• Title/Summary/Keyword: Energy Diffusion

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A Model for Activation Energy of Moisture Diffusion in Wood (수분확산(水分擴散)의 활성화(活性化)에너지 모델)

  • Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.4
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    • pp.21-30
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    • 1992
  • An activation energy equation for moisture diffusion in wood was developed with an assumption that activation energy is directly proportional to wood specific gravity. Theoretical activation energies obtained from the activation energy equation were revealed to be always lower than actual activation energies, which implies that activation energy isn't affected only by wood specific gravity. The other affecting factors are possibly anatomical structures of wood which determine a ratio of vapor diffusion to bound water diffusion in wood. For the convenience of estimating actual activation energy by using the activation energy equation, thirteen kinds of species were categorized into three groups according to their anatomical structures.

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A Study on NO Emission Behavior through Preferential Diffusion of $H_2$ and H in $CH_4-H_2$ Laminar Diffusion Flames (메탄-수소 층류확산화염에서 $H_2$와 H의 선호확산이 NO 거동에 미치는 영향에 관한 연구)

  • Park, Jeong;Kwon, Oh-Boong;Yun, Jin-Han;Keel, Sang-In
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.3
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    • pp.265-274
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    • 2007
  • A study has been conducted to clarify NO emission behavior through preferential diffusion effects of $H_2$ and H in methane-hydrogen diffusion flames. A comparison is made by employing three species diffusion models. Special concerns are focused on what is the deterministic role of the preferential diffusion effects in flame structure and NO emission. The behavior of maximum flame temperatures with three species diffusion models is not explained by scalar dissipation rate but the nature of chemical kinetics. The preferential diffusion of H into reaction zone suppresses the populations of the chain carrier radicals and then flame temperature while that of $H_2$ produces the increase of flame temperature. These preferential diffusion effects of $H_2$ and H are also discussed about NO emissions through the three species diffusion models.

Theoretical studies on the stabilization and diffusion behaviors of helium impurities in 6H-SiC by DFT calculations

  • Obaid Obaidullah;RuiXuan Zhao;XiangCao Li;ChuBin Wan;TingTing Sui;Xin Ju
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.2879-2888
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    • 2023
  • In fusion environments, large scales of helium (He) atoms are produced by a radical transformation along with structural damage in structural materials, resulting in material swelling and degradation of physical properties. To understand its irradiation effects, this paper investigates the stability, electronic structure, energetics, charge density distribution, PDOS and TDOS, and diffusion processes of He impurities in 6HSiC materials. The formation energy indicates that a stable, favorable position for interstitial He is the HR site with the lowest energy of 2.40 eV. In terms of vacancy, the He atom initially prefers to substitute at pre-existing Si vacancy than C vacancy due to lower substitution energy. The minimum energy paths (MEPs) with migration energy barriers are also calculated for He impurity by interstitial and vacancy-mediated diffusion. Based on its calculated energy barriers, the most possible diffusion path includes the exchange of interstitial and vacancy sites with effective migration energies ranging from 0.101 eV to 1.0 eV. Our calculation provides a better understanding of the stabilization and diffusion behaviors of He impurities in 6H-SiC materials.

THE EFFECT OF SI-RICH LAYER COATING ON U-MO VS. AL INTERDIFFUSION

  • Ryu, Ho-Jin;Park, Jae-Soon;Park, Jong-Man;Kim, Chang-Kyu
    • Nuclear Engineering and Technology
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    • v.43 no.2
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    • pp.159-166
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    • 2011
  • Si-rich-layer-coated U-7 wt%Mo plates were prepared in order to evaluate the diffusion barrier performance of the Si-rich layer in U-Mo vs. Al interdiffusion. Pure Si powder was used for coating the U-Mo plates by annealing at $900^{\circ}C$ for 1 h under vacuum of approximately 1 Pa. Si-rich layers containing more than 60 at% of Si were formed on U-7 wt%Mo plates. Diffusion couple tests were conducted in a muffle furnace at $560-600^{\circ}C$ under vacuum using Si-rich-layer-coated U-Mo plates and pure Al plates. Diffusion couple tests using uncoated U-Mo plates and Al-(0, 2 or 5 wt%)Si plates were also conducted for comparison. Si-rich-layer coatings were more effective in suppressing the interaction during diffusion couple tests between coated U-Mo plate and Al, when compared with U-Mo vs. Al-Si diffusion couples, since only small amounts of Al in the coating could be found after the diffusion couple tests. Si-rich-layer-coated U-7wt%Mo particles were also prepared using the same technique for U-7 wt%Mo plates to observe the microsturctures of the coated particles.

Direct Measurement of Diffusion Length in Mixed Lead-halide Perovskite Films Using Scanning Photocurrent Microscopy

  • Kim, Ahram;Son, Byung Hee;Kim, Hwan Sik;Ahn, Yeong Hwan
    • Current Optics and Photonics
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    • v.2 no.6
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    • pp.514-518
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    • 2018
  • Carrier diffusion length in the light-sensitive material is one of the key elements in improving the light-current conversion efficiency of solar-cell devices. In this paper, we measured the carrier diffusion length in lead-halide perovskite ($MAPbI_3$) and mixed lead-halide ($MAPbI_{3-x}Cl_x$) perovskite devices using scanning photocurrent microscopy (SPCM). The SPCM signal decreased as we moved the focused laser spot away from the metal contact. By fitting the data with a simple exponential curve, we extracted the carrier diffusion length of each perovskite film. Importantly, the diffusion length of the mixed-halide perovskite was higher than that of the halide perovskite film by a factor of 3 to 6; this is consistent with the general expectation that the carrier mobility will be higher in the case of the mixed lead-halide perovskites. Finally, the diffusion length was investigated as a function of applied bias for both samples, and analyzed successfully in terms of the drift-diffusion model.

