proposed the calculation method of horizontal forces on reinforced concrete vertical silos under the action of earthquakes. Without considering the effect of torsional effect, this article aims to reveal the expansion factor of the silo group considering the torsional effect through experiments. Through two-way seismic simulation shaking table tests on reinforced concrete column-supported group silo structures, the basic dynamic characteristics of the structure under earthquake are obtained. Taking into account the torsional response, the structure has three types of storage: empty, half and full. A comprehensive analysis of the internal force conditions under the material conditions shows that: the different positions of the group bin model are different, the side bin displacement produces a displacement difference, and a torsional effect occurs; as the mass of the material increases, the structure's natural vibration frequency decreases and the damping ratio Increase; it shows that the storage material plays a role in reducing energy consumption of the model structure, and the contribution value is related to the stiffness difference in different directions of the model itself, providing data reference for other researchers; analyzing and calculating the model stiffness and calculating the internal force of the earthquake. As the horizontal side shift increases in the later period, the torsional effect of the group silo increases, and the shear force at the bottom of the column increases. It is recommended to consider the effect of the torsional effect, and the increase factor of the torsional effect is about 1.15. It can provide a reference for the structural safety design of column-supported silos.

• Current Photovoltaic Research
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• v.6 no.4
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• pp.94-101
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• 2018

Light elevated temperature induced degradation (LeTID) was noted as an issue in multi-crystalline silicon solar cells (MSSC) by Ram speck in 2012. In contrast to light induced degradation (LID), which has been researched in silicon solar cells for a long time, research about both LeTID and the mechanism of LeTID has been limited. In addition, research about LeTID in single-crystalline silicon solar cells (SSSC) is even more limited. In order to improve understanding of LeTID in SSSC with a passivated emitter rear contact (PERC) structure, we fabricated four group samples with boron and oxygen factors and evaluated the solar cell characteristics, such as the cell efficiency, $V_{oc}$, $I_{sc}$, fill factor (FF), LID, and LeTID. The trends of LID of the four group samples were similar to the trend of LeTID as a function of boron and oxygen.

• Journal of Periodontal and Implant Science
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• v.42 no.6
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• pp.248-255
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• 2012

Purpose: The aim of the present study was to evaluate the biological response of alkali- and heat-treated titanium-8tantalum-3niobium surfaces by cell proliferation and alkaline phosphatase (ALP) activity analysis. Methods: Commercial pure titanium (group cp-Ti) and alkali- and heat-treated titanium-8tantalum-3niobium (group AHT) disks were prepared. The surface properties were evaluated using scanning electron microscopy, energy dispersed spectroscopy and X-ray photoelectron spectroscopy (XPS). The surface roughness was evaluated by atomic force microscopy and a profilometer. The contact angle and surface energy were also analyzed. The biological response of fetal rat calvarial cells on group AHT was assessed by cell proliferation and ALP activity. Results: Group AHT showed a flake-like morphology microprofile and dense structure. XPS analysis of group AHT showed an increased amount of oxygen in the basic hydroxyl residue of titanium hydroxide groups compared with group cp-Ti. The surface roughness (Ra) measured by a profilometer showed no significant difference (P>0.05). Group AHT showed a lower contact angle and higher surface energy than group cp-Ti. Cell proliferation on group AHT surfaces was significantly higher than on group cp-Ti surfaces (P<0.05). In comparison to group cp-Ti, group AHT enhanced ALP activity (P<0.05). Conclusions: These results suggest that group AHT stimulates osteoblast differentiation.