Research of the Performance Improvement of a Light Shelf Depending on the Diffusion Film Installation Position (확산필름 부착 위치에 따른 광선반 성능개선 연구)

  • Park, Eunsu;Lee, Heangwoo;Song, Seonkjae;Kim, Yongseong
    • KIEAE Journal
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    • v.17 no.3
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    • pp.91-97
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    • 2017
  • Purpose: Various studies on a light shelf are in progress, but it has the problem of glare occurrence. The present study suggested a diffusion film as the method for resolving the glare problem, and aimed to establish light shelf-related basic data by conducting the performance evaluation of a light shelf depending on the installation position of the diffusion film. Method: To carry out the light shelf performance evaluation depending on the diffusion film installation position, three cases were established: no diffusion film installation (Case 1), diffusion film installation on the reflector (Case 2), and diffusion film installation on the upper glass surface of the window for light shelf installation (Case 3); and the energy reduction performance, luminance, and luminance contrast were analyzed based on a testbed. Result: The conclusions of this study are as follows. 1) When the diffusion film was applied, the amount of light introduced through the light shelf decreased, and the average indoor illumination decreased accordingly. 2) For Case 3, the lighting energy reduction performance was identical to the lighting energy reduction efficiency of the existing light shelf; and for Case 2, it was found to be inappropriate as the lighting energy consumption increased compared to that of the existing light shelf. 3) The analysis of the glare for the cases established in this study showed that the luminance contrast was low for Case 3, and thus the glare problem could be minimized. 4) The specific angle of the light shelf could induce the glare problem by increasing the luminance depending on the external condition. 5) Based on the aforementioned contents, the installation position of the diffusion film for improving the lighting performance and glare problem of the light shelf was found to be the upper glass surface of the window for light shelf installation.

A study on a sequenced directed diffusion algorithm for sensor networks (센서네트워크용 Sequenced Directed Diffusion 기법 연구)

  • Jang, Jae-Shin
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.11 no.5
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    • pp.889-896
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    • 2007
  • Advances in wireless networking, micro-fabrication and integration, and embedded microprocessors have enabled a new generation of massive-scale sensor networks. Because each sensor node is limited in size and capacity, it is very important to design a new simple and energy efficient protocol. Among conventional sensor networks' routing protocols, the directed diffusion scheme is widely blown because of its simplicity. This scheme, however, has a defect in that sending interest and exploratory data messages while setting connection paths consumes much energy because of its flooding scheme. Therefore, this paper proposes a new sensor network routing protocol, called sequenced directed diffusion with a threshold control, which compromises the conventional directed diffusion scheme's defect and offers an energy efficient routing idea. With a computer simulation, its performance is evaluated and compared to the conventional directed diffusion scheme. Numerical results show that the proposed scheme offers energy efficiency while routing packets, and resolves ill-balanced energy consumption among sensor nodes.

Drift Diffusion of Radiation-produced Point Defects to Edge Dislocation

  • Park, S.S.;Chang, K.O.;Choi, S.P.;Kim, C.O.
    • Nuclear Engineering and Technology
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    • v.31 no.2
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    • pp.151-156
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    • 1999
  • Under the heavy irradiation of crystalline materials when the production and the recombination of interstitials and vacancies are included, the diffusion equations become nonlinear. An effort has been made to arrange an appropriate transformation of these nonlinear differential equations to more solvable Poisson's equations, finally analytical solutions for simultaneously calculating the concentrations of interstitials and vacancies in the angular dependent Cottrell's potential of the edge dislocation have been derived from the well-known Green's theorem and perturbation theory.

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Formation and Growth of Hydride Blisters in Zr-2.5Nb Pressure Tubes

  • Cheong, Yong-Moo;Gong, Un-Sik;Choo, Ki-Nam;Kim, Sung-Soo;Kim, Young-Suk
    • Nuclear Engineering and Technology
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    • v.33 no.2
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    • pp.192-200
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    • 2001
  • Hydride blisters were formed on the outer surface of Zr-2.5Nb pressure tube by a non- uniform steady thermal diffusion process. A thermal gradient was applied to the pressure tube with a heat bath kept at a temperature of 415$^{\circ}C$ and an aluminum cold finger cooled with flowing water of 15$^{\circ}C$. Optical microscopy and tree-dimensional laser profilometry were used to characterize the hydride blisters with different hydrogen concentrations and thermal diffusion time. Hydride blisters were expected to start at a hydrogen concentration of 30 - 70 ppm and a thermal diffusion time of 4 - 6$\times$10$^{5}$ sec. The hydride blister size increases with higher hydrogen concentrations and longer thermal diffusion time . Some of the samples revealed cracks on the hydride blisters. The ratio of hydride blister depth to height was estimated as approximately 8: 1.

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