• International Journal of Railway
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• v.6 no.3
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• pp.85-89
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• 2013

The purpose of this paper is investigating the effect and influence rates of utilizing thin walled energy absorption tubes for improving crashworthiness parameter by increasing energy absorption of the body in high speed railcars. In order to find this, a proper profile of available tubes is chosen and added to the structure of selected high speed train in Iranian railway network (Pardis Trainset) and then examined in the scenario of impact with other moving rolling stock. Because of the specific features of LS-DYNA 3D software at collision analysis, the dynamic simulation has been performed in LS-DYNA 3D. The results of the analysis clearly indicate the improvement of train crashworthiness as the energy absorption of structure increases more than 30 percent in comparison with the original body. This strategy delays and reduces the shock to the structure. The verification of the simulation is by using ECE R66 standard.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.465-469
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• 2009

Characteristics of oxidation reaction of four lanthanide chlorides(Ce, Nd, Pr and $EuCl_3$) in a oxygen-eutectic(LiCl-KCl) salt bubble column was investigated. From the results obtained from the thermochemical calculations by HSC chemistry software, the most stable lanthanide compounds in the oxygen-used rare earth chlorides system were oxychlorides(EuOCl, NdOCl, PrOCl) and oxides($CeO_2$, $PrO_2$), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides for Eu, Nd and Pr and oxides for Ce and Pr were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes : small cubic(oxide) and large tetragonal (oxychloride) structures. The conversion efficiencies of the lanthanide elements to their molten salt-insoluble precipitates(or compound) were increased with the sparging time and temperature, and Ce showed the best reactivity. In the conditions of $650^{\circ}C$ of the molten salt temperature and 420 min of the sparging time, the conversion efficiencies were over 99% for all the investigated lanthanide chlorides.

• Polymer(Korea)
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• v.33 no.2
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• pp.131-136
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• 2009

The effect of the chemical structure of the peroxide crosslinking agent on the reactive crosslinking reaction of EVA was investigated and the physical properties of the crosslinked EVA were studied as well. It was found that peroxide with one peroxy group (perbutyl peroxide) is more effective than peroxides with two peroxy group (2,5 dimethyl 2,5 di(tert-butylperoxyl) hexane and 1,1-di(tert-buthylperoxy)-3,3,5-tri-methylcyclohexane) in melt reactive crosslinking reaction of EVA. The rate of crosslinking was increased by the use of crosslinking acceleration agent but the noticeable effect on degree of crosslinking was not found. Crosslinking caused the lowering of melt flow ability of EVA but mechanical properties were enhanced by the crosslinking of EVA.

• Bulletin of the Korean Chemical Society
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• v.12 no.3
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• pp.265-270
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• 1991

Theoretical calculations on the stabilization energies of framework atoms in hydrolyses Co(Ⅱ )-exchanged zeolite A were made using some potential energy functions and optimization program. The protons which are produced by hydrolysis of $[Co(H_2O)_n]^{2+}$ ion in large cavity showed a tendency to attack the framework oxygen atom O(1) preferentially, and the oxygen atom O(4) within OH- ion was coordinated at Al atom. The weakness of bonds between T(Si, Al) and oxygen by attack of proton and too large coordination number around small aluminum atom will make the framework of Co(Ⅱ)-exchanged zeolite A more unstable. The stabilization energy of $Co_4Na_4$-A framework (- 361.57 kcal/mol) was less than that of thermally stable zeolite A($Na_{12-}$A: - 419.68 kcal/mol) and greater than that of extremely unstable Ba(Ⅱ)-exchanged zeolite A($Ba_{6-}$A: - 324.01 kcal/mol). All the data of powder X-ray diffraction, infrared and Raman spectroscopy of Co(Ⅱ)-exchanged zeolite A showed the evidence of instability of its framework in agreement with the theoretical calculation. Three different groups of water molecules are found in hydrated Co(Ⅱ )-exchanged zeolite A; W(Ⅰ) group of water molecules having only hydrogen-bonds, W(Ⅱ) group water coordinated to $Na^+$ ion, ans W(Ⅲ) group water coordinated to Co(Ⅱ) ion. The averaged interaction energy of each water group shows the decreasing order of W(Ⅲ)>W(Ⅱ)>W(Ⅰ).